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Abstrakty
Ultrasonic velocity, viscosity and density studies on solution of tetrapentylammonium bromide (Pen4NBr) in N,N-dimethylformamide, ethylmethylketone (EMK) and DMF-EMK solvent mixtures containing 0, 20, 40, 60, 80 and 100 mol % of DMF at 298, 308 and 318K have been reported. From the velocity, viscosity and density data values, various parameters namely, the adiabatic compressibility (β), Intermolecular free length (Lf), specific acoustic impedance (Z), free volume (Vf), internal pressure (πi) and relaxation time (τ) have been calculated. All these parameters have been discussed separately to throw light on the solute-solvent and solvent-solvent interactions.
Rocznik
Tom
Strony
103--113
Opis fizyczny
Bibliogr. 28 poz., tab., wz.
Twórcy
autor
- Department of Chemistry, BTC DAV College, Banikhet (Dalhousie), Distt. Chamba, H.P. India
Bibliografia
- [1] Mercus Y; Ion Solvation, John Willy and Sons, New York (1985).
- [2] Conway B.E., Ionic hydration in Chemistry & Biophysics, Elsevier Scientific Pub. Co., New York (1981).
- [3] Patial B. S.; International Letters of Chemistry, Physics and Astronomy, 8(2)(2015)120-132.
- [4] Jacobson B., Acta Chem. Scand, 5(1951)1214; 6(1952)1485;J. chem.. Phys. 20(1952)927.
- [5] Ali A., Hyder S. and Nain A.K., Acoustic let. 21(1998)21;J. Mol. Liq.79(1991)89; Indian J. Phys. B74(2000)63.
- [6] Kannappan V. and Jaya Santhi R, Indian J. Pure Appl. Phys.,43(2005)750.
- [7] Ali A., Nain A.K. and Kamil M, Thermochim Acta, 274(1986)209.
- [8] Nikam P.S. & Hiray A.R.; Indian J. Pure and Appl. Phys.,29(1991)601.
- [9] Kinginger J.B., Tannahill M.M., Greenberg M.S. and Popov A.I., J. Phys. Chem.,77(1973)2444.
- [10] Hill N.E. & Vanghan W.E., Dielectric properties and Molecular Behaviour. (Van Nostrand. New York),(1969)31.
- [11] Syal V.K., Bajaj J.M., Chauhan S. & Chauhan M. S., J. Indian Chem. Soc.,69(1992)807.
- [12] Syal V.K., Patial B. S. & Chauhan S., Acoustics Letters,23(7)(2000)137.
- [13] Patial B.S.; IOSR-JAC,8(2)(2015)1-4.
- [14] Patial B.S.; IOSR-JAC,7(2014)1-5.
- [15] Patial B.S., Chauhan S., Chauhan M.S. & Syal V.K.; Ind. J. of Chem. 41A(2002)2039.
- [16] Syal V.K., Chauhan Anita & chauhan Suvarcha, J. Pure Appl. Ultrason. 27(2005)61-69.
- [17] Kumar G. Pavan, Babu Ch. Praveen, Samatha K., Jyosthna N., Showrilu K., International Letters of Chemistry, Physics and Astronomy 10(2014)25-37.
- [18] Eyring H. and Kincaid J.F.,J.Chem.,6(1928)620.
- [19] Syal V K, Chauhan S & Uma Kumari, Indian J. pure Appl. Phys., 43(2005)844.
- [20] Syal V.K. , Lal G., Bist P. & Chauhan S., J. Mol. Liq., 63(1995)317.
- [21] Syal V.K., Chauhan S. & Gautam R., Ultrasonics,36(1998)619.
- [22] Kumar R, S. Jayakumar & Kannappan, Indian J. pure Appl. Phys., 46(2008)169-175.
- [23] Erying H and Kincaid J.F.; J. Pure & Appl. Ultrason.,6(1938)620.
- [24] Sanaria M.R. & Parsania P.H.; J. Pure and Appl. Ultrason., 22(2000)54.
- [25] Ali Askar S.J.; Journal of Chemical and Pharmaceutical Research,4(1)(2012)617-632.
- [26] V.K.Syal, S. Chauhan, Anita Chauhan and P.Sharma, J. Polymer Material, 22,(2005),323.
- [27] Dhanlakshmi A., JamineVasantha Rani E., & Lakshmi Seetal; Abstract Proceedings, International Conference and Exhibition on Ultrasonics,N.P.L.(PUSA), New Delhi, Dec. 2-4(1999)243.
- [28] Chauhan S. Kuldeep K., Patial B.S.; Indian J Pure & App. Phys.,51(2013)531-541.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-fe96ac96-2721-448a-8237-d31d4420759b