Photoacoustic Method as a Tool for Analysis of Concentration-Dependent Thermal Effusivity in a Mixture of Methyl Alcohol and Water

• Autorzy: Ponikwicki Nikodem , Szczepanik Łukasz , Gondek Joanna , Linde Bogumił B.J. , Skrodzka Ewa Barbara , Molchanov Vladimir , Yushkov Konstantin B. , Grechishkin Rostislav

Identyfikatory

DOI

10.24425/aoa.2019.126361

• Języki publikacji: EN

Abstrakty

EN

It has been shown in the present paper that exploitation of the experimental potential of a photoacoustic technique can provide information on a type of intermolecular interactions in aqueous mixtures containing organic liquids, when the basic parameters of these mixtures, such as density, ρ, specific heat, c_p, or thermal conductivity, λ, are unknown. Earlier investigations of concentration dependence of effusivity in different aqueous solutions of organic liquids demonstrated that the photoacoustics method is a sensitive tool to identify hydrophobic properties of such liquids. In our experiment this suggestion was exploited for a solution of methanol which is known to display much weaker hydrophobicity than other alcohols. It was confirmed that the location of extreme deviations from linearity for the thermal effusivity, Δe, agrees well with that of characteristic points for the isentropic compressibility coefficient, κ_S, and the excess molar volume, V^E_m , as a function of the concentration.

Słowa kluczowe

EN

thermal effusivity; aqueous solutions; methanol; photoacoustic technique

• Wydawca: Instytut Podstawowych Problemów Techniki PAN ; Komitet Akustyki PAN ; Polskie Towarzystwo Akustyczne
• Czasopismo: Archives of Acoustics
• Rocznik: 2019
• Tom: Vol. 44, No. 1
• Strony: 153--160
• Opis fizyczny: Bibliogr. 34 poz., rys., tab., wykr.

Twórcy

autor

Ponikwicki Nikodem

• Institute of Experimental Physics, University of Gdańsk, Gdańsk, Poland

autor

Szczepanik Łukasz

• Institute of Experimental Physics, University of Gdańsk, Gdańsk, Poland

autor

Gondek Joanna

• Institute of Experimental Physics, University of Gdańsk, Gdańsk, Poland

autor

Linde Bogumił B.J.

• Institute of Experimental Physics, University of Gdańsk, Gdańsk, Poland

autor

Skrodzka Ewa Barbara

• Institute of Acoustics, Faculty of Physics, A. Mickiewicz University, Umultowska 85, 61-612 Poznań, Poland

autor

Molchanov Vladimir

• National University of Science and Technology “MISIS”, 119049 Moscow, Russia

autor

Yushkov Konstantin B.

• National University of Science and Technology “MISIS”, 119049 Moscow, Russia

autor

Grechishkin Rostislav

• Department of Physics, Tver State University, 170100 Tver, Russia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).