Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
Fertilizer encapsulation through polymer membranes can reduce fertilizer losses and minimize environmental pollution. In this paper, an emulsion of ethyl cellulose (EC)/vinyl acetate (VAc)/butyl acrylate (BA) was successfully prepared by pre-emulsified semi-continuous seed emulsion polymerization. EC/BA/VAc films showed biodegradability. The influence of the EC content on the properties of EC/BA/VAc films was also investigated by DSC, a water absorbency analysis, etc. Controlled-release urea encapsulated by EC/BA/VAc latex was prepared in a film coating machine and conformed to the standards for slow-release fertilizers of the Committee of European Normalization. The release of urea from controlled-release urea encapsulated by EC/BA/VAc latex containing 0%, 5%, 10%, and 15% EC was 75.1%, 65.8%, 70.1% and 84.1%, respectively, after 42 days, and controlled-release urea encapsulated by EC/BA/VAc latex (5% EC) had the best controlled-release ability. Therefore, controlled-release urea encapsulated by EC/BA/VAc latex has many potential applications in agricultural industry.
Czasopismo
Rocznik
Tom
Strony
108--112
Opis fizyczny
Bibliogr. 30 poz., rys., tab.
Twórcy
autor
- College of Basic Sciences of Huazhong Agricultural University, Wuhan, China 430070
autor
- Hubei University of Technology, College of Bioengineering, Wuhan, China 430068
autor
- College of Basic Sciences of Huazhong Agricultural University, Wuhan, China 430070
autor
- Centre for Microelement Research of Huazhong Agricultural University Laboratory of Plant Nutrition and Ecological Environment Research, , Wuhan, China 430070
autor
- College of Basic Sciences of Huazhong Agricultural University, Wuhan, China 430070
Bibliografia
- 1. Elbarbary, A.M. & Ghobashy, M.M. (2017). Controlled release fertilizers using superabsorbent hydrogel prepared by gamma radiation. Radiochimica Acta 105 (10), 865-876. DOI: 10.1515/ract-2016-2679.
- 2. Wei, Y., Li, J., Li, Y., Zhao, B., Zhang, L., Yang, X. & Chang, J. (2017). Research on permeability coefficient of a polyethylene controlled-release film coating for urea and relevant nutrient release pathways. Polym. Test. 59, 90-98. DOI: 10.1016/j.polymertesting.2017.01.019.
- 3. Sabadini, R.C., Silva, M.M., Pawlicka, A. & Kanicki, J. (2008). Gellan gum-O,O’-bis(2-aminopropyl)-polyethylene glycol hydrogel for controlled fertilizer release. J. Appl. Polym. Sci. 135(2), 45636-45642. DOI: 10.1002/app.45636.
- 4. Hong, K. & Park, S. (2000). Polyurea microcapsules with different structures: Preparation and properties. Appl. Polymer. Sci. 78(4), 894-898. DOI: 10.1002/1097-4628(20001024)78:4<894::AID -APP240> 3.0.CO;2-9.
- 5. Kumbar, S.G., Kulkarni, A.R., Dave, A.M. & Aminabha, T.M. (2001). Encapsulation efficiency and release kinetics of solid and liquid pesticides through urea formaldehyde crosslinked starch, guar gum, and starch guar gum matrices. Appl. Polym. Sci. 82, 2863-2866. DOI: 10.1002/app.2141.abs.
- 6. Han, X., Chen, S. & Hu, X. (2009). Controlled-release fertilizer encapsulated by starch/polyvinyl alcohol coating. Desalination. 240, 21-26. DOI: 10.1016/j.desal.2008.01.047.
- 7. Chen, L., Xie, Z., Zhuang, X., Chen, X. & Jing, X. (2008). Controlled release of urea encapsulated by starch-g- -poly(L-lactide). Carbohy. Polym. 72, 342-348. DOI: 10.1016/j. carbpol.2007.09.003.
- 8. Cruz, D.F., Bortoletto-Santos, R., Guimarães, G.G.F., Polito, W.L. & Ribeiro, C. (2017). Role of polymeric coating on the phosphate availability as a fertilizer: insight from phosphate release by castor polyurethane coatings. J. Agric. Food Chem. 65(29), 5890-5895. DOI: 10.1021/acs.jafc.7b01686.
- 9. Yang, Y.C., Tong, Z.H., Geng, Y.Q., Li, Y.C. & Zhang, M. (2013). Biobased polymer composites derived from corn stover and feather meals as double-coating materials for controlled- release and water-retention urea fertilizers. J. Agric. Food Chem. 61 (34), 8166-8174. DOI: 10.1021/jf402519t.
- 10. Qiao, D., Liu, H., Yu, L., Bao, X., Simon, G.P., Petinakis, E. & Chen, L. (2016). Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer. Carbohydr. Polym. 147, 146-154. DOI: 10.1016/j. carbpol.2016.04.010.
- 11. Zhang, S.G., Yang, Y.C., Gao, B., Li, Y.C. & Li, Z. (2017). Superhydrophobic controlled-release fertilizers coated with bio-based polymers with organosilicon and nano-silica modifications. J. Mater. Chem. A. 5, 19943-19953. DOI: 10.1039/ C7TA06014A.
- 12. Desai, J., Alexander, K. & Riga, A. (2006). Characterization of polymeric dispersions of dimenhydrinate in ethyl cellulose for controlled release. Int. J. Pharm. 308, 115-123. DOI: 10.1016/j.ijpharm.2005.10.034.
- 13. Tarvainen, M., Sutinen, R., Peltonen, S. & Mikkonen, H. (2003). Enhanced film-forming properties for ethyl cellulose and starch acetate using n-alkenyl succinic anhydrides as novel plasticizers. Eur. J. Pharm. Sci. 19, 363-37. DOI: 10.1016/ S0928-0987(03)00137-4.
- 14. Pérez-García, S., Fernández-Pérez, M., Villafranca-Sánchez, M., González-Pradas, E. & Flores-Céspedes, F. (2007). Controlled Release of Ammonium Nitrate from Ethylcellulose Coated Formulations. Ind. Eng. Chem. Res. 46, 3304-3311. DOI: 10.1021/ie061530s.
- 15. Wang, D., Chen, C., Xuan, Y., Huang, Y. & Shen, J. (2009). Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate). Polym. J. 41(1), 69-73. DOI: 10.1295/polymj.PJ2008032.
- 16. Liu, W., Liu, R., Li, Y., Kang, H., Shen, D., Wu, M. & Huang, Y. (2009). Self-assembly of ethyl cellulose-graft-polystyrene copolymers in acetone. Polymer. 50, 211-217. DOI: 10.1016/j.polymer.2008.10.060.
- 17. Kang, H., Liu, W., Liu, R. & Huang, Y. (2008). A Novel, Amphiphilic Ethyl Cellulose Grafting Copolymer with Poly(2-Hydroxyethyl Methacrylate) Side Chains and Its Micellization. Macromol. Chem. Phys. 209, 424-430. DOI: 10.1002/ macp.200700363.
- 18. Abdel-Razik, E.A. (1996). Aspects of thermal graft copolymerization of methyl methacrylate onto ethyl cellulose in homogeneous media. Carbohyd. Polym. 31, 23-21. DOI: 10.1016/j.sna.2018.06.036.
- 19. Shen, D., Yu, H. & Huang, Y. (2005). Densely Grafting Copolymers of Ethyl Cellulose through Atom Transfer Radical Polymerization. J. Polym. Sci. Pol. Chem. 43, 4099-4108. DOI: 10.1002/pola.20908.
- 20. Tang, X., Gao, L., Fan, X. & Zhou, Q. (2007). Controlled Grafting of Ethyl Cellulose with Azobenzene-Containing Polymethacrylates via Atom Transfer Radical Polymerization. J. Polym. Sci. Pol. Chem. 45, 1653-1660. DOI: 10.1002/pola.21932.
- 21. Yuan, W., Yuan, J., Zhang, F. & Xie, X. (2007). Syntheses, Characterization, and in Vitro Degradation of Ethyl Cellulose- -graft-poly(-caprolactone)-block-poly (L-lactide) Copolymers by Sequential Ring-Opening Polymerization. Biomacromolecules. 8, 1101-1108. DOI: 10.1021/bm0610018.
- 22. Chen, R., Chu, F., Gauthier, C., Chazeau, L., Chaduc, I., Bourgeat-Lami, E. & Lansalot, M. (2010). New Ethyl Cellulose/ Acrylic Hybrid Latexes and Coatings via Miniemulsion Polymerization. J. Polym. Sci. Pol. Chem. 48, 2329-2339. DOI: 10.1002/pola.23998.
- 23. Li, Y., Liao, S., Wu, W., Zhen, D. & Xiao, Z. (2012). Synthesis and characterization of EC/ BA / VAc hybrid latexes via pre-emulsified semi-continuous seed emulsion polymerization. Adv. Mater. Res. 550-553, 183-187. DOI: 10.4028/www. scientific.net/AMR.550-553.183.
- 24. General Administration of Quality Supervision, Inspection and Quarantine of China (AQSIQ). (2006). Plastics - Determination of tensile properties - Part 3: Test conditions for films and sheets (GB/T1040.3-2006) (in Chinese).
- 25. Knorst, M.T., Neubert, R. & Wohlrab, W. (1997). Analytical methods for measuring urea in pharmaceutical formulations. J. Pharmaceut. Biomed. 15(11), 1627-1632. DOI: 10.1016/S0731-7085(96)01978-4.
- 26. Zhu, J., Dong, X., Wang, X. & Wang, Y. (2010). Preparation and properties of a novel biodegradable ethyl cellulose grafting copolymer with poly (p-dioxanone) side-chains. Carbohyd. Polym. 80, 350-359. DOI: 10.1016/j.carbpol.2009.11.027.
- 27. Teramoto, Y. & Nishio, Y. (2003). Cellulose diacetate- -graft-poly(lactic acid)s: synthesis of wide-ranging compositions and their thermal and mechanical properties. Polymer. 44, 2701-2709. DOI: 10.1016/S0032-3861(03)00190-3.
- 28. Gambash, S., Kochba, M. & Avnimelech, Y. (1990). Studies on slow-release fertilizers II. A method for evaluation of nutrient release rate from slow-releasing fertilizers. Soil Sci. 150(1), 446-450. DOI: 10.1097/00010694-199007000-00007.
- 29. Trenkel, M.E. (1997). International Fertilizer Industry Association. International Fertilizer Industry Association, Stratospheric Ozone, HMSO, London.
- 30. Shaviv, A. (2001). Advances in Controlled Release of Fertilizers. Advances in Agronomy. 71, 1-49. DOI: 10.1016/ S0065-2113(01)71011-5.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-fef451a8-3859-44b4-99c5-2b487b687922