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The immobilization effect of soil amendments on leaching and bioavailability of Pb, Zn and Cd in highly contaminated soils under industrial impact was studied by collecting the soils in the surroundings of Zn-Pb Smelter “Miasteczko Śląskie” in southern Poland as an example. Various amounts of four additives (phosphate fertilizer, limestone powder, bentonite rock and bog iron ore) were tested in laboratory experiments to compare the effectiveness of three dominant mechanisms of immobilization: precipitation of phosphates, pH increase, and sorption. The contents of metals before immobilization were determined by extraction in CaCl2, EDTA and aqua regia. Cadmium and zinc are mainly represented by soluble, bioavailable forms extractable in CaCl2, while lead by potentially bioavailable speciations extractable by EDTA. Most effective in the immobilization of these metals were the amendments increasing soil pH: limestone powder and phosphate fertilizer. Bog iron ore and bentonite were less effective because the soil pH was too low for efficient cation adsorption.
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Rocznik
Tom
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67--81
Opis fizyczny
Bibliogr. 94 poz., rys., tab., wykr.
Twórcy
autor
- AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ec2cf8f3-724d-4c0f-8803-21491a0627a3