Adsorption of Phenol from Water on Natural Minerals

• Autorzy: Puszkarewicz A. , Kaleta J. , Papciak D.

Identyfikatory

DOI

10.12911/22998993/92890

• Języki publikacji: EN

Abstrakty

EN

Phenol and its derivatives (chlorophenol, nitrophenol, methylphenol, cresol etc.) belong to highly toxic contaminants, and their occurrence in industrial and municipal sewage as well as in groundwater carries a high threat to the environment and human health. Elimination of such contaminants is one of the major challenges in solving the global environmental problems. Implementation of pro-ecological methods of water treatment is associated with the use of natural, cheap and unprocessed materials, with the possibility of their repeated use. The article presents the results of the studies on the use of powdery adsorbents for the removal of phenol from aqueous solutions. The following natural minerals were used: attapulgite – Abso'net Superior Special (ASS) and alganite – Abso'net Multisorb (AM). Tests were performed under non-flowing conditions, in series, depending on the type and dose of adsorbents. Tests were conducted on a model solution of phenol with the initial concentration of C₀ = 20 mg /dm³, at the temp. of 20° C. Alganite mineral (AM) proved to be effective in adsorption of phenol. Maximum adsorption capacity P = 0.21 g/g, was obtained for a dose 10 mg/dm³. Almost complete removal of phenol (99.9%) was obtained for a dose of 500 mg/dm³. For natural attapulgite – Abso'net Superior Special (ASS) the maximum adsorption capacity (at a dose 5 mg/dm³) amounted to P = 0.15 g/g. The efficiency of phenol removal at the level 99% was obtained at a dose of 1000 mg/dm³).

Słowa kluczowe

EN

phenol; adsorption; attapulgite; alganite

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2018
• Tom: Vol. 19, nr 6
• Strony: 132--138
• Opis fizyczny: Bibliogr. 18 poz., rys., tab.

Twórcy

autor

Puszkarewicz A.

• Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Department of Water Purification and Protection, Poznańska 2, 35-084 Rzeszów, Poland

autor

Kaleta J.

• Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Department of Water Purification and Protection, Poznańska 2, 35-084 Rzeszów, Poland

autor

Papciak D.

• Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Department of Water Purification and Protection, Poznańska 2, 35-084 Rzeszów, Poland

Bibliografia

• 1. Ahmaruzzaman M. 2008. Adsorption of phenolic compounds on low-cost adsorbents: A review, Advances in Colloid and Interface Science (143), 48–67.
• 2. Alalm M. G. Tawfik A. 2014. Solar photocatalytic degradation of phenol in aqueous solutions using titanium dioxide, International Journal of Chemical, Materials Science and Engineering 8(2), 43–46.
• 3. Al-Khalid T., El-Naas M. H. 2012. Aerobic Biodegradation of Phenols: A Comprehensive Review, Critical Reviews in Environmental Science and Technology 42, 1631–1690.
• 4. Bazrafshan E., Mostafapour F. K., Mansourian H. J. 2013. Phenolic Compounds: Health Effects and Its Removal From Aqueous Environments by Low Cost Adsorbents, Health Scope. 2(2), 65–66.
• 5. Bielicka-Daszkiewicz K. 2008. Removing phenol from wastewaters by oxidation, Przemysł Chemiczny 87(1), 24–32.
• 6. Bizerea Spiridon O., Preda E., Botez A., Pitulice L. 2013. Phenol removal from wastewater by adsorption on zeolitic composite, Environ Sci. Pollut. Res. 20, 6367–6381.
• 7. Dąbrowski A., Podkościelny P., Hubicki Z., Barczak Z., Robens E. 2005. Adsorption of phenols on activated carbon, Wiadomości Chemiczne, 59(7–8), 631–694.
• 8. Ho Y.S., McKay G. 1999. Pseudo-second-order model for sorption processes, Process Biochemistry 34, 451–465.
• 9. Indu Nair C., Jayachandran K., Shashidhar S. 2008. Biodegradation of phenol, African Journal of Biotechnology 7(25), 4951–4958.
• 10. Janusz W. 2000. The electrical double layer parameters for the group 4 metal oxide/electrolyte system, Adsorpt. Sci. Technol.18 (2), 117–134.
• 11. Kaleta J. 2005. Phenols in water medium, Ecology and Technique 73(1), 3–11.
• 12. Liu Q-S., Zheng T., Wang P., Jiang J.P., Li N. 2010. Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers, Chemical Engineering Journal 157, (2–3), 348–356.
• 13. Michałowicz J., Duda W. 2007. Phenols – Sources and Toxicity, Polish J. of Environ. Stud. 16(3), 347–362.
• 14. MKM Holdings Ltd Group, 2014. Catalog card.
• 15. Płaziński W., Rudziński W. 2011. Adsorption kinetics at solid /solution interfaces . The meaning of the pseudo -first – and pseudo -second -order equations, Journal of Polish Chemical Society 65, 11–12, 1055-1067.
• 16. Puszkarewicz A., 2010. Analysis of phenol adsorption on raw and modified carpathian diatomite, Chemistry-Didactics-Ecology-Metrology 15(2), 189–192.
• 17. Rybiński, P., Janowska G. 2013. Flammability and other properties of elastomeric materials and nanomaterials. Part II. Nanocomposites of elastomers with attapulgite, nanosilica, nanofibres and carbon nanotubes, Polimery 7–8, 533–542.
• 18. Viraraghavan T., Alfaro F. M. 1998. Adsorption of phenol from wastewater by peat, fly ash and bentonite, Journal of Hazardous Materials 57, 59–70.

Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).