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The vast utilizing of aniline in diverse industrial applications makes it predominantly recognized in the eco-geological system. This work investigated the feasibility of reverse osmosis (RO) and nanofiltration (NF) membranes for the removing of aniline from wastewater. The performance of the TFC spiral wound membrane was examined with different operating parameters. The effect of feed concentration (10–200 mg/l) and operating pressure (1–4 bar) on flux and aniline rejection were explored. Additionally, the fouling test for the adopted membranes was conducted for 20 h using NaOH as cleaning agent. The results revealed that a high rejection ratio at noticeable low operation pressure was achieved by using TFC membranes for both of the RO and NF technologies. The maximum aniline rejection was 99.8% and 93.25% under a 1 bar pressure and the concentration of feed 10 mg/l for the RO and NF membranes, respectively. These rejection ratios correspond to the permissible concentration of aniline in the wastewater. The water flux obtained was 6.33 and 13.5 LMH for reverse osmosis and nanofiltration membranes, respectively. The augmentation of operation pressure resulted in decreasing of rejection and rising of the flux. The fouling test showed a reduction in flux of about 0.92 and 4.35% for RO and NF membranes, respectively, from its initial value before membrane cleaning. The results also demonstrated that the reverse osmosis membrane is better than the nanofiltration membrane in terms of removal efficiency.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
118--127
Opis fizyczny
Bibliogr. 36 poz., rys., tab.
Twórcy
autor
- Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
autor
- Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
autor
- Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
autor
- Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
Bibliografia
- 1. Abbas, A.S., Hussien, S.A. 2017. Equilibrium, Kinetic and Thermodynamic Study of Aniline Adsorption over Prepared ZSM-5 Zeolite. Iraqi J. Chem. Pet. Eng., 18, 47–56.
- 2. Abbas, R.N., Abbas, A.S. 2022. Kinetics and Energetic Parameters Study of Phenol Removal from Aqueous Solution by Electro-Fenton Advanced Oxidation Using Modified Electrodes with PbO2 and Graphene. Iraqi J. Chem. Pet. Eng., 23, 1–8.
- 3. Abdel-Rahman, M.A., Shibl, M.F., El-Demerdash, S.H., El-Nahas, A.M. 2020. Simulated kinetics of the atmospheric removal of aniline during daytime. Chemosphere, 255, 1–12.
- 4. Al-Alawy, A.F., Al-Ameri, M.K. 2017. Treatment of Simulated Oily Wastewater by Ultrafiltration and Nanofiltration Processes. Iraqi J. Chem. Pet. Eng., 18, 71–85.
- 5. Aldahlaki, H.H., Al-Yaqoobi, A.M., Alobaidy, A. 2020. Desalination of Shatt al-Arab water by vacuum membrane distillation (VMD). In: AIP Conference Proceedings.
- 6. Al-Jubouri, S.M., Al-Jendeel, H.A., Rashid, S.A., Al-Batty, S. 2023. Green synthesis of porous carbon cross-linked Y zeolite nanocrystals material and its performance for adsorptive removal of a methyl violet dye from water. Microporous Mesoporous Mater. 356, 112587.
- 7. Alsawaftah, N., Abuwatfa, W., Darwish, N., Husseini, G. 2021. A comprehensive review on membrane fouling: Mathematical modelling, prediction, diagnosis, and mitigation. Water, 13, 1–37.
- 8. Ben-David, A., Bason, S., Jopp, J., Oren, Y., Freger, V. 2006. Partitioning of organic solutes between water and polyamide layer of RO and NF membranes: Correlation to rejection. J. Memb. Sci.
- 9. Benito, A., Penades, A., Lliberia, J.L., Gonzalez-Olmos, R. 2017. Degradation pathways of aniline in aqueous solutions during electro- oxidation with BDD electrodes and UV/H2O2 treatment. Chemosphere, 166, 230–237.
- 10. Cao, X., Qiu, L., Feng, X. 2022. Permeability, solubility, and diffusivity of aniline in poly(ether-b-amide) membranes pertaining to aniline removal from aqueous solutions by pervaporation and sorption. J. Memb. Sci., 642.
- 11. Chaturvedi, N.K. 2022. Comparison of available treatment techniques for hazardous aniline-based organic contaminants. Appl. Water Sci., 12, 1–15.
- 12. Chougradi, A., Zaviska, F., Abed, A., Harmand, J., Jellal, J.E., Heran, M. 2021. Batch reverse osmosis desalination modeling under a time-dependent pressure profile. Membranes (Basel), 11, 1–20.
- 13. Crittenden, J.C., Trussell, R.R., Hand, D.W., Howe, K.J., Tchobanoglous, G. 2012. MWH’s Water Treatment: Principles and Design.
- 14. Cui, Y., Liu, X.-Y., Chung, T.-S., Weber, M., Staudt, C., Maletzko, C. 2016. Removal of organic micro-pollutants (phenol, aniline and nitrobenzene) via forward osmosis (FO) process: Evaluation of FO as an alternative method to reverse osmosis (RO). Water Res., 91, 104–114.
- 15. Dakhil, I.H., Naser, G.F., Ali, A.H. 2021. Assessment Of Modified Rice Husks For Removal Of Aniline In Batch Adsorption Process: Optimization And Isotherm Study. J. Ecol. Eng., 22, 179–189.
- 16. Gherasim, C.V., Mikulášek, P. 2014. Influence of operating variables on the removal of heavy metal ions from aqueous solutions by nanofiltration. Desalination, 343, 67–74.
- 17. Gonsior, M., Schmitt-Kopplin, P., Stavklint, H., Richardson, S.D., Hertkorn, N., Bastviken, D. 2014. Changes in Dissolved Organic Matter during the Treatment Processes of a Drinking Water Plant in Sweden and Formation of Previously Unknown Disinfection Byproducts. Environ. Sci. Technol., 48, 12714–12722.
- 18. Hadadian, Z., Zahmatkesh, S., Ansari, M., Haghighi, A., Moghimipour, E. 2021. Mathematical and experimental modeling of reverse osmosis (RO) process. Korean J. Chem. Eng.
- 19. Han, G., Chung, T.-S. 2014. Robust and High Performance Pressure Retarded Osmosis Hollow Fiber Membranes for Osmotic Power Generation Gang. AIChE J., 60, 1107–1119.
- 20. Hidalgo, A.M., León, G., Gómez, M., Murcia, M.D., Bernal, M.D., Ortega, S. 2014. Polyamide nanofiltration membranes to remove aniline in aqueous solutions. Environ. Technol., 35, 1175–1181.
- 21. Jeong, K., Son, M., Yoon, N., Park, S., Shim, J., Kim, J., Lim, J.L., Cho, K.H. 2021. Modeling and evaluating performance of full-scale reverse osmosis system in industrial water treatment plant. Desalination, 518, 1–15.
- 22. Li, J., Jin, Z., Yu, B. 2010. Isolation and characterization of aniline degradation slightly halophilic bacterium, Erwinia sp. Strain HSA 6. Microbiol. Res., 165, 418–426.
- 23. Li, X., Shao, D., Xu, H., Lv, W., Yan, W. 2016. Fabrication of a stable Ti/TiOxHy/Sb-SnO2 anode for aniline degradation in different electrolytes. Chem. Eng. J., 285, 1–10.
- 24. Lin, Y.-L. 2017. Effects of organic, biological and colloidal fouling on the removal of pharmaceuticals and personal care products by nanofiltration and reverse osmosis membranes. J. Membr. Sci. J., 542, 342–351.
- 25. Maguire-Boyle, S.J., Barron, A.R. 2014. Organic compounds in produced waters from shale gas wells. Environ. Sci. Process. Impacts, 16, 2237–48.
- 26. Majeed, N.S., Mohammed, M.A., 2016. Demulsification of Remaining Waste (Water In Oil Emulsions) After Removal Of Phenol In Emulsion Liquid Membrane Process. J. Eng. 22, 83–102.
- 27. Mohammed, S.A.M., Zouli, N., Al-Dahhan, M. 2018. Removal of phenolic compounds from synthesized produced water by emulsion liquid membrane stabilized by the combination of surfactant and ionic liquid. Desalin. Water Treat., 110, 168–179.
- 28. Osorio, S.C., A, P.M.B., Spruijt, E., Dykstra, J.E., Wal, A. van Der, 2022. Modeling micropollutant removal by nanofiltration and reverse osmosis membranes: considerations and challenges. Water Res., 225, 1–18.
- 29. Ren, Z., Zhu, X., Liu, W., Sun, W., Zhang, W., Liu, J., 2014. Removal of Aniline from Wastewater Using Hollow Fiber Renewal Liquid Membrane. Chinese J. Chem. Eng., 22, 1187–1192.
- 30. Salih, M.H., Al-Alawy, A.F. 2022a. MgCl2 and MgSO4 as draw agents in forward osmosis process for East Baghdad oilfield produced water treatment. Desalin. Water Treat., 256, 80–88.
- 31. Salih, M.H., Al-Alawy, A.F. 2022b. A novel forward osmosis for treatment of high-salinity East Baghdad oilfield produced water as a part of a zero liquid discharge system. Desalin. Water Treat., 248, 18–27.
- 32. Tan, C.X., Wong, V.-L., Yeap, S.P. 2022. Optimization of aniline removal using graphite assisted by response surface methodology and box-behnken design. IOP Conf. Ser. Mater. Sci. Eng., 1257, 1–6.
- 33. Wang, L., Cao, T., Dykstra, J.E., Porada, S., Biesheuvel, P.M., Elimelech, M. 2021. Salt and Water Transport in Reverse Osmosis Membranes: Beyond the Solution-Diffusion Model. Environ. Sci. Technol., 55, 16665–16675.
- 34. Yang, C., Wang, D., Tang, Q., MacRae, J.Y. 2019. Removal of aniline from water by an Fe(II)-nano-Fe3O4@PAC heterogeneous catalyst in a Fenton-like process. Environ. Technol., 1–13.
- 35. Zhang, C., Chen, H., Xue, G., Liu, Y., Chen, S., Jia, C. 2021. A critical review of the aniline transformation fate in azo dye wastewater treatment. J. Clean. Prod., 321, 1–16.
- 36. Zhang, H., Zhou, Y., Guo, S., Wang, Z., Wang, Q., 2022. Mineralization of High-Concentration Aqueous Aniline by Hybrid Process. Water, 630, 1–13.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f3733e7f-8756-4b4c-a626-c445ff46803f