Photochemical Degradation of Sulfadiazine

• Autorzy: Lemańska-Malinowska N. , Felis E. , Surmacz-Górska J.

Warianty tytułu

PL

Fotochemiczny rozkład sulfadiazyny

• Języki publikacji: EN

Abstrakty

EN

The photochemical degradation of the sulfadiazine (SDZ) was studied. The photochemical processes used in degradation of SDZ were UV and UV/H2O2. In the experiments hydrogen peroxide was applied at different concentrations: 10 mg/dm3 (2.94*10-4 M), 100 mg/dm3 (2.94*10-3 M), 1 g/dm3 (2.94*10-2 M) and 10 g/dm3 (2.94*10-1 M). The concentrations of SDZ during the experiment were controlled by means of HPLC. The best results of sulfadiazine degradation, the 100% removal of the compound, were achieved by photolysis using UV radiation in the presence of 100 mg H2O2/dm3 (2.94*10-3 M). The determined rate constant of sulfadiazine reaction with hydroxyl radicals k_OH was equal 1.98*109 M-1s-1.

PL

W ramach niniejszego eksperymentu przeprowadzono fotochemiczny rozkład sulfadiazyny (SDZ). Rozkład sulfadiazyny był realizowany z wykorzystaniem procesów UV oraz UV/H2O2. W badaniach użyto nadtlenek wodoru w następujących stężeniach: 10 mg/dm3 (2.94*10-4 M), 100 mg/dm3 (2.94*10-3 M), 1 g/dm3 (2.94*10-2 M) oraz 10 g/dm3 (2.94*10-1 M). Zmiany stężenia SDZ obserwowano przy wykorzystaniu HPLC. Najlepsze rezultaty rozkładu sulfadiazyny, 100% usunięcie badanej substancji, zaobserwowano w procesie fotolizy przy obecności 100 mg H2O2/dm3 (2.94*10-3 M). Stała szybkości reakcji sulfadiazyny z rodnikami hydroksylowymi k_OH wynosiła 1.98*109 M-1s-1.

Słowa kluczowe

EN

sulfadiazine; high performance liquid chromatography (HPLC); HPLC; advanced oxidation processes (AOPs); AOPs; kOH

PL

sulfadiazyna; HPLC; proces fotolizy; proces UV

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2013
• Tom: Vol. 39, no. 3
• Strony: 79--91
• Opis fizyczny: Bibliogr. 36 poz., tab., wykr.

Twórcy

autor

Lemańska-Malinowska N.

• Silesian University of Technology, Environmental Biotechnology Department, Akademicka 2, 44-100 Gliwice, Poland

autor

Felis E.

• Silesian University of Technology, Environmental Biotechnology Department, Akademicka 2, 44-100 Gliwice, Poland

autor

Surmacz-Górska J.

• Silesian University of Technology, Environmental Biotechnology Department, Akademicka 2, 44-100 Gliwice, Poland

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