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Effects of deformation rates on mechanical properties of PP/SEBS blends

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The goal of this study is to examine effects of tensile deformation rates ( e) on tensile properties of polypropylene/poly(styrene-b-ethylene-co-butylene-b-styrene) copolymer (PP/SEBS) blends and to determine suitable S for accurate and reliable evaluation of mechanical properties of the blends in accordance with the results of Izod impact tests. Design/methodology/approach: PP/SEBS blends containing ϕ<sub>e</sub>= 0, 2.5, 5 and 10 volume % of SEBS thermoplastic elastomer were compounded using a twin-screw extruder, and then moulded with an injection moulding machine. Morphology of PP/SEBS blends were analysed by scanning electron microscopy (SEM). Mechanical properties of the blends were investigated tensile and Izod impact tests. Tensile deformation rates έ<sub.1</sub>=1.67 ms<sup>-1</sup> and έ<sub>2</sub>=16.67 ms<sup>-1</sup> were used to determine ultimate tensile properties. Findings: Morphological analyses revealed that SEBS elastomer particles were well-dispersed throughout PP matrix in irregular forms with a narrow size distribution and evidenced a two-phase system formation. At low deformation rate(έ<sub.1</sub>), PP and PP/SEBS blends did not fail during tensile tests despite maximum tensile deformation, ε<sub>max</sub> = 600%; therefore, tensile toughness (U<sub>T</sub>), stress and strain values at break point (σ<sub>b</sub> and ε<sub>b</sub>) of the blends were not determined. However, at high deformation rate ( έ<sub>2</sub>), all specimens tested in this study failed; a slight decrease in ob of the blends with SEBS elastomer was associated with a significant increase in ε<sub>b</sub> and U<sub>T</sub>. Strain-rate-sensitivity of PP/SEBS blends was promoted with SEBS elastomer. Research limitations/implications: Mechanical properties determined through high-velocity tests are beyond the scope of this study. Practical implications: έ of tensile testing machines is readily adjustable, while ε<sub>max</sub> of tensile testing machines is limited. Consequently, in order to evaluate reliably mechanical properties of ductile materials like PP/SEBS blends, e must be so high that ductile materials can fail during tensile tests. Originality/value: Tensile testing at high strain rate έ<sub>2</sub> was concluded to be more suitable for evaluation of mechanical properties of PP/SEBS blends than that of at low strain rate έ<sub>1</sub>.
Rocznik
Strony
26--33
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
  • Department of Materials, Institute of Pure and Applied Sciences, Marmara University, Göztepe Campus, 34722, Kadıköy-İstanbul, Turkey
autor
  • Department of Materials, Technical Education Faculty, Marmara University, Göztepe Campus, 34722 Kadıköy-İstanbul, Turkey
autor
  • Department of Materials and Metallurgy, Chemistry-Metallurgy Faculty, İstanbul Technical University, Ayazağa Campus, 34469 Maslak-İstanbul, Turkey
Bibliografia
  • [1] A.K. Gupta, S.N. Purwar, Crystallization of PP in PP/SEBS blends and its correlation with tensile properties, Journal of Applied Polymer Science 29/5 (1984) 1595-1609.
  • [2] A.K. Gupta, S.N. Purwar, Tensile yield behavior of PP/SEBS blends, Journal of Applied Polymer Science 29/5 (1984) 3513-3531.
  • [3] A.K. Gupta, S.N. Purwar, Studies on binary and ternary blends of polypropylene with SEBS, PS, and HDPE. I. Melt rheological behavior, Journal of Applied Polymer Science 30/5 (1985) 1777-1798.
  • [4] A.K. Gupta, S.N. Purwar, Studies on binary and ternary blends of polypropylene with SEBS, PS, and HDPE. II. Tensile and impact properties, Journal of Applied Polymer Science 30/5 (1985) 1799-1814.
  • [5] A.K. Gupta, S.N. Purwar, Dynamic mechanical and impact properties of PP/SEBS blend, Journal of Applied Polymer Science 31/2 (1986) 535-551.
  • [6] S. Setz, F. Stricker, J. Kressler, T. Duschek, R. Mülhaupt, Morphology and mechanical properties of blends of isotactic or syndiotactic polypropylene with SEBS block copolymers, Journal of Applied Polymer Science 59/7 (1996) 1117-1128.
  • [7] F. Stricker, Y. Thomann, R. Mülhaupt, Influence of rubber particle size on mechanical properties of polypropylene-SEBS blends, Journal of Applied Polymer Science 68/12 (1998) 1891-1901.
  • [8] A. Bassani, L.A. Pessan, E. Hage, Toughening of polypropylene with styrene/ethylene-butylene/styrene triblock copolymer: Effects of mixing condition and elastomer content, Journal of Applied Polymer Science 82/9 (2001) 2185-2193.
  • [9] F.O.M.S. Abreu, M.M.C. Forte, S.A. Liberman, SBS and SEBS block copolymers as impact modifiers for polypropylene compounds, Journal of Applied Polymer Science 95/2 (2005) 254-263.
  • [10] F. Ohashi, T. Hiroe, K. Fujiwara, H. Matsuo, Strain-rate and temperature effects on the deformation of polypropylene and its simulation under monotonic compression and bending, Polymer Engineering and Science 42/5 (2002) 1046-1055.
  • [11] R. Gensler, C.J.G. Plummer, C. Grein, H.-H. Kausch, Influence of the loading rate on the fracture resistance of isotactic polypropylene and impact modified isotactic polypropylene, Polymer 41/10 (2000) 3809-3819.
  • [12] H. Mae, Effects of local strain rate and micro-porous morphology on tensile mechanical properties in PP/EPR blend syntactic foams, Material Science and Engineering A 496 (2008) 455-463.
  • [13] A. van der Wal, R.J. Gaymans, Polypropylene-rubber blends: 3. The effect of the test speed on the fracture behaviour Polymer 40/22 (1999) 6045-6055.
  • [14] W. Jiang, S.C. Tjong, R.K.Y. Li, Brittle-tough transition in PP/EPDM blends: effects of interparticle distance and tensile deformation speed, Polymer 41/9 (2000) 3479-3482.
  • [15] H.H. Le, Th Lüpke, T. Pham, H.-J. Radusch, Time dependent deformation behavior of thermoplastic elastomers, Polymer 44/16 (2000) 4589-4597.
  • [16] C.D. Han, Multiphase flow in polymer processing, Academic Press, London, 1981.
  • [17] H. Eyring, Viscosity, plasticity, and diffusion as examples of absolute reaction rates, Journal of Chemical Physics 4/4 (1936) 283-291.
  • [18] K.A. Brown, R. Brooks, N.A. Warrior, The static and high strain rate behaviour of a commingled E-glass /Polypropylene woven fabric composite, Composite Science and Technology 70 (2010) 272-283.
  • [19] J. Ingram, Y. Zhou, S. Jeelani, T. Lacy, M.F. Horstemeyer, Effect of strain rate on tensile behavior of polypropylene and carbon nanofiber filled polypropylene, Material Science and Engineering A 489 (2008) 99-106.
  • [20] G.C. McGrath, Fracture and toughening in fibre reinforced polymer composites, in: rubber toughened engineering plastics, Chapman & Hall, 1994, 61.
  • [21] C.B. Bucknall, Toughened plastics, Applied Science Publishers Ltd, England, 1977.
  • [22] J. Wu, D. Yu, C.-M. Chan, J. Kim, Y.-W. Mai, Effect of fiber pretreatment condition on the interfacial strength and mechanical properties of wood fiber/PP composites, Journal of Applied Polymer Science 76/7 (2000) 1000-1010.
  • [23] S.C. Tjong, S.-A. Xu, Y.-W. Mai, Impact-specific essential work of fracture of maleic anhydride-compatibilized polypropylene/elastomer blends and their composites, Journal of Polymer Science B 40/17 (2002) 1881-1892.
  • [24] W.Y. Tam, T.Y. Cheung, R.K.Y. Li, Impact properties of glass fibre/impact modifier/polypropylene hybrid composites, Journal of Materials Science 35/6 (2000) 1525-1533.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-eeb633a9-2e03-43dc-9ebd-963060f6f5d0
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