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The feasibility of various composts to operate as sorbents for heavy metals (Cu and Zn) removal from wastewater has been evaluated. Three commercial composts obtained from municipal solid wastes (MWS), sludge sewage (SS) and poultry manure (PM) were selected as potential sorbents. Kinetic and equilibrium tests were conducted in order to assess the equilibrium conditions to remove metals from aqueous samples. For all composts, the maximum time necessary to reach the equilibrium was 240 min. The Freundlich and Langmuir isotherm models were found to fit the sorption data. The SS compost proved to be the one with highest removal capability for both assessed metals, while MWS compost showed to be the less suitable for this purpose. These results can be explained in terms of the compost surface properties, namely, with the cation exchange capacity.
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Tom
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57--65
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Bibliogr. 12 poz., tab., rys.
Twórcy
autor
- Departamento de Ambiente, Escola Superior de Tecnologia e Gestão de Viseu, Campus Politécnico de Repeses, 3500-510 Viseu, Portugal
autor
- Departamento de Ambiente, Escola Superior de Tecnologia e Gestão de Viseu, Campus Politécnico de Repeses, 3500-510 Viseu, Portugal
autor
- Departamento de Ambiente, Escola Superior de Tecnologia e Gestão de Viseu, Campus Politécnico de Repeses, 3500-510 Viseu, Portugal
autor
- Departamento de Ambiente, Escola Superior de Tecnologia e Gestão de Viseu, Campus Politécnico de Repeses, 3500-510 Viseu, Portugal
Bibliografia
- [1] Council Directive 99/31/EC, On the landfill of waste, L 182, 1999.
- [2] GRIMES S., TAYLOR G., COOPER J., The availability and binding of heavy metals in compost derived from household waste, J. Chem. Technol. Biot., 1999, 74, 1125.
- [3] WHO, Guidelines for Drinking Water Quality, World Health Organization, Geneva 2006.
- [4] BAILEY S., OLIN T., BRICKA M., ADRIAN D., A review of potentially low-cost sorbents for heavy metals, Water Res., 1998, 33, 2469.
- [5] HO Y., HUANG C., HUANG H., Equilibrium sorption isotherm for metal ions on tree fern, Process Biochem., 2002, 37, 1421.
- [6] VAZ-MOREIRA I., SILVA M.E., MANAIA C.M., NUNES O.C.P., Diversity of bacterial isolates from commercial and homemade composts, Microbial Ecol., 2008, 55, 714.
- [7] THOMPSON W., LEEGE P.,MILLNER P.,WATSON M.E., Test Methods for the Examination of Composts and Composting, The US Composting Council, US Government Printing Office, 2001.
- [8] COONEY D.O., Adsorption design for wastewater treatment, Lewis Publishers, Boca Raton 1998.
- [9] BRÁS I.P.L., Utilização de Casca de Pinheiro como adsorvente para remoção de pentaclorofenol de águas contaminadas, Dissertação de Doutoramento, FEUP, Porto 2005.
- [10] TSENG R., WU F., JUANG R., Liquid-phase adsorption of dyes and phenols using pinewood-based activated carbons, Carbon, 2003, 41, 487.
- [11] GILBERT O., PABLO J., CORTINA J., AYORA C., Sorption studies of Zn(II) and Cu(II) onto vegetal compost used on reactive mixtures for in situ treatment of acid mine drainage, Water Res., 2005, 39, 2827.
- [12] ULMANU M., MARAÑÓN E., FERNADEZ Y., CASTRILLÓN L., ANGER I., DUMITRIU A., Removal of copper and cadmium ions from diluted aqueous solutions by low cost and waste material adsorbents, Water Air Soil Poll., 2003, 142, 357.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-f702b78d-5f32-4c0a-a4c6-6b2e3a696b66