Use of Metal Oxide-Modified Aerated Concrete for Cleaning Flue Gases from Carbon Monoxide

• Autorzy: Ivanenko Olena , Gomelya Nikolai , Shabliy Tetyana , Trypolskyi Andrii , Nosachova Yuliia , Leleka Serhii , Trus Inna , Strizhak Peter

Identyfikatory

DOI

10.12911/22998993/135873

• Języki publikacji: EN

Abstrakty

EN

The necessity of development of technical solutions that will allow to reduce carbon monoxide emissions of flue gases of industrial productions is substantiated. It is shown that the most rational design solution to the problem of carbon monoxide pollution during the firing of electrode blanks is the use of aerated concrete blocks with a catalyst, which can be quickly and conveniently located directly on the carbon material of the “green” electrodes pouring in the subfloor space of the firing furnaces. Modified by oxides of Mn⁴⁺, Fe²⁺, Fe³⁺, Cu²⁺, Cr³⁺ -catalysts based on aerated concrete were obtained. It is shown that in an empty reactor in the temperature range 200–400 °С the degree of conversion of carbon monoxide in the absence of a catalyst is zero. It is established that on the investigated catalysts based on aerated concrete 100% oxidation of carbon monoxide is achieved at a temperature of 390 °C in the case of using a mixture of catalyst powders 30% CuO + 70% MnO₂, 40% CuO + 60% MnO₂, 50% Fe (Fe_xCr_1-x) 2O₄ + 50% MnO₂; 50% Fe₃O₄ + 50 % MnO₂. It is determined that the addition of ferrite catalyst powder in aerated concrete in a mixture or without manganese dioxide does not critically affect the mechanical properties of the products.

Słowa kluczowe

EN

carbon monoxide; flue gas; purification; catalyst; oxidation; conversion

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 5
• Strony: 104--113
• Opis fizyczny: Bibliogr. 23 poz., rys., tab.

Twórcy

autor

Ivanenko Olena

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0001-6838-5400

autor

Gomelya Nikolai

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0003-1165-7545

autor

Shabliy Tetyana

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0002-6710-9874

autor

Trypolskyi Andrii

• L. V. Pisarzhevskii Institute of Physical Chemistry of The National Academy of Sciences of Ukraine, Science Avenue, 31, 03028 Kyiv, Ukraine

• https://orcid.org/0000-0003-1682-0241

autor

Nosachova Yuliia

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

autor

Leleka Serhii

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0002-4372-9454

autor

Trus Inna

• Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenue 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0001-6368-6933

autor

Strizhak Peter

• L. V. Pisarzhevskii Institute of Physical Chemistry of The National Academy of Sciences of Ukraine, Science Avenue, 31, 03028 Kyiv, Ukraine

• https://orcid.org/0000-0003-0280-8719

Bibliografia

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• 2. Choi K.-H., Lee D.-H., Kim H.-S., Yoon Y.-C., Park C.-S., Kim Y.H. 2016. Reaction Characteristics of Precious-Metal-Free Ternary Mn–Cu–M (M = Ce, Co, Cr, and Fe) Oxide Catalysts for Low-Temperature CO Oxidation. Industrial & Engineering Chemistry Research, 55(16), 4443–4450.
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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).