Three Insensitive Energetic Co-crystals of 1-Nitronaphthalene, with 2,4,6-Trinitrotoluene (TNT), 2,4,6-Trinitrophenol (Picric Acid) and D-Mannitol Hexanitrate (MHN)

• Autorzy: Hong D. , Li Y. , Zhu S. , Zhang L. , Pang C.
• Języki publikacji: EN

Abstrakty

EN

Co-crystallization is proposed as an effective method to alter the physicochemical properties of energetic materials, e.g. density, sensitivity and solubility. As reported in this paper, it was found that 1-nitronaphthalene could form cocrystals with TNT, picric acid and MHN in a 1:1 molecular ratio. The sensitivity and thermal stability of the 1-nitronaphthalene co-crystals was greatly improved compared with that of pure TNT, picric acid and MHN. In addition, the melting points of TNT, picric acid and MHN were lowered through co-crystallization with 1-nitronaphthalene. The electrostatic potential surface of 1-nitronaphthalene, calculated by the DFT method, showed that the electron-rich 1-nitronaphthalene has a tendency to be a proton donor and to co-crystallize with other energetic materials. The structures of the co-crystals of 1-nitronaphthalene with TNT and picric acid were characterized by single crystal X-ray diffraction (SXRD). The 1-nitronaphthalene/MHN co-crystal was studied by powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC) and FTIR.

Słowa kluczowe

EN

co-crystal; insensitive energetic material; crystal structure; explosive properties

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2015
• Tom: Vol. 12, no. 1
• Strony: 47--62
• Opis fizyczny: Bibliogr. 19 poz., rys., tab.

Twórcy

autor

Hong D.

• Nanjing University of Science & Technology, Nanjing 210094, China

autor

Li Y.

• Nanjing University of Science & Technology, Nanjing 210094, China

autor

Zhu S.

• Nanjing University of Science & Technology, Nanjing 210094, China

autor

Zhang L.

• Nanjing University of Science & Technology, Nanjing 210094, China

autor

Pang C.

• Nanjing University of Science & Technology, Nanjing 210094, China

Bibliografia

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