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Warianty tytułu
Języki publikacji
Abstrakty
Active pyrite is one of the most undesirable phenomena in the flotation of porphyry copper ores. Misreported pyrite into copper concentrates decreased the grade and recovery of copper. In this study, the effective parameters on the flotation process including grinding condition and chemical parameters were evaluated in order to decrease the active pyrite recovery by flotation. Firstly, optical microscopic and grinding studies were carried out to determine the optimal particle size and grinding time. The results showed that 43 minutes of grinding is necessary to achieve the optimum liberation degree of 53 µm for flotation. Then, the flotation effective parameters such as pH (7.3, 10, 10.5, 11, 11.5 and 12), collector type (Nascol, Aero 407, Aero 3477 and X231), collector concentration (12 and 25 mg/dm3), depressant concentration (0 and 25 mg/dm3) and frother concentration (0 and 25 mg/dm3) were investigated in a Denver-type laboratory flotation cell with a constant capacity of 2.5 dm3. The results showed that the optimal conditions for chalcopyrite flotation were pH of 11.5, Aero 407 as a collector with concentration of 25 mg/dm3, Dowfroth 250 (DF250) as a frother with concentration of 25 mg/dm3 and Na2SO3 as a depressant with concentration of 25 mg/dm3. The type of collector had greater effect on the chalcopyrite flotation than the other parameters. The recovery and grade of chalcopyrite and pyrite were obtained as 79.95%, 49% and 5.3%, 7.98% using the Aero 407, respectively. Under the optimum conditions, the grade of final concentrate increased from 0.94% to 21.3% with three cleaner stages.
Słowa kluczowe
Rocznik
Tom
Strony
922--933
Opis fizyczny
bibliogr. 29 poz., rys.
Twórcy
autor
- Department of Mining Engineering, Research and Science Campus, Islamic Azad University, Poonak, Hesarak Tehran, Iran
autor
- Amirkabir University of Technology, Tehran, Iran, Amirkabir University of Technology, Tehran, Iran, 1591634311 Tehran, Iran
autor
- Department of Mining Engineering, Research and Science Campus, Islamic Azad University, Poonak, Hesarak Tehran, Iran
Bibliografia
- 1. AGHELI, S., HASSANZADEH, A., HASSAS, B. V., HASANZADEH, M., 2017. Effect of pyrite content of feed and configuration of locked particles on rougher flotation of copper in low and high pyritic ore types. International Journal of Mining Science and Technology.
- 2. AGORHOM, E. A., SKINNER, W., ZANIN, M., 2014. Diethylenetriamine depression of Cu-activated pyrite hydrophobised by xanthate. Minerals Engineering. 57, 36-42.
- 3. BOULTON, A., FORNASIERO, D., RALSTON, J., 2001. Selective depression of pyrite with polyacrylamide polymers. International Journal of Mineral Processing. 61, 13-22.
- 4. CHANDRAPRABHA, M., NATARAJAN, K., MODAK, J. M., 2004. Selective separation of pyrite and chalcopyrite by biomodulation. Colloids and Surfaces B: Biointerfaces. 37, 93-100.
- 5. CHEN, J., LI, Y., CHEN, Y., 2011. Cu–S flotation separation via the combination of sodium humate and lime in a low pH medium. Minerals engineering. 24, 58-63.
- 6. CHEN, X., PENG, Y., BRADSHAW, D., 2013. Effect of regrinding conditions on pyrite flotation in the presence of copper ions. International Journal of Mineral Processing. 125, 129-136.
- 7. DAVENPORT, W. G., KING, M. J., SCHLESINGER, M. E., BISWAS, A. K., 2002. Extractive metallurgy of copper, Elsevier.
- 8. EJTEMAEI, M., NGUYEN, A. V., 2017. Kinetic studies of amyl xanthate adsorption and bubble attachment to Cu-activated sphalerite and pyrite surfaces. Minerals Engineering. 112, 36-42.
- 9. GU, G. H., SUN, X. J., LI, J. H., HU, Y. H., 2010. Influences of collector DLZ on chalcopyrite and pyrite flotation. Journal of Central South University of Technology. 17, 285-288.
- 10. GUO, B., PENG, Y., 2017. The interaction between copper species and pyrite surfaces in copper cyanide solutions. International Journal of Mineral Processing. 158, 85-92.
- 11. HASSANZADEH, A., HASANZADEH, M., 2016. A study on selective flotation in low and high pyritic copper sulphide ores. Separation Science and Technology. 51, 2214-2224.
- 12. HASSANZADEH, A., HASANZADEH, M., 2017. Chalcopyrite and pyrite floatabilities in the presence of sodium sulfide and sodium metabisulfite in a high pyritic copper complex ore. Journal of Dispersion Science and Technology. 38, 782-788.
- 13. HE, S., FORNASIERO, D., SKINNER, W., 2005. Correlation between copper-activated pyrite flotation and surface species: effect of pulp oxidation potential. Minerals engineering. 18, 1208-1213.
- 14. HE, S., SKINNER, W., FORNASIERO, D., 2006. Effect of oxidation potential and zinc sulphate on the separation of chalcopyrite from pyrite. International Journal of Mineral Processing. 80, 169-176.
- 15. HOSEINIAN, F. S., IRANNAJAD, M., NOOSHABADI, A. J., 2015. Ion flotation for removal of Ni (II) and Zn (II) ions from wastewaters. International Journal of Mineral Processing. 143, 131-137.
- 16. HOSEINIAN, F. S., IRANNAJAD, M., SAFARI, M., 2017. Effective factors and kinetics study of zinc ion removal from synthetic wastewater by ion flotation. Separation Science and Technology. 52, 892-902.
- 17. HOSEINIAN, F. S., REZAI, B., KOWSARI, E., 2018. The main factors effecting the efficiency of Zn (II) flotation: Optimum conditions and separation mechanism. Journal of environmental management. 207, 169-179.
- 18. LEPPINEN, J., 1990. FTIR and flotation investigation of the adsorption of ethyl xanthate on activated and non-activated sulfide minerals. International Journal of Mineral Processing. 30, 245-263.
- 19. LI, C., GAO, Z., 2017. Effect of grinding media on the surface property and flotation behavior of scheelite particles. Powder Technology. 322, 386-392.
- 20. LI, Y., CHEN, J., KANG, D., GUO, J., 2012. Depression of pyrite in alkaline medium and its subsequent activation by copper. Minerals Engineering. 26, 64-69.
- 21. MARTIN, C., RAO, S., FINCH, J., LEROUX, M., 1989. Complex sulphide ore processing with pyrite flotation by nitrogen. International Journal of Mineral Processing. 26, 95-110.
- 22. OWUSU, C., ADDAI-MENSAH, J., FORNASIERO, D., ZANIN, M., 2013. Estimating the electrochemical reactivity of pyrite ores-their impact on pulp chemistry and chalcopyrite flotation behaviour. Advanced Powder Technology. 24, 801-809.
- 23. OWUSU, C., ZANIN, M., FORNASIERO, D., ADDAI-MENSAH, J., 2011. Influence of pyrite content on the flotation of chalcopyrite after regrinding with Isamill. Chemeca 2011: Engineering a Better World: Sydney Hilton Hotel, NSW, Australia. 18-21 September 2011, 21.
- 24. PENG, Y., GRANO, S., 2010. Effect of grinding media on the activation of pyrite flotation. Minerals Engineering. 23, 600-605.
- 25. PENG, Y., GRANO, S., FORNASIERO, D., RALSTON, J., 2003. Control of grinding conditions in the flotation of chalcopyrite and its separation from pyrite. International Journal of Mineral Processing. 69, 87-100.
- 26. QIU, Z., LIU, G., LIU, Q., ZHONG, H., ZHANG, M., 2017. Separation of pyrite from chalcopyrite and molybdenite by using selective collector of N-isopropoxypropyl-N′-ethoxycarbonyl thiourea in high salinity water. Minerals Engineering. 100, 93-98.
- 27. SHAKIR, K., ELKAFRAWY, A. F., GHONEIMY, H. F., BEHEIR, S. G. E., REFAAT, M., 2010. Removal of rhodamine B (a basic dye) and thoron (an acidic dye) from dilute aqueous solutions and wastewater simulants by ion flotation. Water research. 44, 1449-1461.
- 28. WANG, Z., QIAN, Y., XU, L. H., DAI, B., XIAO, J. H., FU, K., 2015. Selective chalcopyrite flotation from pyrite with glycerine-xanthate as depressant. Minerals Engineering. 74, 86-90.
- 29. ZHONG, H., HUANG, Z., ZHAO, G., WANG, S., LIU, G., CAO, Z., 2015. The collecting performance and interaction mechanism of sodium diisobutyl dithiophosphinate in sulfide minerals flotation. Journal of Materials Research and Technology. 4, 151-161.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f7c8cff5-619c-41a5-ac7c-88ef779a8603