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Studies on the Ballistic Parameters of a Deterred Triple Base Propellant Used in Large Caliber Ammunition

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this work, the energetic plasticizer N-n-butyl-N-(2-nitroxyethyl)nitramine (Bu-NENA) was used as a deterrent coating for a triple base propellant (TBP) that finds application in large caliber guns. Closed vessel (CV) evaluation was performed to study the ballistic performance of the deterred propellant. A TBP containing nitrocellulose (NC), nitroglycerine (NG) and nitroguanidine (NQ) was coated with an energetic plasticizer using a solution of Bu-NENA. The Bu-NENA coated propellant exhibited inhibition to burning resulting in a reduction in the values of the ballistic parameters viz. (dP/dt)max, burning rate coefficient (β) and relative vivacity (RV), while the pressure index (α) and rise time were increased. The trends obtained during this work display the potential of Bu-NENA as deterrent.
Rocznik
Strony
449--467
Opis fizyczny
Bibliogr. 27 poz., rys., tab.
Twórcy
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
  • Defence Institute of Advanced Technology (Deemed University), Girinagar, Pune, India
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
  • High Energy Materials Research Laboratory, Sutarwadi, Pune-411021, India
Bibliografia
  • [1] Pocock, M.; Einstein, S.; Guyott, C.; Caren, N.; Carlucci D.; Klingaman, K.; Moran, K.B. Modeling of Novel Propellants and Propellant Geometry. Int. Symp. Ballistics, Proc., 23rd, Tarragona, Spain, 2007, 337-342.
  • [2] Mann, D.C. Development of a Deterred Propellant for a Large Caliber Weapon System. J. Hazard. Mater. 1983, 7(3): 259-281.
  • [3] Ryf, K.; Vogelsanger, B.; Schaedeli, U.; Ossola, B. Method of Producing a Functional, High-Energetic Material. Patent US 7473330B2, 2009.
  • [4] Williams, R.A.; Radford, V.A. Process for Deterrent Coating of Triple Base Propellant Compositions. Patent US 4300961, 1981.
  • [5] Northrup, J.R. Energetic Gun Propellant Coating. Patent EU 00633236, 1995.
  • [6] Canterberry, J.B. Polycaprolactone-deterred Nitrocellulose Propellant Compositions and Methods. Patent US 4950342, 1990.
  • [7] Aaronson, H.A.; Shwartz, F.R.; Sukornick, B. Deterrent Coating for Propellant Grains. Patent US 3636882, 1972.
  • [8] Randall, J.C.; Peters. S.; Simmons, R.; Mitchell, S. Energetic Deterrent Coating for Gun Propellant. Patent US 6345577, 2002.
  • [9] Stanley, N.F., Wedwick, J.B. Deterrent Studies of Tank Gun Propellant. JANNAF Propul. Meeting, Proc., San Diego, California, 1987, Vol. I, 215-226.
  • [10] Brodman, B.W.; Devine, M.P.; Finch, R.W.; MacClaren, M.S. Autoradiography Determination of the Dibutyl Phthalate Concentration Profile in a Nitrocellulose Matrix. J. Appl. Polym. Sci. 1974, 18(12): 3739-3744.
  • [11] Brodman, B.W.; Sipia, Jr., J.A.; Schwartz, S. Diffusion of Various Deterrents into Nitrocellulose Matrix. Example of Diffusion with Interaction. J. Appl. Polym. Sci. 1975, 19(7): 1905-1909.
  • [12] Mehta, P.; Shetty, C.P.; Pundkar, R.N.; Shekhar, H. Effect of Loading Densities in Closed Vessel Tests on the Burning Rate of a Propelling Charge. Def. Sci. J. 2015, 65(2): 126-130.
  • [13] Agrawal, J.P. High Energy Materials: Propellant Explosives and Pyrotechnics. 2nd ed., Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010, pp. 218-219; ISBN 978-3-527-32610-5.
  • [14] Meyer, R.; Köhler, J.; Homburg, A. Explosives. 5th ed., Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2002, p. 293; ISBN 3-527-30267-0.
  • [15] Vogelsanger, B.; Ossola, B.; Bronnimann, E. The Diffusion of Deterrents into Propellants Observed by FTIR Microspectroscopy - Quantification of the Diffusion Process. Propellants Explos. Pyrotech. 1996, 21: 330-336.
  • [16] Grivell, M.R. Closed Vessel Test and Determination of Ballistic Properties of Gun Propellants. DSTO Manual WSRL-0291-MA, 1983.
  • [17] Chiu, D.; Grabowsky, A.; Downs, D. Closed Vessel Combustion of Stick Propellant. US Army Armament Research and Development Center, Technical Report ARCLDTR- 84015, 1984.
  • [18] Fong, C.W.; Cooke, C. Diffusion of Deterrents into a Nitrocellulose-Based Structure and Solvent Small Arms Propellant. The Effect of Deterrent Structure and Solvent. J. Appl. Polym. Sci. 1982, 27: 2827-2832.
  • [19] Boulkadid, K.M.; Lefebvre, M.H.; Jeunieau, L.; Dejeaifve, A. Local Temperature Sensitivity Coefficients of a Deterred Spherical Single Base Gun Propellant. Cent. Eur. J. Energ. Mater. 2017, 14(4): 952-965.
  • [20] Leciejewski, Z.; Surma, Z. Effect of Application of Various Ignition Conditions in Closed-Vessel Tests on Burning Rate Calculation of a Fine-Grained Propellant. Combust. Explos. Shock Waves 2011, 47(2): 209-216.
  • [21] Michalski, J.; Leciejewski, Z. Closed Vessel Investigation of Propellant Ignition Process with Using Capillary Plasma Generator. Problems Mechatronics, Armament, Aviation, Saf. Eng. 2015, 6(19): 19-26.
  • [22] Austin, J.M.; Harrison, I.R.; Quickenden, T.I. Electrochemical and Photoelectrochemical Properties of Rhodamine B. J. Phys. Chem. 1986, 90: 1839-1843.
  • [23] Chakraborthy, T.K.; Raha, K.C.; Omprakash, B.; Singh, A. A Study on Gun Propellants Based on Butyl-NENA. J. Energ. Mater. 2004, 22(1): 41-53.
  • [24] Damse, R.S.; Omprakash, B.; Tope, B.G.; Chakraborthy, T.K.; Singh A. Study of N-n-Butyl-N-(2-nitroxyethyl) Nitramine in RDX Based Gun Propellant. J. Hazard. Mater. 2009, 167(1-3): 1222-1225.
  • [25] Liu, D.Y.; Zhao, Z.Y.; Yu, Y.G.; Zhou, Y.H.; Lu, X.; Zhang, L.K. Experiments on the Combustion Characteristics of Deterrent-Coated Propellants and Their Application in Traveling Charge Propulsion. Combust. Sci. Technol. 2012, 184(2): 178-185.
  • [26] Fahrni, M.; Vogelsanger, B.; Steinmann, A.; Ossola, B.; Jeck-Prosch, U.; Huber, A.; Ryf, K. Temperature Independent Propellant Powder. Patent US 7051658B2, 2006.
  • [27] Jeunieau, L.; Lefebvre, M.H.; Fonder, N.; Guilaume, P. Ballistic Stability and Influence of the Firing Temperature of Two Deterred Propellants. Int. Nitrocellulose Symp., 5th, Spiez, 2012.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-fdc88c5a-c1e8-4852-9beb-3be04770709c
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