Extractive detoxification of hydrolysates with simultaneous formation of deep eutectic solvents

• Autorzy: Makoś-Chełstowska Patrycja , Słupek Edyta , Kucharska Karolina , Gębicki Jacek

Identyfikatory

DOI

10.24425/cpe.2023.146720

• Konferencja: 24th Polish Conference of Chemical and Process Engineering, 13-16 June 2023, Szczecin, Poland. Guest editor: Prof. Rafał Rakoczy and 8th European Process Intensification Conference, 31.05–2.06.2023, Warsaw, Poland
• Języki publikacji: EN

Abstrakty

EN

The hydrolysis of lignocellulosic biomass results in the production of so-called fermentation inhibitors, which reduce the efficiency of biohydrogen production. To increase the efficiency of hydrogen production, inhibitors should be removed from aqueous hydrolysate solutions before the fermentation process. This paper presents a new approach to the detoxification of hydrolysates with the simultaneous formation of in-situ deep eutectic solvents (DES). In the first stage of the study, inhibitors were identified in the real hydrolysate samples using high-performance liquid chromatography (HPLC). Four monoterpenes were tested for their potential to extract furfural (FF) with simultaneous DES formation. An optimization process of the most important parameters affecting the extraction process and DES formation (Thymol:FF) was conducted using the Central Composite Design (CCD) model. A temperature of 40 ◦C, pH of 7, mHBD : mHYD ratio of 2:1, and time of 50 min were selected as the optimal conditions. These results indicate the high efficiency of FF removal from hydrolysates (92.1–94.6%) in a one-step process. Meanwhile, the structural properties of the formed DES measured by Fourier-transform infrared spectroscopy (FT-IR) and Nuclear magnetic resonance spectroscopy (NMR) differed only slightly from those of the DES composed of pure substances (Furfural and Thymol).

Słowa kluczowe

EN

hydrolysates; detoxification; deep eutectic solvents; furfural; fermentation

PL

hydrolizaty; detoksykacja; rozpuszczalniki głęboko eutektyczne; fermentacja

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering : New Frontiers
• Rocznik: 2023
• Tom: Vol. 44, nr 3
• Strony: art. no. e18
• Opis fizyczny: Bibliogr. 37 poz., rys., tab., wykr.

Twórcy

autor

Makoś-Chełstowska Patrycja

• Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineering and Chemical Technology, 80-233 Gdansk, Poland

• https://orcid.org/0000-0002-1160-2790

autor

Słupek Edyta

• Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineering and Chemical Technology, 80-233 Gdansk, Poland

• https://orcid.org/0000-0002-4076-1176

autor

Kucharska Karolina

• Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineering and Chemical Technology, 80-233 Gdansk, Poland

• https://orcid.org/0000-0001-5826-922X

autor

Gębicki Jacek

• Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineering and Chemical Technology, 80-233 Gdansk, Poland

• https://orcid.org/0000-0002-4786-8363

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025)