Elemental analysis as an important tool for fuels and biofuels quality control

• Autorzy: Faber J. , Brodzik K.

Identyfikatory

DOI

10.19206/CE-2017-423

• Języki publikacji: EN

Abstrakty

EN

Article presents normalized analytical methods for determination of elements in fuels and biofuels with emphasis on inductively coupled plasma emission spectrometry (ICP-OES) and their advantages and disadvantages. Analytical procedure applied for determination of 20 elements (Al, B, Ba, Ca, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, P, Pb, Si, Sn, Ti, V and Zn) is described with elements of validation. Broad range of elemental analysis results of fuels (B0, B7 and B10) and pure FAME samples are described. Typical contents of selected elements are presented which allows discussion on the domestic fuel quality in regard to non-standardized parameters and their potential effect on combustion engines performance.

Słowa kluczowe

EN

fuels; biofuels; FAME; elemental composition; ICP-OES

PL

paliwa; biopaliwa; skład elementarny

• Wydawca: Polskie Towarzystwo Naukowe Silników Spalinowych
• Czasopismo: Combustion Engines
• Rocznik: 2017
• Tom: R. 56, nr 4
• Strony: 140--144
• Opis fizyczny: Bibliogr. 26 poz., wykr.

Twórcy

autor

Faber J.

• BOSMAL Automotive Research and Development Institute Ltd.

autor

Brodzik K.

• BOSMAL Automotive Research and Development Institute Ltd.

Bibliografia

• [1] PN-EN 590:2013 Automotive fuels – diesel – requirements and test methods.
• [2] PN-EN 228:2013 Automotive fuels – unleaded petrol – requirements and test methods.
• [3] PN-EN 14214:2012 Fatty acid methyl esters (FAME) for use in diesel engines and heating applications – requirements and test methods.
• [4] ASTM D7111-16 Standard test method for determination of trace elements in middle distillate fuels by inductively coupled plasma atomic emission spectrometry (ICP-AES).
• [5] BARKER, J., COOK, S., RICHARDS, P. Sodium contamination of diesel fuel, its interaction with fuel additives and the resultant effects on filter plugging and injector fouling, SAE International Journal of Fuels and Lubrication. 2013, 6(3), 826-838.
• [6] PN-EN 15837: 2011 Ethanol as a blending component for petrol. Determination of phosphorous, copper and sulfur content. Direct method by inductively coupled plasma optical emission spectrometry (ICP OES).
• [7] PN-EN 14538:2008 Fat and oil derivatives. Fatty acid methyl ester (FAME). Determination of Ca, K, Mg and Na content by optical emission spectral analysis with inductively coupled plasma (ICP OES).
• [8] PN-EN 16136:2015-03 Automotive fuels. Determination of manganese and iron content in unleaded petrol. Inductively coupled plasma optical emission spectrometry (ICP OES) method.
• [9] PN-EN 16294:2013-05 Petroleum products and fat and oil derivatives. Determination of phosphorus content in fatty acid methyl esters (FAME). Optical emission spectral analysis with inductively coupled plasma (ICP OES).
• [10] PN-EN 16476:2014-07 Liquid petroleum products. Determination of sodium, potassium, calcium, phosphorus, copper and zinc contents in diesel fuel. Method via inductively coupled plasma optical emission spectrometry (ICP OES).
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• [12] PN-EN 14107:2004 Fat and oil derivatives. Fatty acid methyl esters (FAME). Determination of phosphorous content by inductively coupled plasma (ICP) emission spectrometry.
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• [16] PN-EN ISO 14596:2009 Petroleum products. Determination of sulfur content. Wavelength-dispersive X-ray fluorescence spectrometry.
• [17] PN-EN ISO 14597:2005 Petroleum products. Determination of vanadium and nickel content. Wavelength-dispersive Xray fluorescence spectrometry.
• [18] PN-EN 15485:2009 Ethanol as a blending component for petrol. Determination of sulfur content. Wavelength dispersive X-ray fluorescence spectrometric method.
• [19] PN-EN ISO 20884:2012 Petroleum products. Determination of sulfur content of automotive fuels. Wavelength-dispersive X-ray fluorescence spectrometry.
• [20] ASTM D 5059-14: Standard test methods for lead in gasoline by X-ray spectroscopy.
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• [22] ASTM D 6445-99: Standard test method for sulfur in gasoline by energy-dispersive X-ray fluorescence spectrometry.
• [23] PN-EN 14108:2004 Fat and oil derivatives. Fatty acid methyl esters (FAME). Determination of sodium content by atomic absorption spectrometry.
• [24] PN-EN 14109:2004 Fat and oil derivatives. Fatty acid methyl esters (FAME). Determination of potassium content by atomic absorption spectrometry.
• [25] PN-EN ISO 20846:2012 Petroleum products. Determination of sulfur content of automotive fuels. Ultraviolet fluorescence method.
• [26] ASTM D 5453-16e: Standard test method for determination of total sulfur in light hydrocarbons, spark ignition engine fuel, diesel engine fuel, and engine oil by ultraviolet fluorescence.