Investigation of the Efficiency of the UV/H2O2 Process on the Removal of Dye Acid Green 16 from Aqueous Solutions: Process Optimization and Toxicity Assessment

• Autorzy: Płonka I. , Pieczykolan B. , Barbusiński K. , Kalka J. , Thomas M. , Piskorz P. J.

Identyfikatory

DOI

10.5604/01.3001.0010.5379

Warianty tytułu

PL

Badania efektywności procesu UV/H2O2 w usuwaniu barwnika Acid Green 16 z roztworów wodnych: optymalizacja procesu i ocena toksyczności

• Języki publikacji: EN

Abstrakty

EN

The effects of the removal of Acid Green 16 (100 mg AG-16/dm³, COD=111 mg O₂/dm³) from aqueous solutions by the UV/H₂O₂ process in UV reactors: low pressure lamp (LP, 15W) and medium pressure lamps (MP, 150W) are presented. The best results of AG-16 removal were obtained for H₂O₂ 250 mg/dm³ (99.85%, AG-16=0.15 mg/dm³) and 200 mg/dm³ (99.80%, AG-16=0.20 mg/dm³) for LP and MP lamps, respectively, with the same parameters, i.e. 30 min reaction time and pH 6. Under these conditions, the AG-16 solution was completely discolored and the COD removal efficiency was 57.3% (LP lamp) and 63,4% (MP lamp). However, at optimum conditions of decolorisation, no decrease in the toxicity of solutions (Microtox test) was observed. For the MP lamp, the toxicity of solutions remained at the same level as in the initial solutions (Toxicity Unit, TU=3), whereas in the case of the LP lamp, the TU value after the process increased to 6. In conclusion, the AOPs for toxic pollutants should also be optimised from the point of view of toxicity.

PL

Przedstawiono efekty usuwania barwnika Acid Green 16 (100 mg AG-16/dm³, ChZT=110.9 mg O₂/dm³) z roztworów wodnych metodą UV/H₂O₂ z zastosowaniem dwóch reaktorów UV: z lampą niskociśnieniową (LP, 15W) i średniociśnieniową (MP, 150W). Najlepsze efekty usunięcia AG-16 uzyskano dla H₂O₂ 250 mg/dm³ (99.85%, AG-16=0.15 mg/dm³) i 200 mg/dm³ (99.80%, AG-16=0.20 mg/dm³) odpowiednio dla lamp LP i MP przy tych samych pozostałych parametrach, tj. czasie reakcji 30 min i pH 6. W tych warunkach uzyskano całkowite odbarwienie roztworów barwnika AG-16, a obniżenie wartości ChZT wynosiło 57.3% (lampa LP) i 63,4% (lampa MP). Dla wyznaczonych optymalnych warunków dekoloryzacji roztworów AG-16 ich toksyczność (Microtox test) nie uległa obniżeniu. Dla lampy MP toksyczność pozostała na tym samym poziomie jak roztworów wyjściowych (Jednostka Toksyczności, TU=3), natomiast w przypadku lampy LP wartość TU wzrosła do 6. Wynika z tego, że procesy AOPs dla zanieczyszczeń toksycznych powinny być optymalizowane także z uwzględnieniem analizy toksyczności.

Słowa kluczowe

EN

Acid Green 16; decolorization; toxicity; UV/H2O2 process

PL

Acid Green 16; odbarwianie; toksyczność; proces UV/H2O2

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2017
• Tom: Vol. 25, no. 6 (126)
• Strony: 103--107
• Opis fizyczny: Bibliogr. 35 poz., rys., tab.

Twórcy

autor

Płonka I.

• Silesian University of Technology, Institute of Water and Wastewater Engineering, Gliwice, Poland

autor

Pieczykolan B.

• Silesian University of Technology, Institute of Water and Wastewater Engineering, Gliwice, Poland

autor

Barbusiński K.

• Silesian University of Technology, Institute of Water and Wastewater Engineering, Gliwice, Poland

autor

Kalka J.

• Silesian University of Technology, Environmental Biotechnology Department, Gliwice, Poland

autor

Thomas M.

• Chemiqua Company, Kraków, Poland

autor

Piskorz P. J.

• Chemiqua Company, Kraków, Poland

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).