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Assessment of Modified Rice Husks for Removal of Aniline in Batch Adsorption Process: Optimization and Isotherm Study

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The present work is aimed at investigating the capability of chemically modified rice husks (MRH) for the reduction of aniline ions from industrial wastewater. The experiments have been conducted to examine the influence of four operating parameters in the batch adsorption technique. The effect of initial concentrations of aniline (10–100) mg•L-1, MRH dose (0.1–1) g/100 ml, pH (3–9), and contact time (10–90) min has been studied. The selected range of operating factors was designed using the response surface method to establish a mathematical model that describes the adsorption process. The optimum parameters were 25 mg•L-1 initial concentration of aniline, 0.68 g MRH dose, 6.6 pH, and 70 min contact time. The point of zero charge was found equal to 6.8. The maximum removal efficiency of 84.97% was found under optimum conditions. The consistency of the mathematical model has been examined and the equilibrium results confirmed with the standard adsorption isotherm models, Langmuir and Freundlich, with a high correlation coefficient.
Słowa kluczowe
Rocznik
Strony
179--189
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
  • Department of Chemical Engineering Department, College of Engineering, Al-Muthanna University, Iraq
  • Department of Chemical Engineering Department, College of Engineering, Al-Muthanna University, Iraq
  • Department of Chemical Engineering Department, College of Engineering, Al-Muthanna University, Iraq
Bibliografia
  • 1. Ahmadi, S., F.K. Mostafapour, and E. Bazrafshan. 2017. Removal of aniline from aqueous solutions by coagulation/flocculation–flotation. Chem Sci Int J 1: 1-10.
  • 2. Ahmed, H., G. Naser, and A. Alkaim. 2018. Treatment of Textile Industries Wastewater by Advance Oxidation Process. J. Eng Appl. Sci.: 1042-1045.
  • 3. Ali, A.H. 2017. Preparation and Characterization of Nanoparticles TiO2 and Its Application for Methylene Blue Dye Degradation under Solar Light. Journal of Global Pharma Technology.
  • 4. Ali, A.H., and I.H. Dakhil. 2012. Photocatalytic decolorization of Methyl Red dye under solar light. Jornal of kerbala university 10.
  • 5. Chang, Y.-P., C.-L. Ren, J.-C. Qu, and X.-G. Chen. 2012. Preparation and characterization of Fe3O4/ graphene nanocomposite and investigation of its adsorption performance for aniline and p-chloroaniline. Applied Surface Science 261: 504-509.
  • 6. Dakhil, I.H. 2013. Adsorption of Chromium (VI) from Aqueous Solutions using Low Cost Adsorbent: Equilibrium and Regeneration Studies. Journal of Engineering 19: 1395-1407.
  • 7. Dakhil, I.H. 2015a. Adsorption of Lead from Industrial Effluents using Rice Husk. International Journal of Engineering and Management Research (IJEMR) 5: 109-116.
  • 8. Dakhil, I.H. 2015b. Effect of Adding Zinc Oxide on Waste Rubber Tire Powder for Increasing Adsorption of Cadmium (II) from Wastewater. The Iraqi Journal For Mechanical And Material Engineering: 416-427.
  • 9. Dakhil, I.H. 2016a. Acomparative Study for Removal of Dyes from Textile Effluents by Low Cost Adsorbents. Mesop. environ. j, Spicial Issue A:1-9.
  • 10. Dakhil, I.H. 2020. Recycling of Agriculture Wastes for Efficient Removal of Methyl Orange Dye Using Batch Adsorption Unit. Page 012186 in IOP Conference Series: Materials Science and Engineering. IOP Publishing.
  • 11. Dakhil, I.H., and A.H. Ali. 2021. Adsorption of methylene blue dye from industrial wastewater using activated carbon prepared from agriculture wastes. Desalination and Water Treatment 216: 372-378.
  • 12. Dakhil, I.H., G.F. Naser, and A.H. Ali. 2021. Response Surface Modeling of Arsenic Adsorption by Modified Spent Tea Leaves. Page 012129 in IOP Conference Series: Materials Science and Engineering. IOP Publishing.
  • 13. Dakhil, L.I.H. 2016b. Removal of Kerosene from Wastewater Using Locally Sawdust. Page 17 in Proceeding of 1st International Conference of Southern Technical University/Iraq.
  • 14. Ferreira, M., M. Pinto, I.C. Neves, A. Fonseca, O. Soares, J. Órfão, M. Pereira, J. Figueiredo, and P. Parpot. 2015. Electrochemical oxidation of aniline at mono and bimetallic electrocatalysts supported on carbon nanotubes. Chemical Engineering Journal 260: 309-315.
  • 15. He, S., G. Chen, H. Xiao, G. Shi, C. Ruan, Y. Ma, H. Dai, B. Yuan, X. Chen, and X. Yang. 2021. Facile preparation of N-doped activated carbon produced from rice husk for CO2 capture. Journal of colloid and interface science 582: 90-101.
  • 16. Jiang, Y., H. Wang, Y. Shang, and K. Yang. 2016. Simultaneous removal of aniline, nitrogen and phosphorus in aniline-containing wastewater treatment by using sequencing batch reactor. Bioresour Technol 207: 422-429.
  • 17. Jiang, Z., and D. Hu. 2019. Molecular mechanism of anionic dyes adsorption on cationized rice husk cellulose from agricultural wastes. Journal of Molecular Liquids 276: 105-114.
  • 18. Khaniabadi, Y.O., R. Heydari, H. Nourmoradi, H. Basiri, and H. Basiri. 2016. Low-cost sorbent for the removal of aniline and methyl orange from liquid-phase: aloe vera leaves wastes. Journal of the Taiwan institute of chemical engineers 68: 90-98.
  • 19. Kolar, P., and H. Jin. 2019. Baseline characterization data for raw rice husk. Data in brief 25:104219.
  • 20. Liu, Q., L. Zhang, P. Hu, and R. Huang. 2015. Removal of aniline from aqueous solutions by activated carbon coated by chitosan. Journal of Water Reuse and Desalination 5: 610-618.
  • 21. Melliti, A., V. Srivastava, J. Kheriji, M. Sillanpää, and B. Hamrouni. 2021. Date Palm Fiber as a novel precursor for porous activated carbon: Optimization, characterization and its application as Tylosin antibiotic scavenger from aqueous solution. Surfaces and Interfaces 24: 101047.
  • 22. N’Diaye, A., C. Boudokhane, M. Kankou, and H. Dhaouadi. 2019. Potential of rice husk ash in atrazine removal. Chemistry and Ecology 35: 678-692.
  • 23. Shao, L., X.Q. Cheng, Y. Liu, S. Quan, J. Ma, S. Z. Zhao, and K.Y. Wang. 2013. Newly developed nanofiltration (NF) composite membranes by interfacial polymerization for Safranin O and Aniline blue removal. Journal of Membrane Science 430: 96-105.
  • 24. Srivastava, V.C., I.D. Mall, and I.M. Mishra. 2006. Characterization of mesoporous rice husk ash (RHA) and adsorption kinetics of metal ions from aqueous solution onto RHA. Journal of hazardous materials 134: 257-267.
  • 25. Taher, I.A., I. Dakhil, Z. Kubba, and A.H. Ali. 2018. Degradation High Concentration of Eosin Yellowish Dye in Heterogeneous Catalyst Solution. Journal of Global Pharma Technology 10: 704-709.
  • 26. Thakur, S., and K. Qanungo. 2020. Removal of aniline blue from aqueous solution using adsorption: A mini review. Materials Today: Proceedings.
  • 27. Zhou, Y., X. Gu, R. Zhang, and J. Lu. 2014. Removal of aniline from aqueous solution using pine sawdust modified with citric acid and β-cyclodextrin. Industrial & Engineering Chemistry Research 53: 887-894.
  • 28. Zhou, Y., R. Zhang, K. Chen, X. Zhao, X. Gu, and J. Lu. 2017. Enhanced adsorption and photo-degradation of bisphenol A by β-cyclodextrin modified pine sawdust in an aquatic environment. Journal of the Taiwan institute of chemical engineers 78: 510-516.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f30a6b95-3348-46b8-a919-8aa726c20674
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