Removal of zinc, cadmium and nickel from mining waste leachate using walnut shells

• Autorzy: Ayala Julia , Fernandez Begona

Identyfikatory

DOI

10.5277/epe190210

• Języki publikacji: EN

Abstrakty

EN

The removal of heavy metals from aqueous solutions using walnut shells was investigated. The effects of pH, contact time, initial metal concentration, adsorbent concentration, and co-ions were studied in synthetic solutions. Metal uptake was found to be dependent on the initial pH of the solution; the removal rate increased upon increasing pH, showing the highest affinity at pH 5–7. The amount of metal removed improved with increasing initial concentration. Increasing adsorbent dosage enhanced removal efficiency, but reduced the amount absorbed per unit mass of walnut shells. The presence of co-ions suppressed the uptake of heavy metals, divalent ions having a more negative effect than monovalentions. The adsorption of Zn, Cd and Ni onto walnut shells was found to fit Langmuir and Freundlich isotherms. The results obtained in the tests with mining waste leachate showed the potential use of walnut shells for the removal of heavy metals.

Słowa kluczowe

EN

metal ions; adsorption; biosorption; adsorbent; kinetics; copper

PL

jony metali; adsorpcja; biosorpcja; adsorbent; kinetyka; miedź

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2019
• Tom: Vol. 45, nr 2
• Strony: 141--158
• Opis fizyczny: Bibliogr. 25 poz., tab., rys.

Twórcy

autor

Ayala Julia

• Laboratorio de Metalurgia, Escuela de Minas Energía y Materiales, Universidad de Oviedo, Independencia 13, 33004 Oviedo, Spain

autor

Fernandez Begona

• Laboratorio de Metalurgia, Escuela de Minas Energía y Materiales, Universidad de Oviedo, Independencia 13, 33004 Oviedo, Spain

Bibliografia

• [1] OWSIANIAK M., HOLM P.E., FANTKE P., CHRISTIANSEN K.S., BORGGAARD O.K., HAUSCHILD M.Z., Assessing comparative terrestrial ecotoxicity of Cd, Co, Cu, Ni, Pb, and Zn. The influence of aging and emission source, Environ. Pollut., 2015, 206, 400.
• [2] AYALA J., FERNÁNDEZ B., Bayer electrofilter fines as potential Se(VI) adsorbents, JOM, 2015, 67, 2727.
• [3] COMAN V., ROBOTIN B., ILEA P., Nickel recovery/removal from industrial wastes. A review, Res. Cons. Rec., 2013, 73, 229.
• [4] FU F., WANG Q., Removal of heavy metal ions from wastewaters. A review, J. Environ. Manage., 2011, 92, 407.
• [5] LI L., TAKAHASHI N., KANEKO K., SHIMIZU T., TAKARADA T., A novel method for nickel recovery and phosphorus removal from spent electroless nickel-plating solution, Sep. Purif. Techn., 2015, 147, 237.
• [6] AYALA J., FERNANDEZ B., Treatment of mining waste leachate by the adsorption process using spent coffee grounds, Environ. Techn., 2018, 15, 1.
• [7] AZOUAOU N., SADAOUI Z., DJAAFRI A., MOKADDEM H., Adsorption of cadmium from aqueous solution onto untreated coffee grounds: Equilibrium, kinetics and thermodynamics, J. Hazard. Mater., 2010, 184, 126.
• [8] BAYO J., Kinetic studies for Cd(II) biosorption from treated urban effluents by native grapefruit biomass (Citrus paradisi L.). The competitive effect of Pb(II), Cu(II) and Ni(II), Chem. Eng. J., 2012, 191, 278.
• [9] KUMAR P.S., RAMALINGAM S., SATHYASELVABALA V., KIRUPHA S.D., MURUGESANAND A., SIVANESAN S.,
• Removal of cadmium(II) from aqueous solution by agricultural waste cashew nut shell, Korean J. Chem. Eng., 2012, 29, 6, 756.
• [10] SAADAT S., KARIMI-JASHNI A., Optimization of Pb adsorption onto modified walnut shell using factorial design and simplex methodologies, Chem. Eng. J., 2011, 173, 743.
• [11] MARTÍNEZ NIETO L., BEN DRISS S., HODAIFA G., FAUR C., RODRÍGUEZ S., GIMÉNEZ J.A., OCHANDO J., Adsorption of iron on crude olive stones, Ind. Crops Prod., 2010, 32, 467.
• [12] KAMAR F.H., NECHIFOR A.C., ALWAN G.M., CRACIUN M.E., Comparative removal of lead, copper and cadmiun ions from wastewater in single and ternary batch biosorption systems onto dry walnut shells, Rev. Chim. (Bucharest), 2015, 66 (8), 1083.
• [13] GALA A., SANAK-RYDLEWSKA S., A comparison of Pb2+ sorption from aqueous solutions on walnut shells and plum stones, Polish J. Environ. Stud., 2011, 20 (4), 877.
• [14] SAHOO P.K., TRIPATHY S., PANIGRAHI M.K., EQUEENUDDIN S.M., Evaluation of the use of an alkali modified fly ash as a potential adsorbent for the removal of metals from acid mine drainage, Appl. Water Sci., 2013, 3, 567.
• [15] SRIVASTAVA V.C., MALL I.D., MISHRA I.M., Equilibrium modeling of ternary adsorption of metal ions onto rice husk ash, J. Chem. Eng. Data, 2009, 54, (3), 705.
• [16] Food and Agricultural Organization (FAO), http://faostat.fao.org/site/339/default.aspx (accessed on 22.12.16).
• [17] LAVEDRINE F., RAVEL A., VILLET A., DUCROS V., ALARY J., Mineral composition of two walnut cultivars originating in France and California, Food Chem., 2000, 68 (3), 347.
• [18] ÖZCAN M.-M., İMAN C., ARSLA D., Physicochemical properties, fatty acid and mineral content of some walnuts (Juglans regia L.) types, Agric. Sci., 2010, 1 (2), 62.
• [19] SOCRATES G., Infrared and Raman characteristic group frequencies. Tables and Charts, 3rd Ed., Wiley, Chichester 2001.
• [20] IQBAL M., SAEED A., ZAFAR S.I., FTIR spectrophotometry, kinetics and adsorption isotherms modeling, ion exchange, and EDX analysis for understanding the mechanism of Cd2+ and Pb2+ removal by mango peel waste, J. Hazard. Mater., 2009, 164, 161.
• [21] KAMAR F.H., NECHIFOR A.C., Removal of copper ions from industrial wastewater using walnut shells as a natural adsorbent material, U.P.B. Bull. Series B, 2015, 77 (3),141.
• [22] PARCK D., YUN Y., PARCK J.M., The past, present and future trends of biosorption, Biotechnol. Bioproc. Eng., 2010, 15, 86.
• [23] SAEED A., IQBAL M., AKHTAR M.W., Removal and recovery of lead(II) from single and multimetal (Cd, Cu, Ni, Zn) solutions by crop milling waste (black gram husk), J. Hazard. Mater., 2005, 117, 65.
• [24] FEIZI M., JALALI M., Removal of heavy metals aqueous solutions using sunflower, potato, canola and walnut shell residues, J. Taiwan Inst. Chem. Eng., 2015, 54, 125.
• [25] CRINI G., BADOT P.M., Sorption processes and pollution. Conventional and non-conventional sorbents for pollutant removal from wastemasters, Presses universitaires de Franche-Comté, Besançon 2010

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).