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In the paper the results of measurements of CO2 absorption rate in aqueous potassium carbonate solutions containing cyclohexylamine, diethanolamine, 2-methylaminoethanol and triethylenetetramine as activators have been presented. Enhnancement mass transfer factors as well as reaction rate constants have been determined. Results show that among the tested activators triethylenetetramine and 2-methyl-aminoethanol may be used (instead of diethanolamine) as new promotors in a modified BENFLIELD process.
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Rocznik
Tom
Strony
83--95
Opis fizyczny
Bibliogr. 29 poz., rys.
Twórcy
autor
- Institute of New Chemical Syntheses, Tysiaclecia Panstwa Polskiego 13A, Pulawy 24-110, Poland
autor
- Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland
autor
- Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland
autor
- Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland
Bibliografia
- 1. Barrett P.V.L., 1966. Gas absorption on sieve plate. Ph. D. Thesis, University of Cambridge, Cambridge, 4-53.
- 2. Barth D., Tondre C., Delpuech J-J., 1983. Stopped-flow determination of carbon dioxide diethanolamine reaction mechanism. Kinetics of carbamate formation. Int. J. Chem. Kin., 15, 1147-1160. DOI: 10.1002/kin.550151104.
- 3. Benson H.E., Field J.H., Haynes W.P., 1956. Improved process for CO2 absorption used hot carbonate solutions. Chem. Eng. Prog., 52, 433-438.
- 4. Benson H.E., Field J.H., 1959. US Patent 2886405.
- 5. Bińczak, G., Pohorecki R., Moniuk W., Możeński C., Cwalina J., Mordecka Z., 2013. Study of carbon dioxide absorption in aqueous solutions of potassium carbonate activated with alkanolamines. Przem. Chem., 92, 321- 324 (in Polish).
- 6. Blanc C., Demarais G., 1981. Vitesses de la réaction du CO2 avec la diéthanolamine. Entropie, 102, 53-61.
- 7. Blauwhoff P.M.M., Versteeg G.F., van Swaaij W.P.M., 1983. A study on the reaction between CO2 and alkanolamines in aqueous solutions. Chem. Eng. Sci., 38, 1411-1429. DOI: 10.1016/0009-2509(83)80077-3.
- 8. Cullinane J.T., Rochelle G.T., 2004. Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine. Chem. Eng. Sci., 59, 3619-3630. DOI: 10.1016/j.ces.2004.03.029.
- 9. Cwalina J., Kubicki J., 1977. Effect of selected activators on carbon dioxide absorption in potassium carbonates solution. Chemia Stosowana (Applied Chemistry), 11, 47-57 (in Polish).
- 10. Danckwerts P.V., Sharma M.M., 1966. The absorption of carbon dioxide into solutions of alkalis and amines (with some notes on hydrogen sulphide and carbonyl sulphide). I. Chem. E. Review Series, No 2, The chemical Engineer, CE 244-278.
- 11. Danckwerts P.V., 1970. Gas-liquid reactions. McGraw-Hill Book Company, New York, 17-21.
- 12. Donaldson T.L., Nguyen Y.N., 1980. Carbon dioxide reaction kinetics and transport in aqueous amine membranes. Ind. Eng. Chem. Fundam., 19, 260-266. DOI: 10.1021/i160075a005.
- 13. Jensen M.B., Jorgensen B., Faurholt C., 1954. Reactions between carbon dioxide and aminoalcohols. I. Monoethanoloamine and diethanolamine. Acta Chem. Scand., 8, 1137-1140. DOI: 10.3891/acta.chem.scand.08- 1137.
- 14. Kim Y.E., Choi J.H., Nam, S.C., Yoon Y.L., 2012. CO2 absorption capacity using aqueous potassium carbonate with 2-methylpiperidine and piperazine. J. Ind. Eng. Chem., 18, 105-110. DOI: 10.1016/j.jiec.2011.11.078.
- 15. Laddha S.S., Danckwerts P.V., 1981. Reaction of CO2 with ethanolamines: Kinetics from gas absorption. Chem. Eng. Sci., 36, 479-482. DOI: 10.1016/0009-2509(81)80135-2.
- 16. Leder F., 1971. The absorption of CO2 into chemically reactive solutions at high temperatures. Chem. Eng. Sci., 26, 1381-1390. DOI: 10.1016/0009-2509(71)80058-1.
- 17. Mimura T., Suda T., Iwacki I., Honda A., Kumazawa H., 1998. Kinetics of reaction between carbon dioxide and sterically hindered amines for carbon dioxide recovery from power plant flue gases. Chem. Eng. Comm., 170, 245-260. DOI: 10.1080/00986449808912745.
- 18. Moniuk W., Pohorecki R., 1991. Viscosity and density of sodium and potassium alkaline solutions. Hung. J. Ind. Chem., 19, 175-178.
- 19. Pohorecki R., Wroński S., 1977. Kinetics and thermodynamics of chemical engineering processes. WNT, Warsaw, 482-486 (in Polish).
- 20. Pohorecki R., 1972. Measurements of reaction rate constant for absorption of CO2 into K2CO3/KHCO3 solutions containing KCl and NaOCl. Inż. Chem. 2, 383-402 (in Polish).
- 21. Pohorecki R., Xoan D.T., Moniuk W., 1988. Study of carbon dioxide absorption in aqueous solution of potassium carbonate containing ethylaminoethanols. II. Kinetic relations for 2-ethylaminoethanol. Inż. Chem. Proc., 9, 667-680 (in Polish).
- 22. Pohorecki R., Kucharski E., 1991. Desoprtion with chemical reaction in the system CO2-aqueous solution of potassium carbonate. Chem. Eng. J., 46, 1-7.
- 23. Sada E., Kumazawa H., Butt M.A., 1976. Gas absorption with consecutive chemical reaction: Absorption of carbon dioxide into aqueous amine solutions. Can. J. Chem. Eng., 31, 421-424. DOI: 10.1002/cjce.5450540507.
- 24. Sharma M.M., 1964. Kinetics of gas absorption. Ph. D. Thesis, University of Cambridge, Cambridge.
- 25. Singh P., Niederer J.P.M., Versteeg G.F., 2009. Structure and activity relationships for amine-based CO2 absorbents - II. Chem. Eng. Res. Des., 87, 135-144. DOI: 10.1016/j.cherd.2008.07.014.
- 26. Tseng P.C., Ho W.S., Savage D.W., 1988. Carbon dioxide absorption into promoted carbonate solutions. AIChE J., 34, 922-931. DOI: 10.1002/aic.690340604.
- 27. Vaidya P.D., Kenig E.Y., 2010. Termolecular kinetic model for CO2-alkanolamine reactions: An overview. Chem. Eng. Technol., 33, 1577-1581. DOI: 10.1002/ceat.201000050.
- 28. Versteeg G.F., Oyevaar M.H., 1989. The reaction between CO2 and diethanolamine at 298 K. Chem. Eng. Sci., 44, 1264-1268. DOI: 10.1016/0009-2509(89)87026-5.
- 29. Yih S.-M., Sun C.-C., 1987. Simultaneous absorption of hydrogen sulphide and carbon dioxide into potassium carbonate solution with or without amine promotors. Chem. Eng. J., 34, 65-72.
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Bibliografia
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