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Gold leching from a Saudi ore by the nonpolluting thiosulfate process

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EN
Abstrakty
EN
In all working Saudi gold mines, ores are treated using the hazardous cyanidation process. Some Saudi gold ores, such as Al-Amar, is known to be refractory to cyanidation. In this work, we have examined the extraction of gold from Al-Amar gold ore by the much environmentally safer and efficient thiosulfate process. The run of mine (ROM) and carbon-in-leach (CIL) feed, that is obtained after separation of copper concentrate from ROM, samples were found to contain 6.5 and 3.6 ppm gold, respectively. The mineralogical microscopic investigations of ROM samples confirmed that fine gold specks were scattered and encapsulated inside sulfide or quartz base minerals. This could explain the expected reason of the difficult leaching of gold by cyanidation. The X-ray diffraction analysis showed that the CIL feed contained quartz, pyrite, sphalerite and chlorite minerals. After detailed leaching studies of CIL feed, almost 70% of gold could be extracted at 0.2 M ammonium thiosulfate and 0.3 M ammonium hydroxide after 24 h. Addition of copper(II) as <0.2 mM only slightly enhanced the gold leaching in the ammoniacal thiosulfate solution. Gold leaching drastically decreased as the concentration of copper(II) increased 0.2 mM due to the degradation of S2O3²¯.
Słowa kluczowe
Rocznik
Strony
59--72
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
  • College of Science, Taif University, P. N. 888,Taif, Saudi Arabia
  • Central Metallurgical R & D Institute, P.O. Box 87, Helwan, Cairo, Egypt
autor
  • College of Science, Taif University, P. N. 888,Taif, Saudi Arabia
  • Ceramic Department, Natural Resources Division, National Research Center, Cairo, Egypt
  • Faculty of Engineering, Taif University, P. N. 888, Taif, Saudi Arabia
  • Faculty of Engineering, Al-Neelain University, Khartoum, Sudan
Bibliografia
  • 1. AL-HOBAIB A. S., AL-JASEEM K. Q., BAIOUMY H. M., AHMED H. A. 2010. Environmental impact assessment inside and around Mahd Adh Dhahab gold mine, Saudi Arabia, Arab. J. Geosci. DOI 10.1007/s12517-010-0259-2.AYLMORE, M.G., 2001. Treatment of a refractory gold-copper sulfide concentrate by copper ammoniacal thiosulfate leaching, Minerals Eng., 14, 6, 615-637.
  • 2. BEAN, S.L., 1997, Thiosulfates. In: Kroschwitz, J.I. (Ed.), Kirk-Othmer Encyclopaedia of Chemical Technology. John Weily & Sons Inc. New York, 51-58.
  • 3. BREUER, P.L. JEFFREY, M.I., 2003. The reduction of copper(II) and the oxidation of thiosulfate and oxysulfur anions in gold leaching solution, Hydrometallurgy 70, 163-173.
  • 4. CHANDRA, I., JEFFREY, M., 2005. A fundamental study of ferric oxalate for dissolving gold in thiosulfate solutions, Hydrometallurgy, 77, 191-201.
  • 5. CHEN, X., 2008, Associated Sulfide Minerals in Thiosulfate Leaching of Gold: Problems and Solutions. A thesis submitted to the Department of Mining Engineering in Conformity with the requirements for the degree of Doctor of Philosophy Queen’s University Kingston, Ontario, Canada.
  • 6. EEC/FDA, 2001. (i) European MSDS: Directive 67/548/EEC. (ii) American MSDS: 29 CFR 1910-1200 (US FDA).
  • 7. HAKIM, H.D., 1982. A new contribution to the study of gold-silver mineralization at Mahd Ad Dahab, Saudi Arabia, Precambrian Research, 16, 4, A22.
  • 8. HUCKERBY, J.A., MOORE J.MCM., DAVID G.R.D., 1982. Mineralization and structure at the Mahd Adh Dahab gold mine, Saudi Arabia, Precambrian Research, 16, 4, A24.
  • 9. JEFFREY, M.I., BREUER, P.L., CHOO, W.L., 2001. A kinetic study that compares the leaching of gold in the cyanide, thiosulfate, and chloride systems, Metallurgical Mater. Transaction B, 32 B, 979.
  • 10. KHANDAKER, N.I., AHMED, M., HARIRI, M.M., AL-OHALI, M.M., GARWAN, M.A., KHAN, K.R., 1997. Microanalytical investigation of gold-bearing rocks from the an Najadi Region in Saudi Arabia, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 130, 654-659.
  • 11. LA BROOY, S.R., LINGE, H.G., WALKER, G.S., 1994. Review of gold extraction from ores, Minerals Eng., 7, 1213-1241.
  • 12. LIU, K.J., YEN, W.T., SHIBAYAMA, A., MIYAZAKI, T., FUJITA, T., 2004. Gold extraction from thiosulfate solution using trioctylmethylammonium chloride, Hydrometallurgy 73, 41-53.
  • 13. MADANI A., HARBI H., 2012. Spectroscopy of the Mineralized Tonalite-diorite Instrusions, Bulghah Gold Mine Area, Saudi Arabia: Effect of Opaques and Alteration Products on Fieldspec Data. Ore Geology Reviews, 44. McNulty, T., 2001. Cyanide substitutes. Mining Magazine, 184, 256-261.
  • 14. NAVARRO, P., ALVAREZ, R., VARGAS, C., AND ALGUACIL, F.J., 2004, On the use of zinc for gold cementation from ammoniacal-thiosulfate solutions. Minerals Eng., 17, 825-831.
  • 15. NAVARRO, P., VARGAS, C., VILLARROEL, A., ALGUACIL, F.J., 2002. On the use of ammoniacal/ammonium thiosulfate for gold extraction from a concentrate. Hydrometallurgy, 65, 37-42.
  • 16. NOHSC, 1999. Approved Criteria for Classifying Hazardous Substances, National Occupational Health and Safety Commission, Sydney, Australia.
  • 17. Rainforest Information Centre, Cyanide ban worldwide. Last updated: July 24, 2005. http://www.rainforestinfo.org.au/gold/Bans.html
  • 18. ROSENHEK, R., Reported incidences of cyanide spills from May 2002 to August 2004 , http://www.mpi.org.au/campaigns/cyanide/cyanide_spills.
  • 19. SALPETEUR I., SABIR H., 1989. Orientation Studies for Gold in the Central Pediplain of Saudi Arabian Shield. Journal of Geochemical Exploration, 34, 189-215.
  • 20. TREMBLAY, L., DESCHENES, G., GHALI, E., MACMULLEN, J., LANOUETTE, M., 1996. Gold recovery from a sulfide bearing gold ore by percolation leaching with thiourea, Intl. J. Min. Proc., 48, 225-244.
  • 21. Wan, R.Y., Le Vier, M., Milles J.D., 1993. Research and development activities for the recovery of gold from non-cyanide solutions. Hydrometallurgy, Fundamentals, Technology and Innovatives, Chapter 27.
  • 22. WEST-SELLS, P.G.,HACKL, R.P., 2005. A novel thiosulfate leach process for the treatment of carbonaceous gold ores. Treatment of Gold Ores, CIM, Alberta, 209-223.
  • 23. ZHANG H., DREISINGER D.B., 2004. The recovery of gold from ammoniacal thiosulfate solutions containing copper using ion exchange resin columns. Hydrometallurgy 72,225-234.ZHANG, H., NICOL, M.J., STAUNTON, W.P., 2005. An electrochemical study of an alternative process for the leaching of gold in thiosulfate solutions. Treatment of Gold Ore, 44th Annual Conference of Metallurgists, Met. Soc, CIM, 243-257.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f5356ba0-a1ef-4be1-8f8c-c16e6d1cbdca
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