Chlorpyrifos Removal from Aqueous Solutions by Emulsion Liquid Membrane: Stability, Extraction, and Stripping Studies

• Autorzy: Al-Damluji Farrah Emad , Mohammed Ahmed A.

Identyfikatory

DOI

10.12911/22998993/156623

• Języki publikacji: EN

Abstrakty

EN

The current paper focuses on assessing key parameters affecting the extraction of Chlorpyrifos as well as emulsion stability using the emulsion liquid membrane technology. Five parameters affecting the extraction have been studied: homogenizer speed, emulsification time, agitating time, surfactant concentration, and stripping phase concentration taking into consideration the emulsion breaking. Experiments proved that using the resulting optimum values will maximize both extraction and stripping efficiencies (93.8% and 94.7% respectively), while minimizing the emulsion breakage (increasing the stability of emulsion) to 0.73% with no need to employ a carrier agent. A 10 min agitating time, 3% (v/v) Span 80 as a surfactant, 12700-rpm homogenizer speed, 0.25 M HCl as an internal phase concentration, and 5 min emulsification time are chosen to be the optimum parameters’ values. A study of extraction kinetics and estimation of mass transfer coefficient was also accomplished (3.89×10^-9m/s). The conclusions of this work can be extended to the removal of other types of pesticides from water.

Słowa kluczowe

EN

emulsion liquid membrane; chlorpyrifos; emulsion droplet size; stability; mass transfer coefficient; extraction efficiency

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2023
• Tom: Vol. 24, nr 2
• Strony: 101--111
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Al-Damluji Farrah Emad

• Environmental Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq

• https://orcid.org/0000-0003-4670-0769

autor

Mohammed Ahmed A.

• Environmental Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).