Bis(salicylaldehyde) orthophenylenediamine as complexing reagent in simultaneous determination of gold, chromium, iron, uranyl, and nickel using capillary zone electrophoresis

• Autorzy: Soomro R , Memon S. Q. , Ahmed M. J , Memon N , Mallah A
• Języki publikacji: EN

Abstrakty

EN

Bis(salicylaldehyde) orthophenylenediamine (BSOPD) is reported here as a complexing reagent for simultaneous determination of six metal ions, gold, chromium, iron(II)/(III), uranyl, and nickel, by capillary zone electrophoresis. The pre-derivatized complexes were injected onto 50 cm bare silica capillary (i.d. 75 µm) with background electrolyte 50 mM citrate:oxalate buffer in 1:1 at pH 4. All metal ions were separated within 15 min including coexisted ions at applied voltage of −15 kV at detection wavelength of 250 nm. Under the abovementioned conditions, limits of quantification and detection were found to be 0.5, 1.0, 1.0, 10.0, 1.0, and 10.0 µg mL^-1; and 0.16, 0.33, 0.33, 3.33, 0.33, and 3.33 µg mL^-1 for Au(III), Cr(VI), Fe(III), Fe(II), UO2(II), and Ni(II), respectively. Linear calibration graphs were obtained in the ranges of 0.5–100, 1–200, 10–100, 1–100, 1–100, and 10–200 µg mL^-1 with the correlation coefficient values 0.9964, 0.9948, 0.9900, 0.9999, 0.9992, and 0.9918 for Au(III); and Cr(VI), Fe(III), Fe(II), UO2(II), and Ni(II), respectively. Applicability of the method has been evaluated by determining gold from wastewater samples of goldsmith factories and uranyl from ore samples. The developed method was also used for the determination of chromium in selected environmental waters (drinking and polluted). The data obtained with developed method were compared with those obtained from atomic absorption spectroscopy, and the results of the analysis were found to be in good agreement.

Słowa kluczowe

EN

capillary zone electrophoresis; separation of gold; chromium; iron; uranyl and nickel; bis(salicylaldehyde) orthophenylenediamine

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2012
• Tom: Vol. 24, no. 4
• Strony: 543--558
• Opis fizyczny: Bibliogr. 43 poz., rys., tab.

Twórcy

autor

Soomro R

• University of Sindh National Center of Excellence in Analytical Chemistry Jamshoro Pakistan

autor

Memon S. Q.

• University of Sindh Institute of Advance Research in Chemical Sciences Jamshoro Pakistan

autor

Ahmed M. J

• University of Chittagong Laboratory of Analytical Chemistry, Department of Chemistry Chittagong 4331 Bangladesh

autor

Memon N

• University of Sindh National Center of Excellence in Analytical Chemistry Jamshoro Pakistan

autor

Mallah A

• University of Sindh M.A. Kazi Institute of Chemistry Jamshoro Pakistan

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