Influence of polyethylenimine on the electrophoretic deposition of SiO2 and Ni/SiO2 coatings on 316L stainless steel

• Autorzy: Ratajski T. , Kalemba-Rec I. , Dubiel B.

Identyfikatory

DOI

10.15199/28.2016.4.6

Warianty tytułu

PL

Wpływ polietylenoiminy na osadzanie elektroforetyczne powłok SiO2 i Ni/SiO2 na stali 316L

• Języki publikacji: EN

Abstrakty

EN

The aim of the present work was to investigate the influence of polyethylenimine, a cationic polymer surfactant, on the microstructure and corrosion resistance of SiO2 and Ni/SiO2 coatings electrophoretically deposited on 316L stainless steel. The relationship between zeta potential and pH of the ethanol-based suspensions of SiO2 and Ni powder particles with addition of polyethylenimine was determined. The parameters of electrophoretic deposition process (applied voltage, time, distance between electrodes) were developed to prepare good quality coatings. Cathodophoresis from suspensions with polyethylenimine addition was performed with slightly lower applied voltage and time as compared to anodic deposition of coatings without surfactant. The microstructure of the coatings, their surface roughness and adhesion to the substrate were investigated. The protective behaviour of the coatings was studied by potentiodynamic measurements in 3.5% NaCl water solution. The microstructure and properties of the coatings were compared with those obtained without polyethylenimine addition. It was determined that the microstructure of SiO2 and Ni/SiO2 coatings deposited from suspensions containing polyethylenimine was more uniform and contained smaller amount of cracks and voids than the coatings achieved without polyelectrolyte. It was also observed that the quality improvement of the coatings deposited on 316L steel due to addition of polyelectrolyte with binding properties leads to increase of their corrosion resistance.

PL

Celem pracy było zbadanie wpływu polietylenoiminy (PEI) na stabilność zawiesin na bazie etanolu używanych do osadzania elektroforetycznego (EPD) powłok SiO2 i nanokompozytowych powłok Ni/SiO2 na stali 316L. Zbadano mikrostrukturę powłok oraz topografię powierzchni, przyczepność do podłoża i odporność na korozję w 3,5% roztworze NaCl.

Słowa kluczowe

EN

electrophoretic deposition (EPD); SiO2 coatings; Ni/SiO2 composite coatings; polyelectrolyte; polyethylenimine

PL

osadzanie elektroforetyczne (EPD); powłoki SiO2; kompozytowe powłoki Ni/SiO2; polielektrolit; polietylenoimina

• Wydawca: Wydawnictwo SIGMA-NOT
• Czasopismo: Inżynieria Materiałowa
• Rocznik: 2016
• Tom: Vol. 37, nr 4
• Strony: 184--189
• Opis fizyczny: Bibliogr. 35 poz., fig., tab.

Twórcy

autor

Ratajski T.

• AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Department of Ferrous Metallurgy, Kraków, Poland

autor

Kalemba-Rec I.

• AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Department of Surface Engineering & Materials Characterisation, Kraków, Poland

autor

Dubiel B.

• AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Department of Ferrous Metallurgy, Kraków, Poland

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.