Inclusion complexation of 2-aminopyrimidines with β-cyclodextrin, physico-chemical and nuclear magnetic spectroscopic studies

• Autorzy: Celin T S , Nagarajan S

Identyfikatory

DOI

10.2478/s13536-013-0158-9

• Języki publikacji: EN

Abstrakty

EN

Inclusion complexation of 2-aminopyrimidines with b-cyclodextrin was studied in the solid state by infrared spectroscopy (IR), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The aminopyrimidine-b-CD complexes were also investigated in a solution by nuclear magnetic resonance spectral techniques (1H-NMR and 13C-NMR). Qualitative modifications in the position and number of peaks or bands obtained from spectral methods as well as thermal analysis indicated the inclusion.

Słowa kluczowe

EN

inclusion; cyclodextrin; aminopyrimidine

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2014
• Tom: Vol. 32, No. 1
• Strony: 39--44
• Opis fizyczny: Bibliogr. 19 poz., rys., tab.

Twórcy

autor

Celin T S

• Department of Chemistry and Research Centre, Scott Christian College (autonomous), Nagercoil-629 003, India

autor

Nagarajan S

• Department of Chemistry, Annamalai University, Annamalainagar-608 002, India

Bibliografia

• [1] D’SOUZA V.T., LIPKOWITZ K.B., Chem. Rev, 98 (1998), 1741.
• [2] SZEJTLI J., Chem. Rev., 98 (1998), 1743.
• [3] BENDER M., KOMIYAMA M., Cyclodextrin Chemistry, Springer Verlag, New York, 1978.
• [4] FRENCH D., Adv. Carbohydr. Chem., 12 (1957), 189.
• [5] FREUDENBERG K., CRAMER F., PLIENINGER H., Ger. Patent 895, 1953.
• [6] SHIRAISHI Y., TOSHIMA N., KAWAMURA T., MIHORI H., SHIRAI H., HIRAI H., J. Mol. Catal., 139 (1999), 149.
• [7] NEPOGODIEV S., STODDART J., Chem. Rev., 98 (1998), 1959.
• [8] AMABILINO D.B., STODDART J.F., Chem. Rev., 95 (1995), 2725.
• [9] SHIGEKAWA H., MIYAKE K., SUMAOKA J., HARADA A., KOMIYAMA M., J. Am. Chem. Soc., 122 (2000), 5411.
• [10] KAWAGUCHI Y., HARADA A., Org. Lett., 21 (2000), 353.
• [11] IIJIMA T., UEMURA T., TSUZUK S., KOMIYAMA J., J. Polym. Sci. Pol. Phys., 16 (1978), 793.
• [12] REKHARSKY M., INOUE Y., J. Am. Chem. Soc., 122 (2000), 4418.
• [13] RAVI P., DIVAKAR S., J. Macromol. Sci. A, 32 (1995), 1061.
• [14] BUGLER J., SOMMERDIJK N., VISSER A., HOEK A., NOLTE R., ENGBERSEN J., REINHOUDT D., J. Am.Chem. Soc., 121 (1999), 28.
• [15] MONFLIER E., TILLOY S., MELIET C., MORTREUX A., OURMENTIN S., LANDY D., SURPATEANU G., New J. Chem., 23 (1999), 469.
• [16] CHANDRASEKARAN S., NAGARAJAN S., IL Farmaco, 60 (2005), 279.
• [17] MEENAKSHISUNDARAM S.P., GOPALAKRISHNAN M., NAGARAJAN S., SARATHI N., Catal. Commun., 8 (2007), 713.
• [18] BALASANKAR T., NAGARAJAN S., Heterocycl. Commun., 10 (2004), 465.
• [19] INGARSAL N., SARAVANAN G., AMUTHA P., NAGARAJAN S., Eur. J. Med. Chem., 42 (2007), 5 – 7, 517.