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Purpose: The results of investigations of properties of PA6 mixed in state the viscoelasticity from polymer about ability of creating of physical bonds was introduced. The polyvinylpyrrolidone about small molecular weight in this aim was applied (10 ± 2,5 thousand). Design/methodology/approach: Within the work some results of chosen properties of PA with different percentage composition with the addition of polyvinylpyrrolidone (PVP) have been presented. In chance of mixing PA6 with PVP forms solution PVP in PA6, to which proper are large intermolecular influence, in this case hydrogen bond. Findings: The functionalactive material was prepared about sharp tuning sorption ability across physical modification polycapramide mixed from bipolar polyvinylpyrrolidone in batch - free state, which be characterizes high ability complex. The properties of the polymer blends depend significantly on the type of the components. That kind of influence manifests especially in the change of the physical properties. Research limitations/implications: The basis condition for reaching the homogeneity, specific structure and the properties of a polymer material is its mutual miscibility of the polymers. Additional agents that make mixing easier are usually applied; they have reactive effect which results in a chemical modification of output polymer along with the change in its chemical structure and the structure of macrochains. In order to achieve this, the polyvinylpyrrolidone has been used. Practical implications: It is possible to foresee, that under the influences large tangent stresses and intermolecular interaction colloidal solution PVP in PA forms about sure homogeneity, after cooling which does not the inversion of winding phases. Large intermolecular influence among PVP and PA6 are unquestionable with regard on their chemical building. The probability of influence of intermolecular influences with this reason results, the leaders to creation of new centres of crystallization near cooling the polymer material. Originality/value: Received however results show thereon that PA with PVP additions create more stable material. Homogeneous material was got about raised elasticity and mechanical durability with perspective of use in textile industry.
Wydawca
Rocznik
Tom
Strony
91--94
Opis fizyczny
Bibliogr. 15 poz., tab., wykr.
Twórcy
autor
- Department of Polymer Processing and Production Management, Technical University, Armii Krajowej Ave. 19c, 42-200 Czestochowa, Poland
autor
- Department of Polymer Processing and Production Management, Technical University, Armii Krajowej Ave. 19c, 42-200 Czestochowa, Poland
autor
- Department of Polymer Processing and Production Management, Technical University, Armii Krajowej Ave. 19c, 42-200 Czestochowa, Poland
Bibliografia
- [1] S.C. Manning, R.B. Moore: Reactive compatibilization of polypropylene and polyamide-6,6 with carboxylated and maleated polypropylene, Polymer Engineering and Science Vol. 39, No 10, 1921 ÷ 1926, 1999.
- [2] J. Campoy, J. M. Arribas, U.M. Zaporta: Crystallization kinetics of polypropylene-polyamide compatibilized blends, Eur. Polym. J., Vol. 31, No 5, 475 ÷ 480, 1995.
- [3] J. Koszkul: Polymeric materials, Publication of Technical University of Czestochowa (in Polish).
- [4] B. Ohlsson, H. Hassander, B.Törnell: Effect of the mixing procedure on the morphology and properties of compatibilized polypropylene/polyamide blends,Polymer Engineering and Science, Vol. 39, No 20, 4715 ÷ 4721, 1998.
- [5] K. Cho, B. H. Lee, K. M. Hawang, H. Lee, S. Choe: Rheological and Mechanical properties in polyethylene blends. Polymer Engineering and Science, Vol. 38, No. 12, str. 1969 – 1975, 1998
- [6] C. Koning, M. V. Duin, Ch. Paagnoulle, R. Jerome: Strategies for compatibilization of polymer blends. Prog. Polym. Sci., Vol. 23, str. 707 - 757, 1998
- [7] B.Jurkowska, B. Jurkowski, Preparation of polymeric compositions, WNT, Warsaw, 1995 (in Polish).
- [8] Y.X. Pang, D.M. Jia, H.J. Hu, D.J. Hourston, M. Song: Effects of a compatibilizing agent on the morphology, interface and mechanical behaviour of polypropylene/ poly (ethylene terephthalate) blends. Polymer, Vol. 41, No. 1, str. 357 - 365, 2000.
- [9] M.F. Champagne, M.A. Huneault, C. Roux, W. Peyrel: Reactive compatibilization of polypropylene/ polyethylene terephthalate blends. Polymer Engineering and Science., Vol. 39, No. 6, str. 976 - 984, 1999.
- [10] C.R. Chiang, F.C. Chang: Polymer blends of polyamide-6 (PA6) and poly(phenylene oxide) (PPO) compatibilized by styrene-maleic anhydride (SMA) copolymer. Polymer 1997, Vol. 38, No. 19, str. 4807 - 4817.
- [11] N. Dharmarajan, S. Datta, G. Ver Strate, L. Ban: Compatibilized polymer blends of isotactic polypropylene and styrene-maleic anhydride copolymer. Polymer, Vol. 36, No. 20, str. 3849 - 3861, 1995.
- [12] A. Ibrahim, M. Dahlan: Thermoplastic natural rubber blends. Prog. Polymer Sci., Vol. 23, str. 665 - 706, 1998.
- [13] I. Kelnar, M. Stephan, L. Jakisch, I. Fortelny: Influence of the additive type and modification on the properties of blends of polyamide-6 with poly(styrene-co-maleic anhydride). Polymer Engineering and Science, Vol. 39, No. 6, str. 985 - 995, 1999.
- [14] G. Spadaro, D. Acierno, C. Dispenza, A. Valenza: Thermal analysis of blends made with polyamide 6 and γ-irradiatedpolyethylenes. Thermochimica Acta No. 269/270, str. 261 - 272, 1995.
- [15] J.T. Yeh, Ch.F. Jyan, S.S. Yang, S. Chou: Influence of compatibilization and viscosity ratio on the barrier and impact properties of blends of a modified polyamide-6 and polyethylene. Polymer Engineering and Science, Vol. 39, No. 10, str. 1952 - 1961, 1999
Typ dokumentu
Bibliografia
Identyfikator YADDA
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