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Rheological behavior of sepiolite suspensions homogenized by ultra-turrax high-speed homogenizer

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Języki publikacji
EN
Abstrakty
EN
The ability to disperse sepiolite suspensions is of great interest in various fields such as the production of cosmetics, pharmaceuticals, colors, etc., and in preparing the sample material for analytical purposes. In this study, the flow curves and time-dependent rheological behavior of sepiolite aqueous suspensions homogenized by Ultra-Turrax high-speed rotor-stator homogenizer were investigated under operating conditions. Forward and backward flow curves for homogenized sepiolite suspensions at different homogenization times and solid concentrations were plotted, and the amount of existing hysteresis loop was measured to determine the best conditions for the obtention of a suitable product having gel-forming properties for industrial and/or analytical applications. The results showed that the dispersed sepiolite suspensions exhibited a substantial increase in the viscosity values owing to gel formation, and thixotropic behavior that was rapidly improved by the increasing the solid content of suspension/ homogenization time, and their apparent viscosity decreased by the increasing the time of shearing, and flow characteristic was time-dependent. However, changing the distance between dispersing tool/bottom showed no favorable effect on preserving the rheological behavior of sepiolite suspensions, although the apparent viscosity decreased marginally due to increased distance between dispersing tool/bottom. Also, two time-dependent/independent models, namely the Power-law model and the Weltman model, were used to describe the thixotropy behavior, and different parameters of these models were analyzed. The Weltman model was found to be appropriate to fit the timedependency behavior of sepiolite suspensions and the most obtained value for model parameters A and B belonged to sepiolite suspension with 6 wt% at 25 min, which was considered as the optimized sample in the applied experiments, its final viscosity level increased from 0.82 to 12.55 Pas.
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art. no. 153415
Opis fizyczny
Bibliogr. 21 poz., rys., tab., wykr.
Twórcy
  • Department of Mining Engineering, Faculty of Engineering, Afyon Kocatepe University, 03200 Afyonkarahisar, Turkey
  • Department of Mining Engineering, Faculty of Engineering, Afyon Kocatepe University, 03200 Afyonkarahisar, Turkey
autor
  • Department of Mining Engineering, Faculty of Engineering, Afyon Kocatepe University, 03200 Afyonkarahisar, Turkey
Bibliografia
  • ABDO, J., AL-SHARJI, H., HASSAN, E., 2016. Effects of nano-sepiolite on rheological properties and filtration loss of water-based drilling fluids. Surf. Interface Anal. 48, 522–526.
  • ALTUN, G., OSGOUEI, A.E., SERPEN, U., 2010. Controlling rheological and fluid loss properties of sepiolite based muds under elevated temperatures. In Proceedings World Geothermal Congress, Bali-Indonesia. 1–8.
  • ALVAREZ, A., SANTAREN, J., ESTEBAN-CUBILLO, A., APARICIO, P., 2011. Current industrial applications of palygorskite and sepiolite. In Developments in Palygorskite-Sepiolite Research (E. Galan, A. Singer, editors). Chapter 12. Elsevier 281–298.
  • BARNES, H.A., HUTTON, J.E., WALTERS F.R.S.K., 1989. An Introduction on Rheology. Elsevier. Amsterdam, Holland.
  • CHEMEDA, Y.C., CHRISTIDIS, G.E., TAUHID, KHAN, N.M. KOUTSOPOULOU, E., HATZISTAMOU, V., KELESSIDIS, V.C., 2014. Rheological properties of palygorskite–bentonite and sepiolite–bentonite mixed clay suspensions. Appl. Clay Sci. 90, 165–174.
  • BEKKOUR, K., LEYAMA, M., BENCHABANE, A., SCRIVENER, O., 2005. Time-dependent rheological behavior of bentonite suspensions: An experimental study. J. Rheol. 49(6), 1329-1345.
  • ÇINAR, M., CAN, M.F., SABAH, E., KARAGÜZEL, C., ÇELIK, M.S., 2009. Rheological properties of sepiolite ground in acid and alkaline media. Appl. Clay Sci. 42, 422–426.
  • HEALY, T.W., FUERSTENAU, D.W., 1965. The oxide-water interface---interrelation of the zero point of charge and the heat of immersion. J. Colloid Sci. 20, 376–386.
  • LIU, P., DU, M., CLODE, P., LI, H., LIU, J., LEONG, Y.K., 2020. Surface chemistry. microstructure. and rheology of thixotropic 1-D sepiolite gels. Clays Clay Miner. 68, 9–22.
  • SANTAREN, J., PEREZ-CASTLLS, R., ÁLVAREZ, A., 1987. Time-dependent rheological behavior of sepiolite suspensions. In Proceedings The Sixth Meeting of The European Clay Groups Seville, Sevilla-Spain 486–489.
  • SHAROBA, A.M., SENGE, B., EL-MANSY, H.A., BAHLOL, H.E., BLOCHWITZ, R., 2005. Chemical. sensory and rheological properties of some commercial German and Egyptian tomato ketchups. Eur. Food Res. Technol. 220, 142–151.
  • SIMONTON, T.C., KOMARNENI, S., ROY, R., 1988. Gelling properties of sepiolite versus montmorillonite. Appl. Clay Sci. 3, 165–176.
  • TANRIVER, N., BENLI, B., KIZILCAN, N., 2015. Rheological properties of polysulfone-sepiolite nanocomposites. Int. Sch. Sci. Res. Innovation. 9(2), 324–328.
  • TUNÇ, S., DUMAN, O., UYSAL, R., 2008. Electrokinetic and rheological behaviors of sepiolite suspensions in the presence of poly(acrylic acid sodium salt)s, polyacrylamides, and poly(ethylene glycol)s of different molecular weights. J. Appl. Polym. Sci. 109, 1850–1860.
  • TUNÇ, S., DUMAN, O., ÇETINKAYA, A., 2011. Electrokinetic and rheological properties of sepiolite suspensions in the presence of hexadecyltrimethylammonium bromide. Colloids Surf. A. 377, 123–129.
  • ÜNAL, H.İ., ERDOGAN, B., 1998. The use of sepiolite for decolorization of sugar juice. Appl. Clay Sci. 12, 419–429.
  • VISERAS, C., MEETEN, G.H., LOPEZ-GALINDO, A., 1999. Pharmaceutical grade phyllosilicate dispersions: The influence of shear history on floc structure. Int. J. Pharm. 182, 7–20.
  • WANG, W., WANG, A., 2016. Recent progress in dispersion of palygorskite crystal bundles for nanocomposites. Appl. Clay Sci. 119, 18–30.
  • WELTMAN, R.N., 1943. Breakdown of thixotropic structure as a function of time. J. Appl. Phys. 14, 343–350.
  • ZHANG, J., XU, S., LI, W., 2012. High shear mixers: A review of typical applications and studies on power draw, flow pattern, energy dissipation and transfer properties. Chem. Eng. Process. 57–58, 25–41.
  • ZHENG, Y.P., ZHANG, J.X., LAN, L., YU, P.Y., 2011. Sepiolite nanofluids with liquid-like behavior. Appl. Surf. Sci. 257, 6171–6174.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-fecf200e-d7c2-41b8-8341-551c5293878f
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