Removal of Diesel Oil from Aqueous Solution Using Agro-Waste Activated Carbon Synthesized by Chemical and Microwave Activation

• Autorzy: Taki Estapraq Ameen , Salman Sami D.

Identyfikatory

DOI

10.12911/22998993/185321

• Języki publikacji: EN

Abstrakty

EN

In this article, buckthorn twigs were used to prepare activated carbon preparation by chemical activation with a microwave technique for removing diesel oil from water. buckthorn twigs and activated carbon were characterized by field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX), and Fourier transform infrared (FTIR) analysis techniques. Design-Expert (13 Stat-Ease) with response surface methodology (RSM) was selected to identify and analyze the effects of activated carbon preparation factors. These factors include impregnation ratio, impregnation time, and microwave power with exposure time on the adsorption of methylene blue dye. Likewise, the effects of adsorption factors including; diesel oil concentration, pH, adsorption time, and adsorbent dosage on the removal efficiency were studied. The results showed that the maximum removal efficiency was 96.0823% with the significance of all adsorption factors. The adsorption data were fitted with the adsorption isotherm and kinetics models. The results showed that Freundlich and second-order kinetic models well described diesel oil adsorption, thus elucidating the applicability of multilayer and chemosorption processes. In addition, the thermodynamics parameters of diesel oil adsorption were determined, and the results demonstrated a spontaneous and endothermic adsorption process.

Słowa kluczowe

EN

activated carbon; adsorption; diesel oil; response surface methodology; chemical activation; microwave activation

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2024
• Tom: Vol. 25, nr 5
• Strony: 10--28
• Opis fizyczny: Bibliogr. 68 poz., rys., tab.

Twórcy

autor

Taki Estapraq Ameen

• Biochemical Engineering Department, Al-Khwarizmi College of Engineering, University of Baghdad, Baghdad 47024, Iraq

autor

Salman Sami D.

• Biochemical Engineering Department, Al-Khwarizmi College of Engineering, University of Baghdad, Baghdad 47024, Iraq

• https://orcid.org/0000-0001-7058-7204

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