Anthropogenic changes of CO2, CH4, N2O, CFCI3, CF2Cl2, CCl2FCClF2, CHCl3, CH3CCI3, CCI4, SF6 and SF5CF3 mixing ratios in the atmosphere over southern Poland

• Autorzy: Różański K. , Nęcki J. , Chmura Ł. , Śliwka I. , Zimnoch M. , Bielewski J. , Gałkowski M. , Bartyzel J. , Rosiek J.

Identyfikatory

DOI

10.7306/gq.1163

• Języki publikacji: EN

Abstrakty

EN

An overview of long-term, sysiematic observations of trace gas composition of the atmosphere over southern Poland is given. Three major greenhouse gases (CO₂, CH₄, N₂O) and selected halocarbons (freons F-11, F-12 and F-113; chloroform; 1,1,1-trichloroetane; carbon tetrachloride; sulphur hexafluoride and trifluoromethyl sulphur pentafuoride) were monitored. Measurements were performed at two locations of contrasting characteristics: (1) the high-mountain site Kasprowy Wierch, High Tatras, representing atmospheric conditions relatively free of local influences, and (2) two sites located in the Kraków agglomeration, representing a typical urban atmosphere. The data available for Kraków and Kasprowy Wierch were compared with the Mace Head data, representing a marine regional background. The impact of continental sources for some of the measured gases is clearly seen in the Kraków and Kasprowy Wierch records. The mean offset between CH₄ concentrations recorded at Kasprowy Wierch and at Mace Head for the period 1998-2012 is 20.7 ppb and stems from continental emissions of this gas originating mainly from anthropogenic activities (leaks of natural gas distribution networks, landfills, livestock). For N₂O, a similar offset of ca. 1 ppb for the period 2009-2012 was observed. Although the long-term concentration trends of selected halogenated compounds measured in Kraków coincide in general with the respective trends in Mace Head data, the Kraków records contain numerous spikes and periods of enhanced concentrations, reflecting the impact of local sources of these compounds. The impact of a legislative framework enforced in Poland in July 2002, regulating the trade, storage and disposal of ozone-depleting substances, is visible in the Kraków record of halogenated compounds.

Słowa kluczowe

EN

atmosphere; monitoring; greenhouse gases; halogenated compounds

• Wydawca: Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
• Czasopismo: Geological Quarterly
• Rocznik: 2014
• Tom: Vol. 58, No. 4
• Strony: 673–--684
• Opis fizyczny: Bibliogr. 31 poz., rys., tab., wykr.

Twórcy

autor

Różański K.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Nęcki J.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Chmura Ł.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland
• Institute of Meteorology and Water Management, National Research Institute, IMGW-PIB, Branch of Kraków, Piotra Borowego 14, 30-215 Kraków, Poland

autor

Śliwka I.

• The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Kraków, Poland

autor

Zimnoch M.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Bielewski J.

autor

Gałkowski M.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Bartyzel J.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Rosiek J.

• 1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Al. Mickiewicza 30, 30-059 Kraków, Poland

Bibliografia

• 1. Bousquet, P., Ringeval, B., Pison, I., Dlugokencky, E.J., Brunke, E.-G., Carouge, C., Chevalier, F., Fortems-Cheiney, A., Frankenberg, C., Hauglustaine, D.A., Krummel, P.B., Langenfelds, R.L., Ramonet, M., Schmidt, M., Steele, L.P., Szopa, S., Yver, C., Viovy, N., Ciais, P., 2011. Source attribution of the changes in atmospheric methane for 2006-2008. At- mospheric Chemistry and Physics, 11:3689-3700.
• 2. Busenberg, E., Plummer, L.N., 2008. Dating groundwater with trifuoromethyl sulfurpentafluoride (SF5CF3), sulfur hexafluoride (SF6), CF3Cl (CFC-13) and CF2Cl2 (CFC-12). Water Research, 44: W02431, 1-18.
• 3. Ciais, P., Reichstein, M., Viovy, N., Granier, A., Ogée, J., Allard, V., Aubinet, M., Buchmann, N., Bernhofer, Chr., Carrara, A., Chevalier, F., Noblet, N., de, Friend, A.D., Friedlingstein, P., Grünwald, T., Heinesch, B., Keronen, P., Knohl, A., Krinner, G., Loustau, D., Manca, G., Matteucci, G., Miglietta, F., Ourcival, J.M., Papale, D., Pilegaaed, K., Rambal, S., Seufert, G., Soussana, J.F., Sanz, M.J., Schulze, E.D., Vesala, T., Valentini, R., 2005. Europe-wide reducton in primary productivity caused by the heat and drought in 2003. Nature, 437: 529-533.
• 4. Chmura, L., Rozanski, K., Necki, J.M., Zimnoch, M., Korus, A., Pycia, M., 2008. Atmospheric concentration of carbon dioxide in Southern Poland: comparison of mountain and urban environments. Polish Journal of Environmental Studies, 17: 859-867.
• 5. Cunnold, D.M. Weiss, R.F., Prinn, R.G., Hartley, D.E., Simmonds, P.G., Fraser, P.J., Miller, B.R., Alyea, F.N., Porter, L., 1997. GAGE/AGAGE measurements indicating reduction in global emissions of CCl3F and CCl2F2 in 1992-1994. Journal of Geophysical Research, 102: 1259-1269.
• 6. Erboy, Y., Smethie, W.M., 2012. Trifluoromethyl sulfur pentafluoride and its relatonship to sufur hexafluoride and chloroiuorocarbon-12 in the atmosphere near the New York City metropolitan area. Atmospheric Environment, 35:135-138.
• 7. Fang, X., Wu, J., Su, S., Han, J., Wu, y., Shi, Y., Wan, D., Sun, X., Zhang, J., Hu, J., 2012. Esimates of major anthropogenic halocarbon emissions from China based on interspecies correlations. Atmospheric Environment, 62: 26-33.
• 8. Fraser, P., Cunnold, D., Alyea, F., Weiss, R.F., Prinn, R.G., Simmonds, P., Miller, B.R., Langenfelds, R., 1996. Lifetime and emission estimates of 1,1,2-trichlorotrifluorethane (CFC-113) from daily global background observations June 1982-June 1994. Journal of Geophysical Research, 101: 12,585-12,599.
• 9. Global Carbon Proj ect, 2012. Carbon budget and trends 2012. www.globalcarbonproject.org/carbonbudget
• 10. GLOBALVIEW-CH4, 2009. Cooperative Atmospheric Data Integration Project - Methane. CD-ROM, NOAA ESRL, Boulder, Colorado. Also available on Internet via anonymous FTP to aftp.cmdl.noaa.gov, Path: products/globalview/ch4], 2009
• 11. GLOBALVIEW-CO2, 2013. Global Atmospheric Data Integration Project. 2013, updated annually. Multi-laboratory compilation of synchronized and gap-filled atmospheric carbon dioxide records for the period 1979-2012 (obspack_co2_1_GLO- BALVIEW-CO2_2013_v1.0.4_2013-12-23). Compiled by NOAA Global Monitoring Division: Boulder, Colorado, U.S.A. Data product accessed at http://dx.doi.org/10.3334/OBSPACK/1002
• 12. Jiang, X., Ku W.L., Shia, R.-L., Li, Q., Elkins, J.W., Prinn, R.G., Yuk, L., Yung, Y.L., 2007. Seasonal cycle of N2O: analysis of data. Global Biogeochemical Cycles, 21: GB1006, 1-12.
• 13. Lasa, J., Śliwka, I., 2001. Stability examination of the response of a GC equipped with an ECD working in a constant current mode. Chemia Analityczna, 46: 421-431.
• 14. Levin, I., Ciais, P., Lengenfelds, R., Schmidt, M., Ramonet, M., Sidorov, K., Tchebakova, N., Gloor, M., Heimann, M., Schulze, E.-D., Vygodskaya, N.N., Shibistova, O., Lloyd, J., 2002. Three years of trace gas observations over the Euro-Siberian domain derived from aircraft sampling - a concerted action. Tellus, B54: 696-712.
• 15. Levin, I., Naegler, T., Heinz, R., Osusko, D., Cuevas, E., Engel, A., Ilmberger, J., Lengenfelds, R.L., Neininger, B., Rohden, C., v., Steele, L.P., Weller, R., Worthy, D.E., Zimov, S.A., 2010. The global SF6 source inferred from long-term high precision atmospheric measurements and its comparison with emission inventories. Atmospheric Chemistry and Physics, 10:2655-2662.
• 16. Maione, M., Giostra, U., Arduini, J., Furlani, F., Graziosi, F., Vullo, E., lo, Bonasoni, P., 2013. Ten years of continuous observations of stratospheric ozone depleting gases at Monte Cimone (Italy) - comments on the effectiveness of the Montreal Protocol from a regional perspective. Science of the Total Environment, 445: 155-164.
• 17. Necki, J.M., Schmidt, M., Rozanski, K., Zimnoch, M., Korus, A., Lasa, J., Graul, R., Levin, I., 2003. Six-year record of atmospheric carbon dioxide and methane at a high-altitude mountain site in Poland. Tellus, 55B: 94-104.
• 18. Nęcki, J.M., Chmura, L., Zimnoch, M., Różański, K., 2013. Impact of emissions on atmospheric composition at Kasprowy Wierch based on results of carbon monoxi de and carbon dioxide monitoring. Polish Journal of Environmental Studies, 22: 1119-1127.
• 19. O'Doherty, S., Cunnold, D., Sturrock, D.A., Ryall, D., Derwent, R.G., Wang, H.J., Simmonds, P., Fraser, P.J., Weiss, R.F., Salameh, P., Miller, B.R., Prinn, R.G., 2001. In-situ chloroform measurements at AGAGE atmospheric research stations from 1994-1998. Journal of Geophysical Research, 106: 20,429-20,444.
• 20. Prinn, R.G., Cunnold, D.M., Rasmussen, R., Simmonds, P.G., Alyea, F.N., Crawford, A., Fraser, P.J., Rosen, R., 1990. Atmospheric emissions and trends of nitrous oxide deduced from ten years of ALE-GAGE data. Journal of Geophysical Research, 95: 18,369-18,385.
• 21. Prinn, R.G., Weiss, R.F., Fraser, P.J., Simmonds, P.G., Cunnold, D.M., Alyea, F.N., O'Doherty, S., Salameh, P., Miller, B.R., Huang, J., Wang, R.H.J., Hartley, D.E., Harth, C., Steele, L.P., Sturrock, G., Midgley, P.M., McCulloch, A., 2000. A history of chemically and radiatively important gases in air deduced from ALE/GAGE/AGAGE. Journal of Geophysical Research, 105: 17,751-17,792.
• 22. Quéré, C., le, Andres, R.J., Boden, T., Conway, T., Houghton, R.A., House, J.I., Marland, G., Peters, G.P., Werf, G.R., van der, Ahlström, A., Andrew, R.M., Bopp, L., Canadell, J.G., Ciais, P., Doney, S.C., Enright, C., Friedlingstein, P., Huntingford, C., Jain, A.K., Jourdain, C., Kato, E., Keeling, R., Klein Goldewijk, K., Levis, S., Levy, P., Lomas, M., Poulter, B., Raupach, M.R., Schwinger, J., Sitch, S., Stocker, B.D., Viovy, N., Zaehle, S., Zeng, N., 2013. The global carbon budget 1959-2011. Earth System Science Data, 5: 165-185.
• 23. Reimann, S., Ali ster, J.M., Simmonds, P.G., Cunnold, D.M., Wang, R.H.J., Li, J., McCulloch, A., Prinn, R.G., Huang, J., Weiss, R.F., Fraser, P.J., O'Doherty, S., Greally, B.B., Stemmler, K., Hill M., Folini, D., 2005. Low European methyl chloroform emissions inferred from long-term atmospheric measurements. Nature, 433: 506-509.
• 24. Rosiek, J., Lasa, J., Śliwka, I., Różański, K., 2007. Application of GC and modulated ECD for the determination of SF5CF3 mixing ratios in the atmosphere. Chemia Analityczna, 52: 235-242.
• 25. Simmonds, P.G., Derwent R.G., McCulloch A., O'Doherty S., Gaudry A., 1998. Long-term trends in concentration of halocarbons and radiatively active trace gases in Atlantic and European air masses monitored at Mace Head, Ireland from 1987-1994. Atmospheric Environment, 30: 4041-4063.
• 26. Simmonds, P.G., Cunnold, D.M., Weiss R.F., Prinn R.G., Fraser P.J., McCulloch A., Alyea F.N., O'Doherty S., 1998. Global trends and emissions of CCl4 from in-situ background observations from July 1978 to June 1996. Journal of Geophysical Research, 103: 16,017-16,027.
• 27. Śliwka, I., Lasa, J., 2002. A method for improvement of precision and accuracy in concentration measurements based on external standard. Chemia Analityczna, 47: 1-17.
• 28. Śliwka, I., Lasa, J., Bielewski, J., Grombik, I., Limanówka, D., Rosiek, J., 2010. Long-term measurements of CFCs and SF6 concentration in air. Polish Journal of Environmental Studies, 19: 811-815.
• 29. Sturges, W.T., Wallington, T.J., Hurley, M.D., Shine, K.P., Sihra, K., Engel, A., Oram, D.E., Penkett, S.A., Mulvaney, R., Brenninkmeijer, C.A.M., 2000. A potent greenhouse gas identified in the atmosphere: SF5CF3. Science, 289: 611-613.
• 30. Sturges, W.T., Oram, D.E., Laube, J.C., Reeves, C.E., Newland, M.J., Hogan, C., Martinerie, P., Witrant, E. Brenninkmeijer, C.A.M., Schuck, T.J., Fraser, P.J., 2012. Emissions halted of the potent greenhouse gas SF5CF3. Atmospheric Chemistry and Phys ics, 12: 3653-3658.
• 31. Thoning, K.W., Tans, P.P., Komhyr, W.D., 1989. Atmospheric carbon dioxide at Mauna Loa Observatory 2. Analysis of the NOAA GMCC data, 1974-1985. Journal of Geophysical Research, 94: 8549-8565.