Separation of Co from Ni and Li from chloride media using polymer inclusion membrane system with thiosalicylate based ionic liquid

• Autorzy: Pospiech Beata

Identyfikatory

DOI

10.37190/ppmp/152997

• Języki publikacji: EN

Abstrakty

EN

The selective removal of cobalt(II) from aqueous chloride solutions containing nickel(II) and lithium(I) was studied. The facilitated transport of metal ions through polymer inclusion membranes (PIMs) with trihexyl(tetradecyl)phosphonium thiosalicylate [PR4][TS] under various conditions was analyzed. In order to optimize the separation process, several factors such as the ion carrier concentration in the membrane as well as of the effect of the concentration of the acids in the source/receiving phases were investigated. The results show that PIM containing 25% CTA as the polymer support, 40% NPOE as the plasticizer and 35% [PR4][TS] allow the selective recovery of more than 90% of cobalt(II) from 6 mol/dm3 hydrochloric acid into 0.5 mol/dm³ sulfuric acid.

Słowa kluczowe

EN

cobalt; lithium; Ionic liquids; polymer inclusion membranes

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 6
• Strony: art. no. 152997
• Opis fizyczny: Bibliogr. 28 poz., rys., wykr.

Twórcy

autor

Pospiech Beata

• Czestochowa University of Technology, Department of Materials Engineering, Czestochowa, Armii Krajowej 19, Poland

• https://orcid.org/0000-0001-6261-2326

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).