Effect of microwave-induced chemical modification of kaolinite and its application as an eco-friendly filler of rubber blends

Feriancová, Andrea; Šulcová, Jana; Pagáčová, Jana; Dubec, Andrej; Papučová, Iveta; Pajtášová, Mariana; Ondrušová, Darina; Ďurišová, Silvia; Dedinský, Maroš; Klepka, Tomasz Waldemar

doi:10.14314/polimery.2025.3.2

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Tytuł artykułu

Effect of microwave-induced chemical modification of kaolinite and its application as an eco-friendly filler of rubber blends

Autorzy

Feriancová Andrea , Šulcová Jana , Pagáčová Jana , Dubec Andrej , Papučová Iveta , Pajtášová Mariana , Ondrušová Darina , Ďurišová Silvia , Dedinský Maroš , Klepka Tomasz Waldemar

Treść / Zawartość

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Identyfikatory

DOI

10.14314/polimery.2025.3.2

Warianty tytułu

Wpływ mikrofal na modyfikację chemiczną kaolinitu i jego zastosowanie jako ekologicznego napełniacza mieszanek gumowych

Języki publikacji

Abstrakty

Kaolinite was subjected to microwave (MW) and chemical modification with silane and copper acetate. The process was carried out for 30, 60 and 120 min. The use of microwave radiation shortened the time of kaolinite modification (from several days to 30 min). The presence of modifying compounds in the kaolinite structure was confirmed by FT-IR, DSC, TGA and SEM. The use of modified kaolinite (10 phr) reduced the rate of vulcanization of natural rubber and facilitated its processing. Moreover, silane-modified kaolinite increased the tensile strength and hardness of natural rubber, which indicates its strengthening effect.

Kaolinit poddano działaniu mikrofal (MW) oraz modyfikacji chemicznej silanem i octanem miedzi. Proces prowadzono przez 30, 60 i 120 min. Zastosowanie promieniowania mikrofalowego skróciło czas modyfikacji kaolinitu (z kilku dni do 30 min). Obecność związków modyfikujących w strukturze kaolinitu potwierdzono metodą FT-IR, DSC, TGA i SEM. Zastosowanie modyfikowanego kaolinitu (10 phr) zmniejszyło szybkość wulkanizacji naturalnego kauczuku i ułatwiło jego przetwórstwo. Ponadto kaolinit modyfikowany silanem zwiększył wytrzymałość na rozciąganie i twardość kauczuku naturalnego co świadczy o jego wzmacniającym działaniu.

Słowa kluczowe

modified kaolinite rubber composites microwave radiation thermal analysis FT-IR

modyfikowany kaolinit kompozyty gumowe promieniowanie mikrofalowe analiza termiczna FT-IR

Wydawca

Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej

Czasopismo

Polimery

Rocznik

2025

Tom

Vol. 70, nr 3

Strony

166--176

Opis fizyczny

Bibliogr. 47 poz., rys., tab., wykr.

Twórcy

autor

Feriancová Andrea

andrea.feriancova@tnuni.sk

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0003-2293-5213

autor

Šulcová Jana

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0002-1148-2581

autor

Pagáčová Jana

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0003-3639-6492

autor

Dubec Andrej

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0009-0001-6145-6357

autor

Papučová Iveta

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0002-3626-4783

autor

Pajtášová Mariana

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0001-7834-977X

autor

Ondrušová Darina

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0003-2167-9174

autor

Ďurišová Silvia

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0002-2268-7742

autor

Dedinský Maroš

Department of Materials Technologies and Environment, Faculty of Industrial Technologies in Púchov, Alexander Dubček University of Trenčín, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

https://orcid.org/0000-0003-2315-3926

autor

Klepka Tomasz Waldemar

Department of Technology and Polymer Processing, Faculty of Mechanical Engineering, Lublin University of Technology, ul. Nadbystrzycka 36, 20-618 Lublin, Poland

https://orcid.org/0000-0001-9182-0845

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Bibliografia

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