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Investigation of the Properties of Polymer Bonded Explosives Based on 1,1-Diamino-2,2-dinitroethene (FOX-7) and 1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane (HMX)

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The influence of polymeric matrices on the physical properties and stability of polymer bonded explosives based on FOX-7 (1,1-diamino-2,2-dinitroethene) and HMX (1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane) was investigated. Samples of explosives were prepared with different polymeric additives e.g. nonylphenylpolyoxyethyleneglycol ethers (ROKAFENOL), silicone greases and poly(3-methyl-3-nitroxymethyloxetane) (Poly(NIMMO)). The mass ratio of polymeric matrices to explosives was determined experimentally in order to obtain plastic samples stable at room temperature. The most promising products were tested for sensitivity to mechanical and thermal stimuli. Determinations of the critical diameter and detonation velocity were also performed. The use of silicone grease in the mixture containing Poly(NIMMO) gave the most desirable results, that is to say a combination of high performance and high stability.
Słowa kluczowe
Rocznik
Strony
859--870
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
autor
  • Military University of Technology, Kaliskiego 2, 00-908 Warsaw, Poland
  • Military University of Technology, Kaliskiego 2, 00-908 Warsaw, Poland
Bibliografia
  • [1] Latypov N., Bergman J., Langlet A., Wellmar U., Bemm U., Synthesis and Reactions of 1,1-Diamino-2,2-dinitroethylene, Tetrahedron, 1998, 54, 11525-11536.
  • [2] Bemm U., Ostmark H., 1,1-Diamino-2,2-dinitroethylene – a Novel Energetic Material with Infinite Layers in Two Dimensions, Acta Cryst., C54, 1998, 1997- 1998.
  • [3] Latypov N., Langlet A., Wellmar U., Chemical Compound Suitable for Use as an Explosive, Intermediate and Method for Preparing the Compound, Patent US 6 312 538 B1, 2001.
  • [4] Ostmark H., Bergman H., Bemm U., Goede P., Holmgren E., Johansson M., Langlet A., Latypov N., Pettersson A., Pettersson M.L., Wingborg N., Vorde C., Stenmark H., Karlsson L., Hihkio M., 2,2-Dinitro-ethene-1,1-diamine (FOX-7) – Properties, Analysis and Scale-up, 32nd Int. Annu. Conf. ICT, Karlsruhe, Germany, 2001, 26-1/26-21.
  • [5] Holmgren E., Carlsson H., Goede P., Latypov N., Crescenzi C., Characterization of FOX-7, Its Precursors and Possible Byproducts, 34th Int. Annu. Conf. ICT, Karlsruhe, Germany, 2003, 107-1/107-11.
  • [6] Janzon B., Bergman H., Eldsater C., Lamnevik C., Ostmark H., FOX-7 – a Novel, High Performance, Low-vulnerability High Explosive for Warhead Applications, 20th Int. Symp. Ballistcs, Orlando, FL, USA, 2003.
  • [7] Matyushin Y.N., Afanasev G.T., Lebedev V.P., Mahov M.N., Pepekin V.I., TATB and FOX-7: Thermochemistry, Performance, Detonability, Sensitivity, 34th Int. Annu. Conf. ICT, Karlsruhe, Germany, 2003, 119-1/119-13.
  • [8] Wild R., Teipel U., Characterization and Explosive Properties of FOX-7, 35th Int. Annu. Conf. ICT, Karlsruhe, Germany, 2004, P69.
  • [9] Cudziło S., Chyłek Z., Diduszko R., Crystallization and Characterization of 1,1-Diamino-2,2-dinitroethene (DADNE) (in Polish), Biul. WAT, 2005, 54(5-6), 5-18.
  • [10] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Investigation of Sensitivity and Detonation Properties of FOX-7, 37th Int. Annu. Conf. ICT, Karlsruhe, Germany, 2006, P57.
  • [11] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Detonation Characteristics of FOX-7 and Equations of State for Its Detonation Products (in Polish), Biul. WAT, 2007, 56(2), 283-296.
  • [12] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Detonation Properties of 1,1-Diamino-2,2-dnitroethene (DADNE), J. Hazard. Mater., 2008, 157, 605-612.
  • [13] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Investigation of Detonation Characteristics and Sensitivity of FOX-7-based Phlegmatized Explosives (in Polish), Biul. WAT, 2008, 57(3), 7-25.
  • [14] Błądek J., Cudziło S., Pietrzyk S., Chyłek Z., Application of Thin Layer Chromatography for Monitoring of FOX-7 Synthesis, Propellants Explos. Pyrotech., 2009, 34, 321-325.
  • [15] Buszewski B., Michel M., Cudziło S., Chyłek Z., High Performance Liquid Chromatography of 1,1-Diamino-2,2-dinitroethene and Some Intermediate Products of Its Synthesis, J. Hazard. Mater., 2009, 164, 1051-1058.
  • [16] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Investigation of Detonation Characteristics and Sensitivity of DADNE-based Phlegmatized Explosives, 41st Int. Annu. Conf. ICT, Karlsruhe, Germany, 2010, 101-1/101-15.
  • [17] Chyłek Z., Cudziło S., Optimization and Scaling-up of 1,1-Diamine-2,2-dinitroethene (FOX-7) Synthesis (in Polish), Biul. WAT, 2011, 60(2), 379-391.
  • [18] Trzciński W.A., Chyłek Z., Modeling of the Synthesis of 1,1-Diamino-2,2-dinitroethylene (DADNE) (in Polish), Biul. WAT, 2011, 60(2), 421-437.
  • [19] Trzciński W.A., Cudziło S., Chyłek Z., Szymańczyk L., Detonation Properties and Thermal Behavior of FOX-7-based Explosives, J. Energ. Mater., 2013, 31, 72-85.
  • [20] Kretschmer A., Gerber P., Happ A., Characterisation of Plastic Bonded Explosive Charges Containing FOX-7, 35th Int. Annu. Conf. ICT, Karlsruhe, Germany, 2004, P172.
  • [21] Helte A., Carlsson T., Eldsäter C., Lundgren J., Örnhed H., Performance of FOX-7 (1,1-Diamino-2,2-dinitroethene) in Shaped Charge Applications, 23rd Int. Symp. Ballistics, Tarragona, Spain, 2007, 59-66.
  • [22] Orzechowski A., Powała D., Maranda A., Florczak B., 1,1-Diamino-2,2-dinitroethylene as a Component of Plastic Bonded Explosives, New Trends Res. Energ. Mater., Proc. Semin., 10th, Pardubice, Czech Republic, 2007, 825-830.
  • [23] Eldsäter C., Edvinsson H., Johansson M., Pettersson Å., Sandberd C., Formulation of PBX’s Based on 1,1-Diamino-2,2-dinitroethylene (FOX-7), 33rd Int. Annu. Conf. ICT, Karlsruhe, Germany, 2002, P63.
  • [24] Eldsäter C., Roman N., Development of Compositions Based on 1,1-Diamino-2,2-dinitroethylene (FOX-7), 8th Int. Semin. Euro Pyro, Saint Malo, France, 2003, 212-223.
  • [25] Elbeih A., Zeman S., Jungova M., Suceska M., Akstein Z., Effect of Different Polymeric Matrices on the Sensitivity and Performance of Interesting Cyclic Nitramines, Cent. Eur. J. Energ. Mater., 2012, 9(2), 131-138.
  • [26] Szala M., Cichoń M., Investigation of Cross-linked Poly(3-methyl-3-nitroxymethyloxetane), Chemik, 2015, 69(3), 133-135.
  • [27] Suceska M., Test Method for Explosives, Springer-Verlag, New York, Inc, 1995, pp. 21-28; ISBN 978-0-387-94555-2.
  • [28] Fried L.E., CHEETAH 1.39 − User’s Manual, UCRL-MA-117541 Rev. 3, Lawrence Livermore National Laboratory Report, Livermore, 1996.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ff897e2f-6e91-4cef-8ead-62d7201f363c
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