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The Relationship between the Monomer Chain Length and the Electro-Optical Properties of Polymer Dispersed Liquid Crystals

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Five polymers dispersed liquid crystalline (LC) films were fabricated using photo-polymerizable monomers with different lengths of carbon chains. These LC films have shown different electro-optical (EO) properties. Through their SEM pictures, the relationship between the linear electro-optical effect and the mesh size of the polymer network was explored. With the increase of number of photo-polymerizable monomers, the mesh size of the polymer network would become larger. So the liquid crystal molecules would be easily oriented in the electric field and therefore, the threshold voltage and saturation voltage would decrease. The open state response times were also reduced and the off state response times would be extended. The DFT simulations have shown principal role of the ground state dipole moments in the observed electro-optical efficiency.
Twórcy
autor
  • Chinese Academy of Sciences, Technical Institute of Physics and Chemistry, Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Beijing 100190, P. R. China.
autor
  • Czestochowa University of Technology, Institute of Electronic and Control System, 17 Armii Krajowej Av., 42-200 Czestochowa, Poland
autor
  • Chinese Academy of Sciences, Technical Institute of Physics and Chemistry, Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Beijing 100190, P. R. China.
autor
  • Chinese Academy of Sciences, Technical Institute of Physics and Chemistry, Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Beijing 100190, P. R. China.
  • Military University Technology, Electronics Department, 2 Kaliskiego Str, Warsaw 00-908, Poland
autor
  • Czestochowa University of Technology, Institute of Material Science Engineering, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland
autor
  • Czestochowa University of Technology, Institute of Electronic and Control System, 17 Armii Krajowej Av., 42-200 Czestochowa, Poland
Bibliografia
  • [1] M. Silva, J. Sotomayor, J. Figueirinhas, Effect of an additive on the permanent memory effect of polymer dispersed liquid crystal films, J. Chem. Technol. Biotechnol. 90, 1565-1569 (2015).
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  • [3] M. Kim, K. Park, S. Seok, J. Ok, H. Jung, J. Choe, D. Kim, Fabrication of microcapsules for dye-doped polymerdispersed liquid crystal-based smart windows, ACS Appl. Mater. Interfaces. 7 (32), 17904-17909 (2015).
  • [4] P. Kumar, S. Kang, S. Lee, K. Raina, Analysis of dichroic dyedoped polymer-dispersed liquid crystal materials for display devices, Thin Solid Films, 520 (1), 457-463 (2011).
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  • [6] J. Liu, W. Gao, I. V. Kityk, X. Liu, Z. Zhen, Optimization of polycyclic electron-donors based on julolidinyl structure in push-pull chromophores for second order NLO effects, Dyes Pigment. 122, 74-84 (2015).
  • [7] J. Liu, G. Xu, F. Liu, I. Kityk, X. Liu, Z. Zhen, Recent advances in polymer electro-optic modulators, RSC Adv. 5, 15784-15794 (2015).
  • [8] S. Myoung, E. Kim, Y. Jung, Electrooptical properties and microstructure of polymer-dispersed liquid crystal doped with various reinforcing materials, Thin Solid Films, 519 (5), 1558-1562 (2010).
  • [9] K.J. Yang, D.J. Yoon, Electro-optical characteristics of dyedoped polymer dispersed liquid crystals, J. Ind. Eng. Chem. 17 (3), 543-548 (2011).
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  • [12] S. T. Wu, A. Y.-G. Fuh, Color dispersion in two-dimensional phase array based on polymer-dispersed liquid crystal film, Opt. Commun. 281 (6), 1732-1738 (2008).
  • [13] K. R. Moon, S. Y. Bae, B. K. Kim, Electro-optical properties of low viscosity driven holographic polymer dispersed liquid crystals, Opt. Mater. 42, 160-166 (2015)
  • [14] B. Yan, J. He, R. Bao, X. Bai, S. Wang, Y. Zeng, Y. Wang, Modification of electro-optical properties of polymer dispersed liquid crystal films by iniferter polymerization, Eur. Polym. J. 44 (3), 952-958 (2008).
  • [15] Y. Kim, D. Jung, S. Jeong, K. Kim, W. Choi, Y. Seo, Optical properties and optimized conditions for polymer dispersed liquid crystal containing UV curable polymer and nematic liquid crystal, Curr. Appl. Phys. 15(3), 292-297 (2015).
  • [16] I. V. Kityk, M. Makowska-Janusik, E. Gondek, L. Krzeminska, A. Daniel, K.J. Plucinski, S. Benet, B. Sahraoui, Optical poling of oligoether acrylate photopolymers doped by stilbenebenzoate derivative chromophores. J. Phys.: Condens. Matter 16 (3), 231-239 (2004).
Uwagi
EN
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f2049480-9340-4741-9cbd-fad4ff0e25a1
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