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During last years protection of the environment is one of the important problems that should be solved by modern technology. The important problems are toxic gases emitted by conventional power plants. One of the methods that contribute to decreasing air pollution is manufacturing of cheap solar energy devices that could be applied in households. Among different type of fabrication technology of solar cells, DSSC technology looks like one of the interesting because it is relatively simple and low cost technology. Nowadays a lot of researcher groups making investigations to improve its setup, to get the cost reduction. The methods to achieve this goal were proposed in ISE (Germany) as a concept of monolithic dye sensitised solar cell. One of the ideas of this solar cells setup is replacing expensive TCO electrode by much cheaper graphite electrode. Replacing TCO glass by graphite layer has to be done only in case of comparable properties of those both electrodes. There are some tested ideas of manufacturing that electrode and some of them are successfully applied. Presented work has been focused on preparation graphite conductive electrode for DSSC technology application, fabricated by screen–printing technique. Investigations concern new graphite past composition suitable for graphite layer preparation. It was been found that applying additive of titanium organic compound (Tyzor GBA) to the past composition result in good properties, characterised by low resistance and good adhesion between graphite particles in the printed layer. Some tested layers prepared from proposed paste compositions characterised by better conductivity then applied in conventional DSSC cells counter electrode. The optimal addition of the modifier has not fixed yet. Among tested pastes the most promising results has been achieved for paste contained the biggest amount of Tyzor GBA.
Czasopismo
Rocznik
Strony
153--156
Opis fizyczny
Bibliogr. 12 poz., rys., tab., wykr.
Twórcy
autor
- Crakow University of Technology, Institute of Materials Engineering, , Jana Pawla II 37 str., 30-867 Krakow, Poland
autor
- Crakow University of Technology, Institute of Materials Engineering, , Jana Pawla II 37 str., 30-867 Krakow, Poland
Bibliografia
- [1] B. O’Regan, M. Grätzel, A low cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 1991, 353, 737–739.
- [2] D. Songyuan, W. Jian at al., The design and outdoor application of dye-sensitized solar cells, Inorganica Chimica Acta, Vol 361, 3, February 15, 2008, 786-791.
- [3] S. Furukawa , H. Iino, T. Iwamoto at al., Characteristics of dye-sensitized solar cells using natural dye, Thin Solid Films, 518, 2009, 526–529.
- [4] A. Kay, M. Grätzel, Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Sol Energy Mater Sol Cells, 1996, 44, 99–117.
- [5] W. Lee, E. Ramasamya at al., Performance variation of carbon counter electrodebased dye-sensitized solar cell, Solar Energy Materials & Solar Cells, 92 ,2008, 814–818.
- [6] E. Ramasamy, W. Lee at al. Portable, parallel grid dyesensitized solar cell module prepared by screen printing, Journal of Power Sources, 165, 2007, 446–449.
- [7] Y. Chiba, A. Islam, at al., Dye-sensitized solar cells with conversion efficiency of 11.1%, Jpn. J. Appl. Phys. 45, 2006, L638–L640.
- [8] P. Li, J. Wu , J. Lin at al., High-performance and low platinum loading Pt/Carbon black counter electrode for dyesensitized solar cells, Solar Energy, 83, 2009, 845–849.
- [9] Z. Huang, X. Liu, K. Li at al., Application of carbon materials as counter electrodes of dye-sensitized solar cells, Electrochemistry Communications, 9, 2007, 596–598.
- [10] H. Zhu, J. Wei, K. Wang, at al., Applications of carbon materials in photovoltaic solar cells, Solar Energy Materials & Solar Cells, 93, 2009, 1461–1470.
- [11] K. Imotoa, K. Takahashi,T. Yamaguchi, High-performance carbon counter electrode for dye-sensitized solar cells, Solar Energy Materials & Solar Cells, 79, 2003, 459–469.
- [12] J. Chen, K. Li, Y. Luo, at al., A flexible carbon counter electrode for dye-sensitized solar cells, Carbon, 47, 2009, 2704 – 2708.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ece9643e-aebe-49b1-a23f-c478befb15dd