Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
The paper presents the results of research on the preparation and use of cellulose granules as carriers of nutrients in the cultivation of plants. The granules were prepared from a cellulose solution in 1-ethyl-3-methylimidazole acetate followed by coagulation in water and primary alcohols: methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and 1-octanol. Modifications of granules were also carried out by hydrophobization at elevated temperature and by encapsulation in a polylactide solution. As a result of the research, cellulose granules were obtained, which were characterized by different porosity, depending on the type of coagulant used. The morphology of granules surface and cross-sections was examined by means of scanning electron microscopy (SEM). The cellulose granules exhibited good sorption/desorption properties which were investigated by conductometry and UV-Vis spectroscopy. The longest desorption time of NH4NO3 was characteristic of granules obtained as a result of thermal hydrophobization of the surface, which were used in the cultivation of the spider plant. As a result of the research, cellulose granules were obtained which may find potential application in crop production, as long-acting, non-dusting and fully biodegradable fertilizers.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
111--122
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- Institute of Textile Engineering and Polymer Materials, University of Bielsko-Biala, ul. Willowa 2, 43-309 Bielsko-Biala, Poland
autor
- Institute of Textile Engineering and Polymer Materials, University of Bielsko-Biala, ul. Willowa 2, 43-309 Bielsko-Biala, Poland
Bibliografia
- 1. Allard A. S., Renberg L., Neilson A. H. 1996. Absence of 14C02 evolution from 14C-labelled EDTA and DTPA and the sediment/water partition ratio. Chemosphere, 33(4), 577-583.
- 2. Alvarez J. M., Obrador A., Rico M. I. 1996. Effects of chelated zinc, soluble and coated fertilizers, on soil zinc status and zinc nutrition of maize. Communications in Soil Science and Plant Analysis, 27(1-2), 7-19.
- 3. Bloem E., Haneklaus S., Haensch R., Schnug E. 2017. EDTA application on agricultural soils affects microelement uptake of plants. Science of the Total Environment, 577, 166-173.
- 4. Earle M. J., Seddon K. R. 2000. Ionic liquids. Green solvents for the future. Pure and Applied Chemistry, 72(7), 1391-1398.
- 5. Fryczkowska B., Wiechniak K. 2017a. Preparation and properties of cellulose membranes with graphene oxide addition. Polish Journal of Chemical Technology, 19(4), 41-49.
- 6. Fryczkowska B., Wyszomirski M., Puzoń M. 2017b. Obtaining and Application of New Cellulose- and Graphene Oxide-Based Adsorbents for Treatment of Industrial Waste Containing Heavy Metals. Journal of Ecological Engineering, 18(6), 43-52.
- 7. Fryczkowska B., Kowalska M., Biniaś D., Ślusarczyk C., Janicki J., Sarna E., Wyszomirski M. 2017c. Properties and structure of cellulosic membranes obtained from solutions in ionic liquids coagulated in primary alcohols. Autex Research Journal, in press.
- 8. Gagliardi B., Pettigrove V. 2013. Removal of intensive agriculture from the landscape improves aquatic ecosystem health. Agriculture, Ecosystems and Environment, 176, 1-8.
- 9. Gathergood N., Garcia M. T., Scammells P. J. 2004. Biodegradable ionic liquids: Part I. Concept, preliminary targets and evaluation. Green Chemistry, 6(3), 166.
- 10. Klem-Marciniak E., Huculak-Mączka M., Hoffman K., Hoffmann J. 2015. Effect of reaction time to receive fertilizer chelates, 9(2), 15-17.
- 11. Luo J., Cai L., Qi S., Wu J., Gu X. W. S. 2017. Improvement effects of cytokinin on EDTA assisted phytoremediation and the associated environmental risks. Chemosphere, 185, 386-393.
- 12. Luo X., Zeng J., Liu S., Zhang L. 2015. An effective and recyclable adsorbent for the removal of heavy metal ions from aqueous system: Magnetic chitosan/cellulose microspheres. Bioresource Technology, 194, 403-406.
- 13. Meers E., Ruttens A., Hopgood M. J., Samson D., Tack F. M. G. 2005. Comparison of EDTA and EDDS as potential soil amendments for enhanced phytoextraction of heavy metals. Chemosphere, 58(8), 1011-1022.
- 14. Novoselov N. P., Sashina E. S., Kuz’mina O. G., Troshenkova S. V. 2007. Ionic liquids and their use for the dissolution of natural polymers. Russian Journal of General Chemistry, 77(8), 1395-1405.
- 15. Suzuki T., Kono K., Shimomura K., & Minami H. 2014. Preparation of cellulose particles using an ionic liquid. Journal of Colloid and Interface Science, 418, 126-131.
- 16. Trygg J., Fardim P., Gericke M., Mäkilä E., Salonen J. 2013. Physicochemical design of the morphology and ultrastructure of cellulose beads. Carbohydrate Polymers, 93(1), 291-299.
- 17. Voon L. K., Pang S. C., Chin S. F. 2015. Highly porous cellulose beads of controllable sizes derived from regenerated cellulose of printed paper wastes. Materials Letters, 164, 264-266.
- 18. Voon L. K., Pan, S. C., Chin, S. F. 2017a. Optimizing Delivery Characteristics of Curcumin as a Model Drug via Tailoring Mean Diameter Ranges of Cellulose Beads, 2017.
- 19. Voon L. K., Pang S. C., Chin S. F. 2017b. Porous Cellulose Beads Fabricated from Regenerated Cellulose as Potential Drug Delivery Carriers, 2017.
- 20. Wang Y., Fang N., Tong L., Shi, Z. 2017. Source identification and budget evaluation of eroded organic carbon in an intensive agricultural catchment. Agriculture, Ecosystems and Environment, 247(2017), 290-297
- 21. Weerachanchai P., Wong Y., Lim K. H. Tan T. T. Y., Lee, . M. 2014. Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity. ChemPhysChem, 15(16), 3580-3591.
- 22. Wendler F., Todi L. N., Meister F. 2012. Thermostability of imidazolium ionic liquids as direct solvents for cellulose. Thermochimica Acta, 528, 76-84.
- 23. Yildir E., Kolakovic R., Genina N., Trygg J., Gericke M., Hanski, L., Ehlers H., Rantanen J., Tenho M., Vuorela P, Fardim P., Sandler N. 2013. Tailored beads made of dissolved cellulose – Investigation of their drug release properties. International Journal of Pharmaceutics, 456(2), 417-423.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f309da62-6b48-46e2-afa2-f473fe2d6b01