Oxygen-containing Tetrazole Salts of 3-Hydrazino-4-amino-1,2,4-triazole (HATr): Nitrogen-rich Ionic Materials with High Thermal Stability

• Autorzy: Wu J.-T. , Zhang J.-G. , Yin X. , Li T. , Wu L. , Zhang Z.-B.

Identyfikatory

DOI

10.22211/cejem/68396

• Języki publikacji: EN

Abstrakty

EN

Energetic salts of doubly-protonated 3-hydrazino-4-amino-1,2,4-triazole (2-4), and mono-protonated 3-hydrazino-4-amino-1,2,4-triazole (5-7), have been prepared in high yields from the corresponding oxygen-containing tetrazoles by (i) reaction of free acids and neutral 3-hydrazino-4-amino-1,2,4-triazole, or (ii) metathesis reactions of 3-hydrazinium-4-amino-1H-1,2,4-triazolium di-chloride with the silver salts of the corresponding oxygen-containing tetrazoles. All of these energetic salts were fully characterized by single-crystal X-ray diffraction, FT-IR and DSC measurements. All of the structures are dominated by extensive hydrogen bonds due to amino groups, hydrazino groups and oxygen atoms in the molecules. These salts exhibit good thermal stability, especially the salt 3-hydrazinium-4-amino-1H-1,2,4-triazolium 1H,1’H-5,5’-bitetrazole-1,1’-diolate (4), which exhibits a measured onset of decomposition temperature of 237 °C. Quantum chemical calculations, carried out using the Gaussian 03 suite of programs and based on the experimental densities were used to calculate the detonation pressures and velocities of all of the salts.

Słowa kluczowe

EN

energetic salts; thermal stability; oxygen-containing tetrazoles; 3-hydrazino-4-amino-1,2,4-triazole

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 1
• Strony: 217--232
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Wu J.-T.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

autor

Zhang J.-G.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

autor

Yin X.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

autor

Li T.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

autor

Wu L.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

autor

Zhang Z.-B.

• State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).