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Reactions of Non-Ionic Surfactants, Triton X-n Type, with OH Radicals : A Review

Identyfikatory
Warianty tytułu
PL
Przegląd stosowanych reakcji niejonowych środków powierzchniowo czynnych typu Triton X-n z rodnikami OH
Języki publikacji
EN
Abstrakty
EN
The mechanism of decomposition of non-ionic surfactants, Triton X-n type, under the influence of ionising radiation is described. The survey of the available data strongly suggests that OH radicals are the main intermediates responsible for the radiation-induced destruction of wastewater containing non-ionic surfactants. The OH radicals’ contribution to advanced oxidation processes is discussed, including the case of textile wastewaters. The importance of pulse radiolysis technique is underlined with regard to the kinetic data determination.
PL
Przedstawiono mechanizm rozkładu niejonowych środków powierzchniowo czynnych typu Triton X-n w roztworze wodnym, zachodzący pod wpływem promieniowania jonizującego. Dane doświadczalne dowodzą, że rodniki OH są najważniejszym czynnikiem odpowiedzialnym za rozkład zanieczyszczeń w procesie radiacyjnego oczyszczania ścieków, także takich które zawierają niejonowe środki powierzchniowo czynne. Przedyskutowana została rola rodników OH w innych wersjach procesu pogłębionego utleniania, także w odniesieniu do ścieków włókienniczych. Podkreślono znaczenie techniki radiolizy impulsowej przy wyznaczaniu stałych kinetycznych.
Rocznik
Strony
81--85
Opis fizyczny
Bibliogr. 32 poz., rys.
Twórcy
autor
  • Technical University of Łódź Institute of Applied Radiation Chemistry ul. Wróblewskiego 15, 93-590 Łódź, Poland Tel (+48) 42 6313181 Fax (+48) 42 6840043
autor
  • Technical University of Łódź Institute of Applied Radiation Chemistry ul. Wróblewskiego 15, 93-590 Łódź, Poland Tel (+48) 42 6313181 Fax (+48) 42 6840043
autor
  • Institute of Knitting Technology and Techniques ul. Piotrkowska 270, 90-361 Łódź, Poland Tel (+48) 42 6847449 Fax (+48) 42 6370218
Bibliografia
  • 1. Manzano M.A., Derales J.A., Sales D., Quiroga J.M., ‘The effect of temperature on the biodegradation of a nonylphenol polyethoxylate in river water’, Water Research 33, pp. 2593, 1999.
  • 2. Franska M., Franski R., Szymanski A., Łukaszewski L., ‘A central fission pathway in alkylphenol etoxylate biodegradation’, Water Research 37, p. 1005, 2003.
  • 3. Masten S.J., Davies S.H.R., ‘Use of ozone and other strong oxidants for hazardous waste management’, in ‘Environmental oxidation’, eds. J.O. Nriagu and H.S. Simmons, J. Wiley and Sons., New York, chapter 18, p. 517, 1994.
  • 4. Rice R.G., ‘Application of ozone for industrial wastewater treatment – a review’, Ozone Sci. & Eng., 18, p. 477, 1997.
  • 5. Karolczak S., ‘Pulse radiolysis – experimental features’ in ‘Properties and reactions of radiation induced transients. Selected topics’, ed. J. Mayer, Polish Scientific Publishers, PWN, Warszawa, chapter 1, pp. 11-37, 1999.
  • 6. Wilson R.L., Greenstock G.L., Adams G.E., Wageman R., Dorfman L.M., ‘The standardization of hydroxyl radical rate data from radiation chemistry’, Int. J. Radiat. Phys. Chem.3, p. 2111971.
  • 7. Jonah C.D., Miller J.R., Matheson M.S., ‘The reaction of eaq- + H3O+. Concentration effects of acid or salts’, J. Phys. Chem.81, p. 931, 1977.
  • 8. Janata E., Schuler R.H., ‘Rate constant for scavenging eaq- in N2O saturated solutions’, J.Phys. Chem. 86, p. 20781982.
  • 9. Buxton G., Greenstock G.L., Helman W. P., Ross A.B., ‘Critical review of rate constants for reaction of hydrated electrons, hydrogen atoms and hydroxyl radicals (˙OH/ O˙–) in aqueous solution’, J. Phys. Chem. Ref. Data, 17, p. 513, 1988.
  • 10.Gordon S., Hart E.J., Matheson M.S., Rabani J., Thomas J.K., ‘Reaction constants of the hydrated electron’, J. Am. Chem. Soc 85, p. 1375, 1963.
  • 11. Gordon S., Hart E.J., Thomas J.K., ‘The ultraviolet spectra of transients produced in the radiolysis of aqueous solutions’, J. Phys. Chem 68, p. 1262, 1964.
  • 12. Perkowski J., Mayer J., Ledakowicz S., ‘Determination of critical micelle concentration of non-ionic surfactants using kinetic approach’, Colloids and Surfactants A: Physicochem. Eng. Aspects 101, p. 103, 1995.
  • 13. Ghosh H.N., Sapre A.V., Rama Rao K.V.S., ‘Dual sites of salvation for electrons and cation-electron recombination observed in the radiolysis of Triton X-100 and water-mixtures. Homogeneous and liquid crystalline regions’, Chem. Phys. Lett. 255, p. 49, 1996.
  • 14. Perkowski J., Mayer J., ‘Pulse radiolysis of Triton X-100 aqueous solution’, J. Radioanal. Nuclear Chem.Articles., 141, p. 271, 1990.
  • 15. Thomas J.H., in ‘Radiation Chemistry: Principles and Applications’, VCH Publishers Inc. p. 377, 1987.
  • 16. Robson R.J., Dennis E.A., ‘The size, shape and hydration of non-ionic surfactant micelles. Triton X-100’, J. Phys. Chem 81, 11, p. 1075, 1977.
  • 17. Perkowski J., Mayer J., ‘Gamma- radiolysis of Triton X-100 aqueous solution’, J.Radioanal. Nuclear Chem., Articles 157, p. 27, 1992.
  • 18. Henglein A., Proske Th., ‘Free radicals in colloidal systems: formation and decay of radicals in the tensides n-hexadecyl-ω hydroxpoly(oxyethylene)’, Macrom. Chem.179, p. 2279, 1978.
  • 19. von Sontag C., Schuchmann H.-P., ‘The chemistry behind the application of ionizing radiation in water-pollution abatement’, in ‘Radiation chemistry. Present status and future trends’, C. D. Jonah, D.S. Madhava Rao eds., Elsevier, Amsterdam - London - New York - Oxford - Paris - Schannon - Tokyo, pp. 657-670, 2001.
  • 20. Perkowski J., Mayer J., ‘Oxygen effect in radiolysis of Triton X-100 aqueous solution’, J. Radioanal. Nucl. Chem., Letters 188, p. 211, 1994.
  • 21. Alfassi Z.B., ‘A comment on ‘Oxygen effect in the radiolysis of Triton X-100 aqueous solution’, by Perkowski and Mayer, J. Radioanal. Nucl. Chem., Letters 188 (1994), 211’ J. Radioanal. Nucl. Chem., Letters 199, p. 423, 1995.
  • 22. Bielski B.H.J., Cabelli D.E., Arudhi A.L., Ross A.B., ‘Reactivity of HO2˙/ O2˙– radicals in aqueous solution’, J. Phys. Chem, Ref. Data 14, p. 1041, 1985.
  • 23. Getoff N., ‘Radiation-induced degradation of water pollutants – state of the art’, Radiat. Phys. Chem 47, p. 581, 1996.
  • 24. Oppenlander T., ‘Photochemical purification of water and air’, Wiley – VCH, chapter 7, p. 189, 2003.
  • 25. Savage P.E., Yu Jianli., Stylski N., Brock E.E., ‘Kinetics and mechanism of methane oxidation in supercritical water’, J. Supercrit. Fluids 12, p. 141, 1998.
  • 26. Brock E.E., Savage P.E., Barker J.R., ‘A reduced mechanism for methanol oxidation in supercritical water’, Chem. Eng. Sci. 53, p. 857, 1998.
  • 27. Kos L., Perkowski J., ‘Application of ozone and UV-radiation in textile wastewater treatment’, Fibres & Textiles in Eastern Europe.1 (24), pp. 61-64, 1999.
  • 28. Kos L., Perkowski J., ‘Application of ozone and hydrogen peroxide in textile wastewater treatment’, Fibres & Textiles in Eastern Europe. 2 (25), pp. 61-64, 1999.
  • 29.Kos L., Perkowski J., ‘Simultaneous application of H2O2 and UV or O3, H2O2 and UV in textile wastewater treatment’, Fibres & Textiles in Eastern Europe. 3 (26), pp. 57-61, 1999.
  • 30. Kos L., Perkowski J., ‘Advanced oxidation process in the technology of textile wastewater treatment’, Fibres & Textiles in Eastern Europe. 1 (28), pp. 66-70, 2000.
  • 31. Perkowski. J., Kos L., ‘Treatment of textile dyeing wastewater by hydrogen peroxide and ferrous ions’, Fibres & Textiles in Eastern Europe. 3 (38), pp. 78-81, 2002.
  • 32. Kos L., Perkowski J., ‘Decolouration of real textile wastewater with advanced oxidation processes’, Fibres & Textiles in Eastern Europe. 4 (43), pp. 81-85, 2003.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e9b7156f-1bf2-473d-a128-3e9f862354c1
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