Synthesis and Characterization of Metal Derivatives of 1,1,2,2-Tetranitraminoethane (TNAE)

• Autorzy: Zhu C. , Meng Z. , Xu Z. , Liu W. , Liu Y. , Shi X. , Liu Y. , Xie T.

Identyfikatory

DOI

10.22211/cejem/92015

• Języki publikacji: EN

Abstrakty

EN

The introduction of anions and cations into energetic materials can significantly improve their physicochemical and energetic properties. The K, Zn, Ba, Cu and Pb salts of 1,1,2,2-tetranitraminoethane (TNAE) were synthesized using TNAE as the starting material, and were characterized by IR spectroscopy, NMR spectroscopy and elemental analysis. All of the energetic salts exhibited relatively high thermal stabilities (decomposition temperatures ranging from 195.1 °C to 279.3 °C) and high densities (ranging from 2.1 g·cm–3 to 3.7 g·cm–3). It was demonstrated that the introduction of metal ions conveys better thermal stability than covalent TNAE itself. More importantly, the Zn, Ba and Cu salts exhibited good thermal stability, high density, low sensitivity, and therefore have the potential to be a new class of insensitive, highly energetic explosives for practical applications.

Słowa kluczowe

EN

Ionic compound; 1,1,2,2-tetranitraminoethane; thermal property; safety performance; thermal decomposition kinetics

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2018
• Tom: Vol. 15, no. 3
• Strony: 435--444
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Zhu C.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China
• School of Chemical Engineering, Yunnan Open University, Kunming 650223, China

autor

Meng Z.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Xu Z.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Liu W.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Liu Y.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Shi X.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Liu Y.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

autor

Xie T.

• School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).