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Gasoline is one of most important sources of energy but when manufactured with low octane number may leave great risk that affect the human health and environment impact. Therefore processes of gasoline production must be developed. Zeolite material dependence on their extremely high frame work extended interactive surface, ability to interact with molecule and cations. They show a wide variety of interesting properties which result in remarkable applications in the fields of catalysts, gas separations, selective adsorption and water softening. Zeolite catalyst loaded with finely (Sr) metal have been used in hydro-cracking, catalytic cracking. The zeolite used is the synthetic zeolite (type Y) has high thermal stability, good surface area and its heterogeneous catalyst which can be separated after treatment and may be reactivated. The study of the octane number was carried out for this zeolite. The gasoline was obtained from market (commercial gasoline) it has octane number 91.7 determined by IROX-2000.The gasoline was treated by zeolite in the temperature about 331 Kelvin. The synthetic zeolite (type-Y) raised the octane number (from 91.7 to 92.4).
Słowa kluczowe
Rocznik
Tom
Strony
184--193
Opis fizyczny
Bibliogr. 22 poz., tab., wykr., wz.
Twórcy
autor
- Department of Chemistry-Elneelain University-Khartoum, Sudan
autor
- Dept. of Chem., College of Science, AI Imam Mohammad Ibn Saud Islamic University (AMSIU), P.O. Box : 5701, Riyadh, KSA
autor
- Dept. of Chem., College of Science, AI Imam Mohammad Ibn Saud Islamic University (AMSIU), P.O. Box : 5701, Riyadh, KSA
Bibliografia
- [1] Abel Derks, and .Co - SUDAN’S OIL INDUSTRY Facts and Analysis- April 2008- p(1-2).
- [2] Nahla Adam-Removal of paraffin wax from Sudanese Petroleum Products-MSc in chemistry Alneelain University- 2011- P(6-7).
- [3] Motaz Elshaikh – enhance octane number by lithium zeolite- Elneelain university- 2013- p(4-35).
- [4] Anton Perdih, Franc Perdih - Chemical Interpretation of Octane Number - Department of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, SI-1000 Ljubljana, Slovenia - Received 12-09-2005 – p (306 – 307).
- [5] Miss Sudaporn Tangkawanit-Synthesis of Zeolites from Perlite and study of their ion exchange properties" A Thesis Submitted in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in Chemistry Suranaree University of Technology Academic Year 2004 – p (1 – 59).
- [6] Hemmler CL, Tajb D G – in Handbook of petroleum Refining Processes – Myers R A ,Editor – New York; MC Grow – Hill 1997 – p(355). (7) R.G. 7. Bell - What are Zeolites – united kingdom- may 2010.
- [7] JOHN D. SHERMAN, Synthetic zeolites and other microporous oxide molecular sieves, Proc. Natl. Acad. Sci. USA Vol. 96, pp. 3471–3478, March 1999]
- [8] B. deKroes, C.J. Groenenboom and P. O’Connor, in: New Zeolites in FCC, Ketjen Catalyst Symposium, Scheveningen, Netherlands, (1986).
- [9] Thomas F. Degnan, Jr. (2000). Applications of zeolites in petroleum refining, Topics in Catalysis 13, pp. 349–356.
- [10] N.Y. Chen, W.E. Garwood and F.G. Dwyer, Shape Selective Catalysisin Industrial Applications (Dekker, New York, 1996).
- [11] N.Y. Chen and T.F. Degnan, Chem. Eng. Prog. 84 (1988) 32.
- [12] JOHN D. SHERMAN, Synthetic zeolites and other microporous oxide molecular sieves, Proc. Natl. Acad. Sci. USA Vol. 96, pp. 3471–3478, March 1999]
- [13] Pramatha Payra and Prabir K. Dutta - Zeolites: A Primer - The Ohio State University, Columbus, Ohio, U.S.A – p (1-5).
- [14] Scherzer J – Gruia A G - Hydrocracking science and technology – New York – Dekker 1996.
- [15] HUDE,Pavol (2011). FCC catalysis - Key Element in Refinery Technology, 45th Int. Petroleum Conf., 13th June 2011, Bratislava, Slovak Republic.
- [16] Cracking catalysts with octane enhancement US patent 4898846 A.
- [17] D.W.Breck.(1974).Zeolite Molecular Sieves, John Wiley and Sons, Inc., New York.10:122.
- [18] G.M Arifuzzaman khan , S.M.Y Arafat, M.N Reza, S.M Abdur Razzague and Md. Shamsul Alam.(2010).Linde Type – Synthesis and effect of crystallization on its surface acidity. Indian Journal of chemical Technology .17:303-308.
- [19] M. M. Rahmana1 , N. Hasnidab , and W. B. Wan Nikb (2009). Preparation of Zeolite Y Using Local Raw Material Rice Husk as a Silica Source, J. Sci. Res. 1 (2), 285-291.
- [20] Albert, B.R., Cheetham, A.K., Stuart, J.A., and Adams, C.J. (1998). Investigation on P zeolites:Synthesis, characterization and structure of highly crystalline low-silica NaP. Microporous and Mesoporous Materials., 21:133-142.
- [21] Holmberg, B.A. H. Wang, J.M. Norbeck, and Y. Yan, Controlling size and yield of zeolite Y nanocrystals using TMABr. Microporous and Mesoporous Materials, 2003. 59: p. 13-28.
- [22] T. Tsutsui, Y. Ueda, K. Ijichi, K. Mizuta and Y. Uemura, 2010. Evaluation of Catalytic Cracking Reactivity of Zeolites using 1-Dodecene as a Model Feedstock-Classification of Zeolites Based on Hydrogen Transfer Reactivity. Journal of Applied Sciences, 10: 3215-3221.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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