Spectroscopic studies of dual fluorescence effects in a selected 1,3,4-thiadiazole derivative in organic solvents and aqueous solutions

• Autorzy: Matwijczuk A. , Matwijczuk A. , Karcz D. , Wybraniec S. , Kluczyk D. , Gagoś M. , Niewiadomy A.

Identyfikatory

DOI

10.4467/2353737XCT.17.031.6342

Warianty tytułu

PL

Badania spektroskopowe efektów podwójnej fluorescencji w wybranym związku z grupy 1,3,4-tiadiazoli w rozpuszczalnikach organicznych oraz roztworach wodnych

• Języki publikacji: EN

Abstrakty

EN

Spectroscopic studies of the fluorescence emission of selected 1,3,4-thiadiazoles in organic solvents and an aqueous solution were carried out. An interesting effect of pH-induced dual fluorescence was observed in the aqueous solution. The use of organic solvents resulted either in a single fluorescence maximum, double fluorescence (two well-resolved emission bands), or the dual fluorescence effect. The results obtained suggest that the fluorescence emission effects in 1,3,4-thiadiazoles are associated with both the conformational isomerism and the chromophore aggregation phenomena.

PL

W niniejszym artykule przedstawiono wyniki badań emisji fluorescencji wybranych związków z grupy 1,3,4-tiadiazoli w rozpuszczalnikach organicznych oraz roztworach wodnych. W środowisku wodnym dla badanych związków zaobserwowano interesujący efekt podwójnej fluorescencji indukowany między innymi zmianami pH. W rozpuszczalnikach innych niż woda obserwowano efekt albo pojedynczej fluorescencji lub dwóch rozdzielonych pasm emisji fluorescencji oraz efektu podwójnej fluorescencji. Na podstawie prezentowanych wyników badań zaproponowano, że na obserwowane efekty fluorescencyjne wpływ mogą mieć zarówno zmiany konformacyjne jak również procesy związane z agregacją chromoforową.

Słowa kluczowe

EN

double fluorescence; dual fluorescence effect; molecular spectroscopy; chromophore aggregation; 1,3,4-thiadiazole; charge transfer (CT)

PL

efekt podwójnej fluorescencji; spektroskopia molekularna; agregacja chromoforowa; 1,3,4-tiadiazole; transfer ładunku (CT)

• Wydawca: Wydawnictwo Politechniki Krakowskiej im. Tadeusza Kościuszki
• Czasopismo: Technical Transactions
• Rocznik: 2017
• Tom: Vol. 3(114)
• Strony: 47--61
• Opis fizyczny: Bibliogr. 43 poz., wz., wykr., tab.

Twórcy

autor

Matwijczuk A.

autor

Matwijczuk A.

• Department of Biophysics, University of Life Sciences in Lublin

autor

Karcz D.

• Department of Analytical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology

autor

Wybraniec S.

• Department of Analytical Chemistry, Faculty of Chemical Engineering and Technology, Cracow University of Technology

autor

Kluczyk D.

• Department of Cell Biology, Institute of Biology, Maria Curie-Skłodowska University

autor

Gagoś M.

• Department of Cell Biology, Institute of Biology, Maria Curie-Skłodowska University

autor

Niewiadomy A.

• Department of Chemistry, University of Life Sciences in Lublin

Bibliografia

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Uwagi

EN

Section "Chemistry"