Modified Ginstling–Brounshtein model for wet precipitation synthesis of hydroxyapatite: analytical and experimental study

• Autorzy: Krauklis A. E. , Kreicbergs I. , Dreyer I.

Identyfikatory

DOI

10.5277/ABB-01196-2018-02

• Języki publikacji: EN

Abstrakty

EN

Hydroxyapatite is the main mineral component in bones and teeth, thus being an important material in bone tissue engineering, e.g., for replacement and elimination of defects. Hydroxyapatite is widely used in real-life applications due to excellent biocompatibility and bioactivity. Wet precipitation synthesis of hydroxyapatite is limited by diffusivity. Hence, choice of a diffusion model becomes critical. The purpose of this work is three-fold. It experimentally validates the use of Ginstling–Brounshtein model for hydroxyapatite synthesis. It determines the effect of Ca(OH)2 concentration on the kinetics and reports a modified model to account for this phenomenon. It reports obtained kinetic constants that describe hydroxyapatite synthesis. Methods: Particle size was determined using scanning electron microscopy and digital microscopy. Conversion kinetics were monitored using powder X-ray diffraction. Results: Experimental validation was provided. Furthermore, the process was found dependent on the calcium hydroxide concentration and the model was modified to account for this phenomenon. Kinetic constants describing the synthesis of hydroxyapatite were obtained and reported. Conclusions: The model was well consistent with the experimental data and can be used for describing synthesis of hydroxyapatite for various suspension concentrations.

Słowa kluczowe

EN

biomaterials; hydroxyapatite; synthesis; diffusion; Ginstling–Brounshtein model

PL

biomateriały; synteza; dyfuzja; model Ginstling-Brounshteina

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Acta of Bioengineering and Biomechanics
• Rocznik: 2018
• Tom: Vol. 20, no. 4
• Strony: 47--57
• Opis fizyczny: Bibliogr. 25 poz., rys., tab., wykr.

Twórcy

autor

Krauklis A. E.

• Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology, Trondheim, Norway
• Institute of General Chemical Engineering, Riga Technical University, Riga, Latvia

autor

Kreicbergs I.

• Institute of General Chemical Engineering, Riga Technical University, Riga, Latvia

autor

Dreyer I.

• Institute of General Chemical Engineering, Riga Technical University, Riga, Latvia

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).