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Dilute sulfuric acid and acidic ionic liquids are pretreatment methods used to selectively hydrolyze hemicellulose from lignocellulosic biomasses. In this work, a comparison between these techniques is carried out by treating sugarcane bagasse both with 1-ethyl-3-methylimidazolium hydrogen sulfate at different ionic-liquid and water contents and with H 2 SO 4 at the same conditions and equivalent ionic liquid molar contents. Results from the use of ionic liquid showed that it was possible to tune the biomass treatment either to achieve high hemicellulose hydrolysis yields of 72.5 mol% to very low furan and glucose co-production, or to obtain furfural at moderate yields of 18.7 mol% under conditions of low water concentration. In comparison to the use of ionic liquid, sulfuric acid pretreatment increased hemicellulose hydrolysis yields by 17%, but the 8.6 mol% furfural yield was also higher, and these yields were obtained at high water concentration conditions. Besides, no such tuning ability of the biomass treatment conditions can be made.
Wydawca
Czasopismo
Rocznik
Tom
Strony
35--53
Opis fizyczny
Bibliogr. 51 poz.
Twórcy
- Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, I.P. Estrada do Paço do Lumiar 22, 1649-038, Lisboa, Portugal
- Permanent address: Departamento de Bioquímica, Instituto de Química Universidade Federal do Rio de Janeiro Av. Athos da Silveira Ramos, 149 Centro de Tecnologia, Cidade Universitária, 21941-909 Rio de Janeiro, Brazil
autor
- Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, I.P. Estrada do Paço do Lumiar 22, 1649-038, Lisboa, Portugal
- Permanent address: CICECO, Aveiro Institute of Materials, Department of Chemistry University of Aveiro, 3810-193 Aveiro, Portugal
autor
- Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, I.P., Estrada do Paço do Lumiar 22, 1649038, Lisboa, Portugal, fax: +351217163636; phone: +351210924600 ext. 4224
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f28d7a97-0cf8-4845-8531-489e9a985738