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Assessment of the Effect of Oxygen and Carbon Dioxide Concentrations on Gas Evolution During Heat Treatment of Thermoanthracite Carbon Material

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The processes of the interaction of carbon material (thermoanthracite pouring) with a gas-air mixture in a heat chamber were studied while heating to 800–850°C. The influence of temperature, oxygen and carbon dioxide concentration on the formation efficiency of carbon monoxide, carbon dioxide, hydrogen and methane was determined. A pilot plant was created, which provided heating of the carbon material at the indicated temperatures and regulating the supply of air and carbon dioxide. It was found that a noticeable oxidation of the carbon material in the heat chamber in the presence of oxygen or carbon dioxide occurs at the temperatures above 500°C. Significant concentrations of carbon monoxide were formed at temperatures of 600–800°C. It was shown that when using gas mixtures with an oxygen content of 7–21% minimum concentrations of carbon monoxide are formed at an oxygen content of 14%. At temperatures above 500°C, the formation of hydrogen and methane in gas flows was noted. The methane yield increased with the decreasing oxygen content.
Rocznik
Strony
139--149
Opis fizyczny
Bibliogr. 16 poz., rys., tab.
Twórcy
autor
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu, 37/4, 03056 Kyiv, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu, 37/4, 03056 Kyiv, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu, 37/4, 03056 Kyiv, Ukraine
autor
  • Private Joint Stock Company «Ukrainian Graphite», Pivnichne shose str., 20, 69600 Zaporizhzhia, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu, 37/4, 03056 Kyiv, Ukraine
Bibliografia
  • 1. Rattan G., Kumar M. 2014. Сarbon Monoxide Oxidation Using Cobalt Catalysts: A Short Review. Chemistry & Chemical Technology, 8 (3), 249–260. (in Ukrainian).
  • 2. Karvatskii A., Leleka S., Pedchenko A., Lazariev T. 2016. Numerical analysis of the physical fields in the process of electrode blanks graphitization in the castner furnace. Eastern-European Journal of Enterprise Technologies, 6 (5 (84)), 19–25. (in Ukrainian).
  • 3. Panov E. N., Shilovich I. L., Ivanenko E. I., Buryak V. V. 2012. Thermal and chemical aspects of formation со in the process of baking of electrodes. Eastern-European Journal of Enterprise Technologies, 4 (6 (58)), 15–18. (in Ukrainian).
  • 4. Matkovskij P. E., Sedov I. V., Savchenko V. I., Yarullin R. S. 2011. Tekhnologii polucheniya i pererabotki sintez-gaza. Gazokhimiya, 3–4 (19–20), 77–84. (in Russian).
  • 5. Kovalev V. E., Gusev A. L., Shalimov Yu. N. 2010. Optimizacziya proczessov polucheniya sintez-gaza s poziczij ekonomiki. Alternativnaya energetika i ekologiya, 6 (86), 20–25. (in Russian).
  • 6. Tsyganova E. I., Didenkulova I. I., Shekunova V. M., Aleksandrov Yu. A. 2007. Development of new catalysts for heterogenic catalytic СО to СО2 oxidation on the basis of β-diketonate metals on a synthetic foamed ceramic. Vestnik Nizhegorodskogo universiteta im. N. I. Lobachevskogo, 2, 95–101. (in Russian).
  • 7. Kašpar J., Fornasiero P., Hickey N. 2003. Automotive catalytic converters: current status and some perspectives. Catalysis Today, 77 (4), 419–449.
  • 8. Ivanova, N. D., Ivanov, S. V., Boldyrev, E. I., Sokolskiy, G. V., Makeeva, I. S. 2002. Vysokoeffektivnye oksidno-margancevye katalizatory reakcii okisleniya SO. Zhurnal prikladnoy himii, 75 (9), 1452–1455. (in Russian).
  • 9. Sokolskyi H. V., Ivanov S. V., Ivanova N. D., Boldyrev Ye. I., Lobunets Т. P., Тоmila Т. V. 2012. Doped manganese (IV) oxide in organic compounds destruction and elimination processes from aqueous solutions. Himiya i tekhnologiya vody, 34 (5), 386–397. (in Ukrainian).
  • 10. Dey, S., Dhal, G. C., Prasad, R., Mohan, D. (2017). Effects of Doping on the Performance of CuMnOx Catalyst for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3), 370–383.
  • 11. Sokolskyi H. V., Ivanov S. V., Ivanova N. D., Boldyriev Ye. I., Kobylianska O. V. 2007. Spriamuvannia defektnoho poriadku v produktakh anodnoho okyslennia z bahatokomponentnykh za ionamy metaliv elektrolitiv dlia ekolohichnoho katalizu. AVIA–2007: materialy Mizhnarodnoi naukovotekhnichnoi konferentsiyi, Kyiv, 3 (41.77–41.80). (in Ukrainian).
  • 12. Panov Ye., Gomelia N., Ivanenko O., Vahin A., Leleka S. 2019. Estimation of the еffect of temperature, the concentration of oxygen and catalysts on the oxidation of the thermoanthracite carbon material. Eastern-European Journal of Enterprise Technologies, 2/6 (98), 43–50.
  • 13. Molina A., Mondragon F. 1998. Reactivity of coal gasification with steam and CO2. Fuel, 77 (15), 1831–1839.
  • 14. Karvackiy A. Ya., Leleka S. V., Pulinec I. V., Lazarіev T. V. 2011. Development of burning regulations take into account the dynamics of gas emission of burning blanks. Eastern-European Journal of Enterprise Technologies, 6 (5 (54)), 42–45. (in Ukrainian).
  • 15. Bogacki M., Oleniacz R., Mazur M., Szczygłowski P. 2012. Air pollution emissions during baking of semi-finished graphite products in a tunnel furnace. Environment Protection Engineering, 38 (1), 15–23.
  • 16. Karvatskii A. Ya., Shylovych I. L., Krutous L. V., Kutuzov S. V. 2013. Decrease of CO concentration using installation for carbon monooxide convesion. Eastern-European Journal of Enterprise Technologies, 2 (11 (62)), 38–41. (in Ukrainian).
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f6b33ee1-83a5-49bf-8cbd-24df6bb0338c
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