Adsorption of arsenic on granular ferric hydroxide (GEH®). Impact of initial concentration of arsenic(V) on kinetics and equilibrium state

• Autorzy: Saldaña-Robles A. , Saldaña-Robles A. , Márquez-Herrera A. , Ruiz-Aguilar G. M. L. , Flores-Ortega A. , Saldaña-Robles N.

Identyfikatory

DOI

10.5277/epe180304

• Języki publikacji: EN

Abstrakty

EN

The present study discusses the adsorption kinetics of arsenic(V) on granular ferric hydroxide (GEH) and the GEH adsorption capacity for arsenic(V) at equilibrium. The impact of temperature on GEH adsorption capacity was studied, as well as the effects of the initial concentration of arsenic(V) and GEH concentration on the adsorption rates of arsenic(V). The Freundlich isotherm describes the arsenic(V) adsorption behavior reasonably well (r² > 0.965). The adsorption kinetics was studied by fitting the experimental data to both first-order and second-order models. The maximum adsorption capacity of arsenic(V) on GEH was 2.701 mg·g^–1, which is higher than the adsorption capacities of other adsorbents reported. The kinetics of arsenic(V) adsorption was well defined by the second-order model, with the correlation coefficients in the range of 0.960–0.987. This study shows that due to its properties, GEH is a good candidate for removal of arsenic(V) from groundwater.

Słowa kluczowe

EN

adsorption; groundwater; kinetics

PL

adsorpcja; wody podziemne; kinetyka

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2018
• Tom: Vol. 44, nr 3
• Strony: 51--62
• Opis fizyczny: Bibliogr. 30 poz., tab., rys.

Twórcy

autor

Saldaña-Robles A.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

autor

Saldaña-Robles A.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

autor

Márquez-Herrera A.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

autor

Ruiz-Aguilar G. M. L.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

autor

Flores-Ortega A.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

autor

Saldaña-Robles N.

• Division Ciencias de la Vida, Campus Salamanca-Irapuato, Universidad de Guanajuato, Ex Hacienda El Copal, Km. 9 Carretera Irapuato-Silao, Irapuato, GTO

Bibliografia

• [1] KOLBE F., WEISS H., MORGENSTERN P., WENNRICH R., LORENZ W., SCHURK K., STANJEK H., DAUS B., Sorption of aqueous antimony and arsenic species onto akaganeite, J. Colloid Interface Sci., 2011, 357 (2), 460.
• [2] RAZO I., CARRIZALES L., CASTRO J., DÍAZ-BARRIGA F., MONROY M., Arsenic and heavy metal pollution of soil, water and sediments in a semi-arid climate mining area in Mexico, Water Air Soil Pollut., 2004, 154 (1), 129.
• [3] SONG S., LOPEZ A., HERNANDEZ D.J., PENG C., MONROY-FERNANDEZ M.G., RAZO-SOTO I., Arsenic removal from high-arsenic water by enhanced coagulation with ferric ions and coarse calcite, Water Res. J., 2006, 40 (2), 364.
• [4] CAMACHO L.M., GUTIÉRREZ M., ALARCÓN M.T., VILLALBA M.L., DENG S., Occurrence and treatment of arsenic in groundwater and soil in northern Mexico and southwestern USA, Chemosphere, 2011, 83 (3), 211.
• [5] BANERJEE K., GARY L.A., PREVOST M., NOUR S., JEKEL M., GALLAGHER P.M., BLUMENSCHEIN C.D.,Kinetic and thermodynamic aspects of adsorption of arsenic onto granular ferric hydroxide (GFH), Water Res., 2008, 42, 3371.
• [6] CHEN R., ZHI C., YANG H., BANDO Y., ZHANG Z., SUGIUR N., GOLBERG D., Arsenic(V) adsorption on Fe3O4 nanoparticle-coated boron nitride nanotubes, J. Colloid Interface Sci., 2011, 359 (1), 261.
• [7] LAMM S.H., ROBBINS S.A., ZHOU C., LU J., CHEN R., FEINLEIB M., Bladder/lung cancer mortality in blackfoot-disease (BFD). Endemic area villages with low (<150 µg/L) well water arsenic levels. An exploration of the dose–response Poisson analysis, Regul. Toxicol. Pharmacol., 2013, 65, 147.
• [8] LIN H.J., SUNG T.I., CHEN C.Y., GUO H.R., Arsenic levels in drinking water and mortality of liver cancer Taiwan, J. Hazard. Mater., 2013, 262, 1132.
• [9] WHO, Guidelines for Drinking Water Quality, 1. Recommendations, World Health Organization, Geneva 1993.
• [10] Mexican Official Norm, NOM-127-SSA-1994, 2000. Environmental health, water for use and human intake – permissible limits of quality and treatments that must be applied for water purification.
• [11] BASKAN M.B., PALA A., Removal of arsenic from drinking water using modified natural zeolite, Desalination, 2011, 281, 396.
• [12] MOSTAFA M.G., CHEN Y.H., JEAN J.S., Kinetics and mechanism of arsenate removal by nanosized iron oxide-coated perlite, J. Hazard. Mater., 2011, 187, 89.
• [13] GILES D.E., MOHAPATRA M., ISSA T.B., Iron and aluminum based adsorption strategies for removing arsenic from water, J. Environ. Manage., 2011, 92, 3011.
• [14] JAIN C.K., SINGH R.D., Technological options for the removal of arsenic with special reference to South East Asia, J. Environ. Manage., 2012, 107, 1.
• [15] AREDES S., KLEIN B., PAWLIK M., The removal of arsenic from water using natural iron oxide minerals, J. Clean Prod., 2012, 29–30, 208.
• [16] NIETO C., RANGEL J.R., Anchorage of iron hydro(oxide) nanoparticles onto activated carbon to remove As(V) from water, Water Res., 2012, 46 (9), 2973.
• [17] TRESINTSI S., SIMEONIDIS K., VOURLIAS G., STAVROPOULOS G., MITRAKAS M., Kilogram-scale synthesis of iron oxyhydroxides with improved arsenic removal capacity. Study of Fe(II) oxidation/precipitation parameters, Water Res., 2012, 46 (16), 5255.
• [18] TANBOONCHUY V., GRISDANURAK G., LIAO C.H., Background species effect on aqueous arsenic removal by nano zero-valent iron using fractional factorial design, J. Environ. Manage., 2012, 205–206, 40.
• [19] JIANG W., CHEN X., NIU Y., PAN B., Spherical polystyrene-supported nano-Fe3O4 of high capacity and low-field separation for arsenate removal from water, J. Hazard. Mater., 2012, 243, 319.
• [20] DRIEHAUS W., Arsenic removal from drinking water. The GEH® process, AWWA Inorganic Contaminants Workshop, Albuquerque, NM, U.S.A., 2000.
• [21] HU S., LU J., JING C., A novel colorimetric method for field arsenic speciation analysis, J. Environ. Sci., 2012, 24 (7), 1341.
• [22] GUTIÉRREZ O.E., GARCÍA G., ORDOÑEZ E., OLGUÍN M.T., CABRAL-PRIETO A., Synthesis, characterization and adsorptive properties of carbon with iron nanoparticles and iron carbide for the removal of As(V) from water, J. Environ. Manage., 2013, 114, 1.
• [23] MALANA M.A., QURESHI R.B., ASHIQ M.N., Adsorption studies of arsenic on nano aluminium doped manganese copper ferrite polymer (MA, VA, AA) composite: Kinetics and mechanism, Chem. Eng. J., 2011, 172 (2–3), 721.
• [24] LADEIRA A.C.Q., CIMINELLI V.S.T., Adsorption and desorption of arsenic on an oxisol and its constituents, Water Res., 2004, 38 (8), 2087.
• [25] GU Z., FANG J., DENG B., Preparation and evaluation of GAC-based iron-containing adsorbents for arsenic removal, Environ. Sci. Technol., 2005, 39 (10), 3833.
• [26] DELIYANNI E.A., BAKOYANNAKIS D.N., ZOUBOULIS A.I., MATIS K.A., Sorption of As(V) ions by alaganeite-type nanocrystals, Chemosphere, 2003, 50 (1), 155.
• [27] BADRUZZAMAN M., WESTERHOFF P., KNAPPE D.R.U., Intraparticle diffusion and adsorption of arsenate onto granular ferric hydroxide (GFH), Water Res., 2004, 38, 4002.
• [28] AMY G., CHEN, H., BRANDHUBER N., GRAZIANO N., VON GUNTEN U., CHOWDHURY Z., KOMMINENI S.,BANERJEE K., JEKEL M., Impact of water quality parameters on adsorbent treatment technologies for arsenic removal, AWWA Research Foundation, 2004.
• [29] HIGHFIELD D.E., Arsenic occurrence in metro Phoenix ground water and treatment by granular ferric hydroxide, MS Thesis, Arizona State University, Tempe 2002.
• [30] RODRÍGUEZ R., MORALES-ARREDONDO I., RODRÍGUEZ I., Geological differentiation of groundwater threshold concentrations of arsenic, vanadium and fluorine in El Bajio Guanajuatense, Mexico, Geofísica Internacional, 2016, 55 (1), 5.