Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
Natural radioactive elements such as uranium and thorium restrict the use of red mud as building materials or additives, and may cause environmental problems. The distribution features of U and Th in red mud was studied from micro and macro analysis, using EPMA, LA-ICP-MS, and methods of mineralogy and beneficiation. Based on the micro-area scanning analysis, main chemical compositions in red mud, such as Ca, Al, Si, Na, and K are dispersive while Fe and Ti mainly tend to concentrate in granular phases. Based on the in-situ analysis, the distribution of main elements and most trace elements in micro-zone of red mud was homogeneous. In micro-zone area, the variation tendency of thorium content was similar with Y in red mud samples. By means of the methods of mineralogy and beneficiation, red mud samples were separated into different fractions. U and Th tend to be enriched in the low density fraction of the red mud. Th presented a high concentration in the finest particle size fractions of the red mud. Neither U or Th was regularly distributed in various magnetic red mud fractions. Thorium fingerprint peaks were determined in perovskite by EDX under TEM, which is proposed to be one of the radioactivity sources in Bayer red mud.
Słowa kluczowe
Rocznik
Tom
Strony
110--120
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
autor
- Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
autor
- School of Geographic and Environmental Sciences, Guizhou Normal University, Guiyang, 550001, China
autor
- Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
- University of Chinese Academy of Sciences, Beijing 100049, China
autor
- Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
- University of Chinese Academy of Sciences, Beijing 100049, China
Bibliografia
- ADAMS J.A.S., RICHARDSON K.A., 1960a, Radioactivity of aluminum metal, Economic geology, 55, 1060-1063.
- ADAMS J.A.S., RICHARDSON K.A., 1960b, Thorium, uranium and zirconium concentrations in bauxite, Economic geology, 55, 1653-1675.
- AKINCI A., ARTIR R., 2008, Characterization of trace elements and radionuclides and their risk assessment in red mud, Materials Characterization, 59, 417-421.
- GELENCSER A., KOVATS N., TUROCZI B., ROSTASI A., HOFFER A., IMRE K., NYIRO-KOSA I., CSAKBERENYI-MALASICS D., TOTH A., CZITROVSZKY A., NAGY A., NAGY S., ACS A., KOVACS. A., FERINCZ A., HARTYANI Z., POSFAI M., 2011, The red mud accident in Ajka (Hungary): Characterization and potential health effects of fugitive dust, Environmental Science & Technology, 45, 1608-1615.
- GRAFE M., POWER G., KLAUBER C., 2011, Bauxite residue issues: III. Alkalinity and associated chemistry, Hydrometallurgy, 108, 60-79.
- GU H., WANG N., 2013. Leaching of uranium and thorium from red mud using sequential extraction methods, Fresenius Environmental Bulletin, 22(9a), 2763-2769.
- GU H., WANG N., LIU S., 2012, Radiological restrictions of using red mud as building material additive, Waste Management & Research, 30(9): 961-965.
- HUANG Y., WANG N., WAN J., LIN J., LIU B., GU H., LI H., TIAN Y., 2009, Comprehensive utilization of red mud and control techniques of radioactive issues, Bulletin of Mineralogy, Petrology and Geochemistry, 28(2),128-130 (in Chinese).
- HYUN J., ENDOH S., MASUDA K., SHIN H., OHYA H., 2005, Reduction of chlorine in bauxite residue by fine particle separation, International Journal Mineral Processing, 76, 13-20.
- KLAUBER C., GRAFE M., POWER G., 2011, Bauxite residue issues: II. options for residue utilization, Hydrometallurgy, 108, 11-32.
- KOVACS T., SAS Z., SOMLAI J., JOBBAGY V., SZEILER G., 2012, Radiological investigation of the effects of red mud disaster, Radiation Protection Dosimetry, 152, (1-3), 76-79.
- LI Y., WANG J., WANG X., WANG B., LUAN Z., 2011, Feasibility study of iron mineral separation from red mud by high gradient superconducting magnetic separation, Physica C, 471, 91-96.
- LIU W., YANG J., XIAO B., 2009, Review on treatment and utilization of bauxite residues in China, International Journal of Mineral Processing 93, 220-231.
- LIU W., ZHANG X., JIANG W., ZHU X., YANG J., 2011, Study on particle-size separation pretreatment of Bayer red mud, Chinese Journal of Environmental Engineering, 5(4), 921-934 (in Chinese).
- LIU Y., LIN C., WU Y., 2007, Characterization of red mud derived from a combined Bayer Process and bauxite calcination method, Journal of Hazardous Materials, 146, 255-261.
- PARSHAKOV N.S., LAUBENBAKH A.I., SLAVYAGINA I.I. SKOSYREVA L.N., 1978, Features of distribution of radioactive elements in bauxite-bearing deposits, International Geology Review, 20(11), 1319-1329.
- PARSHAKOV N.S., MENYAYLOV A.A., LAUBENBAKH A.I., SKOSYREVA L.N., SLAVYAGINA I.I., 1977, Radioactivity and mineral composition of bauxites. International Geology Review, 19(6), 737-740.
- RUYTERS S., MERTENS J., VASSILIEVA E., DEHANDSCHUTTER B., POFFIJN A., SMOLDERS E., 2011, The red mud accident in Ajka (Hungary): Plant toxicity and trace metal bioavailability in red mud contaminated soil, Environmental Science & Technology 45: 1616-1622.
- SAMAL S., ROY A.K., BANDHOPADDYAY A., 2013, Proposal, resources and utilization of red mud in India-a review, International Journal of Mineral Processing, 118, 43-55.
- SOMLAI J., JOBBAGY V., KOVACS J., TARJAN S., KOVACS T., 2008, Radiological aspects of the usability of red mud as building material additive, Journal of Hazardous Materials, 150, 541-545.
- ZHANG L., ZHANG H., GUO W., TIAN Y., 2014, Removal of malachite green and crystal violet cationic dyes from aqueous solution using activated sintering process red mud, Applied Clay Science, 93-94, 85-93.
- ZHAO Y., WANG J., LIU C., LUAN Z., WEI N., LIANG Z., 2009, Characterization and risk assessment of red mud derived from the sintering alumina process, Fresenius Environmental Bulletin, 18(6), 989-993.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f289dfe2-6f8d-49a7-b5a5-18bb787829f8