Study of methylene blue adsorption by modified kaolinite by dimethyl sulfoxide

• Autorzy: Lellou Salima , Kadi Samir , Guemou Laid , Schott Jacques , Benhebal Hadj

Identyfikatory

DOI

10.2478/eces-2020-0015

• Języki publikacji: EN

Abstrakty

EN

Tamazert kaolin was modified with dimethyl sulfoxide (DMSO). The starting material and resulting from the intercalation were characterized by X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy (SEM). Intercalation caused considerable changes in our clay by increasing the basal spacing to 11.22 Å, an intercalation rate of 98 %. The adsorption of methylene blue was studied as a function of pH, contact time, temperature, dye concentrations and adsorbents. Kinetic data have been adequately described by the pseudo-second order and intraparticle scattering model. The adsorption isotherm is in good agreement with the Redlich-Peterson model. A change in thermodynamic values (ΔH°, ΔS° and ΔG°) was observed after intercalation. Adsorption became non-spontaneous exothermic and ordered.

Słowa kluczowe

EN

kaolin; DMSO; intercalation; adsorption; methylene blue

PL

kaolin; DMSO; interkalacja; adsorpcja; błękit metylenowy

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. S
• Rocznik: 2020
• Tom: Vol. 27, nr 2
• Strony: 225--239
• Opis fizyczny: Bibliogr. 38 poz., rys., tab., wykr.

Twórcy

autor

Lellou Salima

• Laboratory of Plant Physiology Applied to Above-Soil Culture, Department of Nature and Life Sciences, University of Tiaret BP 78 Zaaroura, Tiaret 14000, Algeria, phone [phone], fax [phone]

autor

Kadi Samir

• Laboratory of Plant Physiology Applied to Above-Soil Culture, Department of Nature and Life Sciences, University of Tiaret BP 78 Zaaroura, Tiaret 14000, Algeria, phone [phone], fax [phone]

autor

Guemou Laid

• Improvement and Enhancement of Local Animal Production Laboratory, Department of Nature and Life Sciences, University Centre Ahmed Ben Yahia Al-wancharissi, Tissemsilt 38000, Algeria, phone [phone], fax [phone]

autor

Schott Jacques

• Geosciences Environment Laboratory Toulouse (GET), CNRS-IRD-OMP - Toulouse University, 14, Avenue Edouard Belin, 31400 Toulouse, France, phone [phone], fax [phone]

autor

Benhebal Hadj

• Department of Material Sciences, University of Tiaret BP 78 Zaaroura, Tiaret 14000, Algeria, phone [phone], fax [phone]

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Uwagi

PL

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).