Setting Time and after Setting Properties of High Calcium Fly Ash Geopolymers with Different Concentration of Sodium Hydroxide

• Autorzy: Mohamed Rosnita , Abd Razak Rafiza , Al Bakri Abdullah Mohd Mustafa , Sofri Liyana Ahmad , Aziz Ikmal Hakem , Shahedan Noor Fifinatasha

Identyfikatory

DOI

10.24425/amm.2022.137791

• Języki publikacji: EN

Abstrakty

EN

Setting time in geopolymers is known as the time taken for the transition phase of liquid to solid of the geopolymer system in which is represented in the initial setting and final setting. Setting time is significant specifically for application in the construction field. This study intends to determine the setting time of high calcium fly ash geopolymers and the properties of the geopolymers after setting (1-day age). This includes the determination of heat evolved throughout geopolymerization using Differential Scanning Calorimeter. After setting properties determination includes compressive strength and morphology analysis at 1-day age. High calcium fly ash was used as geopolymer precursor. Meanwhile, for mixing design, the alkali activator was a mixture of sodium silicate and sodium hydroxide (concentration varied from 6M-14M) with a ratio of 2.5 and a solid-to-liquid ratio of 2.5. From this study, it was found that high calcium fly ash geopolymer with 12M of NaOH has a reasonable setting time which is suitable for on-site application as well as an optimal heat evolved (-212 J/g) which leads to the highest compressive strength at 1-day age and no formation of microcracks observed on the morphology. Beyond 12M, too much heat evolved in the geopolymer system can cause micro-cracks formation thus lowering the compressive strength at 1-day age.

Słowa kluczowe

EN

high calcium fly ash geopolymers; setting time; heat evolved; early age properties; concentration of sodium hydroxide

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2022
• Tom: Vol. 67, iss. 2
• Strony: 563--567
• Opis fizyczny: Bibliogr. 20 poz., fot., rys., tab., wykr., wzory

Twórcy

autor

Mohamed Rosnita

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis, Malaysia

• https://orcid.org/0000-0003-0778-9246

autor

Abd Razak Rafiza

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Civil Engineering Technology, Perlis, Malaysia

• https://orcid.org/0000-0001-5499-8564

autor

Al Bakri Abdullah Mohd Mustafa

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis, Malaysia

• https://orcid.org/0000-0002-9779-8586

autor

Sofri Liyana Ahmad

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Civil Engineering Technology, Perlis, Malaysia

• https://orcid.org/0000-0001-8008-3923

autor

Aziz Ikmal Hakem

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia

• https://orcid.org/0000-0002-2152-8918

autor

Shahedan Noor Fifinatasha

• Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia

• https://orcid.org/0000-0001-5390-4829

Bibliografia

• [1] W.W.A. Zailani, M.M.A.B. Abdullah, M.F. Arshad, R.A. Razak, M.F.M. Tahir, R.R.M.A. Zainol, M. Nabialek, A.V. Sandu, J.J. Wysłocki, K. Błoch, Materials 14, 56 (2021).
• [2] O.H. Li, L. Yun-Ming, H. Cheng-Yong, R. Bayuaji, M.M.A.B. Abdullah, F.K. Loong, T.A. Jin, N.H. Teng, M. Nabiałek, B. Jeż, N.Y. Sing, Magnetochemistry 7 (1), 9 (2021).
• [3] N.H. Jamil, M.M.A.B. Abdullah, F. Che Pa, M. Hasmaliza, W.M.A. Ibrahim, I.H.A. Aziz, B. Jeż, M. Nabiałek, Magnetochemistry 7, 32 (2021).
• [4] R. Hussin, S. Sharif, M. Nabiałek, S.Z.A. Rahim, M.T.M. Khushairi, M.A. Suhaimi, M.M.A.B. Abdullah, M.H.M. Hanid, J.J. Wysłocki, K. Błoch, Materials 14 (3), 665 (2021).
• [5] N.F. Shahedan, M.M.A.B. Abdullah, N. Mahmed, A. Kusbiantoro, S. Tammas-Williams, L.Y. Li, I.H. Aziz, P. Vizureanu, J.J. Wysłocki, K. Błoch, M. Nabiałek, Materials 14, 809 (2021).
• [6] N.A.M.A. Tamizi, S.Z.A. Rahim, A.E.-H. Abdellah, M.M.A.B. Abdullah, M. Nabiałek, J.J. Wysłocki, B. Jeż, P. Palutkiewicz, R.A. Rahman, M.N.M. Saad, M.F. Ghazli, Materials 14, 1416 (2021).
• [7] M.A. Faris, M.M.A.B. Abdullah, R. Muniandy, M.F. Abu Hashim, K. Błoch, B. Jeż, S. Garus, P. Palutkiewicz, N.A. Mohd Mortar, M.F. Ghazali, Materials 14, 1310 (2021).
• [8] F. Han, Z. Zhang, J. Liu, P. Yan, J. Therm. Anal. Calorim. 124, 1691-1703 (2016).
• [9] Z. Sun, A. Vollpracht, Cem. Concr. Res. 103, 110-122 (2017).
• [10] Z.H. Abbas, Constr. Mater. 7, 154-162 (2016).
• [11] R. Kumar, J. Therm. Anal. Calorim. 3, 41-54 (2018).
• [12] Z. Zhang, H. Wang, J.L. Provis, F. Bullen, A. Reid, Y. Zhu, Thermochim. Acta 539 23-33 (2012).
• [13] P. Chindaprasirt, T. Phoo-Ngernkham, S. Hanjitsuwan, S. Horpibulsuk, A. Poowancum, B. Injorhor, Case Stud. Constr. Mater. 9 (2018)
• [14] L. N. Tchadjie, S. O. Ekolu, J. Mater. Sci. 53, 4709-4733 (2018).
• [15] R. Cornelis, H. Priyosulistyo, I. Satyarno, App. Mech. Mater. 881, 158-164 (2018).
• [16] H.T. Ng, C.Y. Heah, Y.M. Liew, M.M.A.B. Abdullah, Aip Conf. Proc. 2045, 10-15 (2018). DOI: https://doi.org/10.1063/1.5080911
• [17] S.M.A. Kabir, U.J. Alengaram, M.Z. Jumaat, A. Sharmin, A. Islam, Adv. Mater. Sci. Eng. 2015, 647401 (2015).
• [18] D.D. Burduhos Nergis, M.M.A.B. Abdullah, P. Vizureanu, European Journal of Materials Science and Engineering 2 (4), 111-118 (2017).
• [19] D.D. Burduhos Nergis, P. Vizureanu, D. Topa, M.G. Minciuna, M.M.A.B. Abdullah, IOP Conf. Series: Materials Science and Engineering 877, 012044 (2020).
• [20] S.F. Azzahran Abdullah, L. Yun-Ming, M.M. Al Bakri, H. Cheng-Yong, K. Zulkifly, K. Hussin, IOP Conf. Ser. Mater. Sci. Eng. 343, 1 (2018)

Uwagi

1. The author would like to acknowledge the support from the Fundamental Research Grant Scheme (FRGS) under a grant number of 9003-00747 FRGS/1/2019/TK06/UNIMaP/02/1 from Ministry of Higher Education Malaysia. The authors also would like to acknowledge Centre of Excellence Geopolymer and Green Technology (CeGeoGTech), Universiti Malaysia Perlis and School of Materials and Mineral Sources Engineering of Universiti Sains Malaysia. Special thanks to those who contributed to this project directly or indirectly.

2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).