Impact of the Mixture of Hexa(N-hydroxymethyl)amidocyclotriphosphazene and Partially Methylated Melamine Formaldehyde Resin on the Flame Retardancy of Paper

• Autorzy: Tang L. , Zhao J. , Sui X. , Song H. , He W.

Identyfikatory

DOI

10.5604/12303666.1201144

Warianty tytułu

PL

Wpływ mieszaniny hexa(N-hydroksymetylo)amidocyklotrifosfazenu i częściowo zmetylowanej żywicy melaminowoformaldehydowej na zmniejszenie palności papieru

• Języki publikacji: EN

Abstrakty

EN

The flame retardancy of the mixture of hexa(N-hydroxymethyl)amidocyclotriphosphazene and partially methylated melamine formaldehyde resin (HHMATP/PMMM) in paper was proposed by limiting oxygen index measurement (LOI), the vertical burning test and cone calorimetry test (CCT). In our research, the LOI of washed FR-paper could still be up to 33.5%; the after flame time , and burning time were reduced to 4.8 s & 0 s, and the char length was only 12.0 mm. While the results of CCT imply that compared with non-flame retarded paper, the heat release rate (HRR) of FR-paper with HHMAPT/PMMM increases gently; the mass loss becomes significantly slow, and the prolonged maximum heat release rate (PHRR), average heat release rate (MHRR), average effective heat of combustion (MEHC) and total heat release (THR) drop greatly. According to the experimental results, HHMATP/PMMM has not only excellent flame retardancy in paper but also good water resistance, with HHMATP/PMMM playing a flame retardant role mainly by means of the condensed phase mechanism.

PL

Badano zmniejszenie palności papieru stosując mieszaninę hexa(N-hydroxymethyl)amidocyclotriphosphazene i częściowo zmetylowanej żywicy melamine formaldehyde (HHMATP/PMMM) poprzez indeks tlenowy (LOI), test pionowego palenia i test kalorymetru stożkowego (CCT). Eksperymenty wykazały, że HHMATP/PMMM ma nie tylko dobry wpływ na ograniczenie palności papieru, ale również na jego odporność na działanie wody.

Słowa kluczowe

EN

hexa(N-hydroxymethyl)amidocyclotriphosphazene; partially methylated; melamine formaldehyde resin; flame retardancy; paper

PL

hexa(N-hydroksymetyl)amidocyklotrifosfazen; ognioodporność; palność papieru

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2016
• Tom: Vol. 24, no. 4 (118)
• Strony: 153--160
• Opis fizyczny: Bibliogr. 27 poz., rys., tab.

Twórcy

autor

Tang L.

• College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China
• Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education of China, Qilu University of Technology, Jinan, P. R. China

autor

Zhao J.

• College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China

autor

Sui X.

• College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China

autor

Song H.

• College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China

autor

He W.

• College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China

Bibliografia

• 1. Köklükaya O, Carosio F, Grunlan J C and Wågberg L. Flame-Retardant Paper from Wood Fibers Functionalized via Layerby-Layer Assembly. ACS Appl. Mater. Interfaces 2015; 7: 23750−23759.
• 2. Li C, Hui LF and Liu Z. Development status and trend in flame retardant paper. China Pulp ＆ Paper Industry 2010; 23: 62-66.
• 3. Cui JF, Guo JH and Yang BP. Investigation and preparation of sizing agent with waterborne epoxy bromine carbon resin for flame retardant paper. Journal of Lanzhou University of Technology 2010; 36: 62-65.
• 4. Katovic D, Vukusic SB, Grgac SF, Lozo B and Banic D. Flame retardancy of paper obtained with environmentally friendly agents. Fibres and Textiles in Eastern Europe 2009; 17, 3(74): 90-94.
• 5. Guo DD and Li YT. Synthesis of Halogen-Free Flame Retardant Agent and Its Application in the Paper making. Paper and Paper Making 2012; 31: 54-57.
• 6. Ma ML. Modified amidine urea phosphate flame retardant impregnated paper research. Fire Science and Technology 2012; 28: 932-933, 940.
• 7. Zhou H, Liu Z and Wei YJ. Research on the preparation of flame retardant magnesium hydroxide as fire retardant in paper. China Pulp & Paper 2009; 28: 13-16.
• 8. Liu YJ, Hao ZX and Liu YW. Multiple layered double hydroxyl metal composite oxide is used as flame retardant filler preparation of flame retardant in paper. China Pulp & Paper 2012; 31: 17-21.
• 9. Wang SL and Huang JL. Silicon doping effect on the properties of flame retardant filler magnesium aluminum hydrotalcite. China Pulp & Paper Industry 2012; 33: 40-43.
• 10. Wang SL, Huang JL, Shao XJ and Chen FS. Doped zinc magnesium aluminum water talc in the paper for application of the flame retardant. China Pulp & Paper Industry 2012; 33: 38-41.
• 11. Hu F, Nie SX and OuYang CL. Research on Sodium aluminum silicate coating properties of flame retardant paper combined systems. China Pulp & Paper 2012; 31: 22-25.
• 12. Yang SS. The development of sepiolite flame retardant in paper. Transactions of China Pulp & Paper 2005; 20: 153-155.
• 13. Liagkouridis L, Cousins IT and Cousins AP. Emissions and fate of brominated flame retardants in the indoor environment: A critical review of modeling approaches. Science of the Total Environment 2014; 491-492: 87-99.
• 14. Alongi J, Carletto RA, Di Blasio A, Carosio F, Bosco F and Malucelli G. DNA: a novel, green, natural flame retardant and suppressant for cotton. J. Mater. Chem. A 2013; 1: 4779-4785.
• 15. Cain A A, Nolen C R, Li Y C, Davis R and Grunlan J C. Phosphorous-filled nanobrick wall multilayer thin film eliminates polyurethane melt dripping and reduces heat release associated with fire. Polym. Degrad. Stab. 2013; 98: 2645-2652.
• 16. Alongi J, Carletto R A, Bosco F, Carosio F, Di Blasio A, Cuttica F, Antonucci V, Giordano M, Malucelli G. Caseins and hydrophobins as novel green flame retardants for cotton fabrics. Polym. Degrad. Stab. 2014; 99: 111-117.
• 17. Camino G, Costa L, Luda di Cortemiglia M P. Overview of fire retardant mechanisms. Polym. Degrad. Stab. 1991; 33: 131-154.
• 18. Alongi J, Di Blasio A, Cuttica F, Carosio F and Malucelli G. Bulk or surface treatments of ethylene vinyl acetate copolymers with DNA: Investigation on the flame retardant properties. Eur. Polym. J. 2014; 51: 112-119.
• 19. Qian LJ. The current research and development status quo of phosphorus-containing flame retardants. Chinese Journal of Flame Retardant 2011; 3: 2-4.
• 20. Hebeish A, Waly A and Abou-Okeil AM. Flame retardant cotton. Fire and Materials 1999; 23: 117-123.
• 21. Shizuo K. Fireproofing Method of fibers by aminophosphazenes derivatives. Patent JP0104074A2, JP, 1989.
• 22. He W, Liu YJ and Tang LS. Preparation of high performance flame retardant paper. Paper Science & Technology, 2014; 33: 46-49.
• 23. He W, Bi W, Ke Y, Liu YJ and Tang LS. Flame retarded paper with hexaadimocyclotriphosphazene. Paper Science & Technology 2015; 34: 24-26.
• 24. He W, Liu YJ, Li T and Tang LS. The flame retardancy of hexahydroxymethyladimocyclotriphosphazene on paper. Paper Science & Technology 2015; 34: 34-38.
• 25. Coating Process Board. Coating process board (the first volume). Beijing: Chemical Industry Press 1997; 553-555.
• 26. Yang KJ, Su WQ, Shen J. Mechanism and progress of wet strength agent for paper making. Paper Science & Technology 2006; 25: 58-62.
• 27. Maynard SJ, Sharp TR and Haw JF. Thermal degradation chemistry of poly(diphenoyphosphazene). Macromolecules 1991; 24: 2794-2799

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.