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Urea formaldehyde (UF) resins are brittle and to improve their tensile properties poly(vinyl alcohol) (PVA) has been used to modify the UF resin. An easy improved procedure was developed to make PVA modified UF resin on the basis of conventional synthesis of UF resin. Prepolymer of UF was mixed with different weight percentages of PVA (1-5%) to synthesize modified UF resin which can be used to make adhesive for forest products. Both UF and modified UF resins were characterized by FTIR, physico-mechanical and thermal properties analyses. Modified UF resin containing 2 wt. % PVA exhibited better results than the UF.
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53--66
Opis fizyczny
Bibliogr. 34 poz., wykr., tab.
Twórcy
autor
- Fiber & Polymer Research Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka-1205, Bangladesh
autor
- Department of Chemistry, Eden Mohilla College, Dhaka, Bangladesh
autor
- Department of Chemistry, Eden Mohilla College, Dhaka, Bangladesh
autor
- Fiber & Polymer Research Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka-1205, Bangladesh
autor
- Fiber & Polymer Research Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka-1205, Bangladesh
autor
- Fiber & Polymer Research Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka-1205, Bangladesh
Bibliografia
- 1. Liu M., Thirumalai R.V.K.G., Wu Y., Wan H.: Characterization of the crystalline regions of cured urea formaldehyde resin. RSC Advances 7 (2017) 49536-49541.
- 2. Solt P., Konnerth J., Altmutter W.G., Kantner W., Moser J., Mitter R., Herwijnen H. W.G.v.: Technological performance of formaldehyde-free adhesive alternatives for particleboard industry. International Journal of Adhesion and Adhesives 94 (2019) 99-131.
- 3. Li B., Zhang J., Ren X., Chang J., Gou J.: Preparation and Characterization of Bio-Oil Modified Urea-Formaldehyde Wood Adhesives. BioResources 9(3) (2014) 5125-5133.
- 4. Pink S., Herwijnen H.W.G., Veigel S., Altmutter W.G., Riegler M.: Urea-formaldehyde microspheres as a potential additive to wood adhesive. Journal of Wood Science 64 (2018) 390-397.
- 5. Ullah H., Azizli K., Man Z.B, Ismail M.B.C.: Synthesis and Characterization of Urea-formaldehyde Microcapsules Containing Functionalized Polydimethylsiloxanes. Procedia Engineering 148 (2016) 168-175.
- 6. Luo J., Zhang J., Gao Q., Mao A., Li J.: Toughening and Enhancing Melamine-Urea-Formaldehyde Resin Properties via in situ Polymerization of Dialdehyde Starch and Microphase Separation. Polymers 11 (2019) 1-18.
- 7. Ebewele R.O., Myers G.E., River B.H., Koutsky J.A.: Polyamine-Modified Urea-Formaldehyde Resins. I. Synthesis, Structure, and Properties. Journal of Applied Polymer Science 47 (1991) 2997-3012.
- 8. Kariuki S.W., Wachira J., Kawira M., Murithi G.: Formaldehyde Use and Alternative Biobased Binders for Particleboard Formulation: A Review. Journal of Chemistry (2019) 1-12. Article ID 5256897.
- 9. Zorba T., Papadopoulou E., Hatjiissaak A., Paraskevopoulos K.M., Chrissafis K.: Urea formaldehyde resins characterized by thermal analysis and ftir method. Journal of Thermal Analysis and Calorimetry 92 (2008) 29-33.
- 10. Ratna D., Banthia A.K.: Rubber Toughened Epoxy. Macromolecular Research 12(1) (2004) 11-21.
- 11. Seongsu P., Byung D.P.: Crystallinity of Low Molar Ratio Urea-Formaldehyde Resins Modified with Cellulose Nanomaterials. Journal of the Korean Wood Science and Technology 49(2) (2021)169-180.
- 12. Lubis M.A.R., Park B.D.: Modification of urea-formaldehyde resin adhesives with oxidized starch using blocked pMDI for plywood. Journal of Adhesion Science and Technology (2018). DOI: 10.1080/01694243.2018.1511075
- 13. Chen K., Cheng X., Chen Y., Qi J., Xie J., Huang X., Jiang Y., Xiao H.: Thermal Degradation Kinetics of Urea−Formaldehyde Resins Modified by Almond Shells. ACS Omega 6 (2021) 25702−25709.
- 14. Lu L., Wang Y., Li T., Wang S., Yang S., Qing Y., Li X., Wu Y., Liu M.: Calcium carbonate modified urea–formaldehyde resin adhesive for strength enhanced medium density fiberboard production. RSC Advances 11 (2021) 25010.
- 15. Wibowoa E.S., Lubis M.A.R., Park B.D.: In-situ modification of low molar ratio urea–formaldehyde resins with cellulose nanofibrils for plywood. Journal of Adhesion Science and Technology (2021).
- 16. Yadava S.M., Lubis M.A.R., Park B.D.: Modification of nanoclay with different methods and its application in ureaformaldehyde bonded plywood panels. Wood Material Science & Engineering (2021).
- 17. Adegoke O.A., Ogunsanwo O.Y., Olaoye K.O.: Modification of Urea Formaldehyde Resin with Pyrolytic Oil on Particleboard. Journal of Forest and Environmental Science 36 (3) (2020) 219-224.
- 18. Lubis M.A.R., Park B.D.: Enhancing the performance of low molar ratio urea–formaldehyde resin adhesives via in-situ modification with intercalated nanoclay. The Journal of Adhesion 97(14) (2020) 1271-1290.
- 19. İstek A., Biçer A., Özlüsoylu I.: Effect of sodium carboxymethyl cellulose (Na-CMC) added to urea-formaldehyde resin on particleboard properties. Turkish Journal of Agriculture and Forestry 44 (2020) 526-532.
- 20. Réh R., Krišt’ák L., Sedliacik J., Bekhta P., Božiková M., Kunecová D., Vozárová V., Tudor E.M., Antov P., Savov V.: Utilization of Birch Bark as an Eco-Friendly Filler in Urea-Formaldehyde Adhesives for Plywood Manufacturing. Polymers 13 (2021) 511.
- 21. Antov P., Savov V., Krišťák L., Réh R., Mantanis G.I.: Eco-Friendly, High-Density Fiberboards Bonded with Urea-Formaldehyde and Ammonium Lignosulfonate. Polymers 13 (2021) 220.
- 22. Li B.P.M.K., Yuan S.Y.T.Q., Du G.B., Sun R.C.: Eco-Friendly Phenol-Urea-Formaldehyde Co-condensed Resin Adhesives Accelerated by Resorcinol for Plywood Manufacturing. ACS Omega 3 (2018) 8521-8528.
- 23. Ferreira A.M., Pereira J., Almeida M., Ferra J., Paiva N., Martins J., Carvalho L.H., Magalhães F.D.: Effect of spent sulfite liquor on urea–formaldehyde resin performance. Journal of Applied Polymer Science 136(17) (2018) 47389.
- 24. Jiang S., Hu M., Du G., Duan Z., Zhou X., Li. T.: Highly branched polyurea-enhanced urea formaldehyde resin. ACS Applied Polymer Materials 3 (2021) 1157-1170.
- 25. Mathis E., Michon M.L., Billaud C., Grau P., Bocahut A., Vergelati C., Long D.R.: Thermoset modified with polyethersulfone: characterization and control of the morphology, Journal of Polymer Science. Part A-1, Polymer Chemistry 58 (8) (2020) 1177-1188.
- 26. Acebo C., Ramis X., Serra A.: Improved epoxy thermosets by the use of poly(ethyleneimine) derivatives. Physical Sciences Reviews (2017) 1-31, 20160128.
- 27. Feldman D.: Poly(vinyl alcohol) nanocomposites: Recent contributions to engineering and medicine. AIMS Materials Science 8(1) (2021) 119-129.
- 28. Li J., Zhang Y.: Morphology and Crystallinity of Urea-Formaldehyde Resin Adhesives with Different Molar Ratios Polymers 13 (2021) 673.
- 29. Ohalete M.N., Popoola A.V.: Urea-formaldehyde Resins Synthesis, Modification and Characterization. Journal of Applied Chemistry (IOSR-JAC) 12(8) (2019) 19-25.
- 30. Jovanovic S.S., Jovanovic V., Konstantinovic S., Markovic G., Cincovic M.M.: Thermal behavior of modified urea–formaldehyde resins. Journal of Thermal Analysis and Calorimetry 104 (2011) 1159–1166.
- 31. Chen X., Afreen S., Yu X., Dong C., Kong Q.: Modified melamine-formaldehyde resins improve tensile strength along with antifouling and flame retardancy in impregnation of cellulose paper. RSC Advances 9 (2019) 36788-36795.
- 32. Balasubramanya P.C., Natarajan K.: Mechanical and Morphological Studies of Modified Epoxy Resin Matrix for Composite Applications. International Journal of Emerging Technology and Advanced Engineering 4(1) (2014) 281-288.
- 33. Jinhong D., Ming C.H.: The Fabrication, Properties, and Uses of Graphene/Polymer Composites. Macromolecular Chemistry and Physics 213 (2012) 1060-1077.
- 34. Yuan J., Zhao X., Ye L.: Structure and properties of urea-formaldehyde resin/polyurethane blend prepared via in-situ polymerization. RSC Advances 5 (2015) 53700-53707.
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Bibliografia
Identyfikator YADDA
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