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NH4+ adsorption and adsorption kinetics by sediments in a drinking water reservoir

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Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The sorption isotherm and sorption kinetics of NH4+by the Fen River reservoir sediment were investigated for a better understanding of the NH4+ sorption characteristics and parameters. The results showed that Q (adsorption content) increased with the increase of Ceq (equilibrium concentration), sorption isotherms could be described by Freundlich equation (R2 from 0.97 to 0.99). Cation exchange capacity (CEC) had a significant correlation with the parameters K and n (R2 was 0.85 and 0.95, respectively). The ENC0 (Ceq as Q was zero) of S1, S2, S3 and S4 was 1.25, 0.57, 1.15 and 1.14 mg L-1, respectively, and they were less than the NH4+ concentrations in reservoir water. The sediments released NH4+ to the Fen River reservoir water and acted as a pollution source, in the form of complex and heterogeneous adsorbents. The NH4+ adsorption kinetic process was composed of ‘fast’ and ‘slow’ reaction patterns and could be fitted using both Elovich equation and Pseudo second-equation. More than one-step may be involved in the NH4+ sorption processes, and interior diffusion was not dominant ion action.
Słowa kluczowe
Rocznik
Strony
90--95
Opis fizyczny
Bibliogr. 26 poz., rys., tab., wykr.
Twórcy
autor
  • College of Chemical and Biological Engineering, Taiyuan University of Science and Technology, China
autor
  • Institute of Shanxi Soil and Water Conservation, China
Bibliografia
  • [1]. Aminot, A. & Andrieux, F. (1996). Concept and determination of exchangeable phosphate in aquatic sediments, Water Research, 30, 11, pp. 2805-2811.
  • [2]. Balci, S. & Dincel, Y. (2002). Ammonium ion adsorption with sepiolite: use of transient uptake method, Chemical Engineering Processing: Process Intensification, 41, 1, pp. 79-85.
  • [3]. Bouyoucos, G.J. (1951). A recalibration of the hydrometer method for making mechanical analysis of soils, Agronomy Journal, 43, 9, pp. 434-438.
  • [4]. Brankov, J., Milijašević, D. & Milanović, A. (2012). The assessment of the surface water quality using the water pollution index: A case study of the Timok River (The Danube River Basin), Serbia, Archives of Environmental Protection, 38, 1, pp. 49-61.
  • [5]. Darvishi, G., Kootenaei, F.G., Ramezani, M., Lotfi , E. & Asgharnia, H. (2016). Comparative Investigation of River Water Quality by OWQI, NSFWQI and Wilcox Indexes (Case study: the Talar River-IRAN), Archives of Environmental Protection, 42, 1, pp. 41-48.
  • [6]. de-Bashan, L.E., Hemandez, J.P., Morey, T. & Bashan, Y. (2004). Microlgae growth-promoting bacteria as “helpers” for microalgae: a novel approach for removing ammonium and phosphorus from municipal wastewater, Water Research, 38, 2, pp. 466-474.
  • [7]. Demirbas, E., Kobya, M. & Sulak, M.T. (2008). Adsorption kinetics of a basic dye from aqueous solutions onto apricot stone activated carbon, Bioresource technology, 99, 13, pp. 5368-5373.
  • [8]. Dixit, S.G., Vanjara, A.K., Nagarkar, J., Nikoorazm, M. & Desi, T. (2002). Co-adsorption of quaternary ammonium compounds- -nonionic surfactants on solid-liquid interface, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 205, 1-2, pp. 39-46.
  • [9]. Gurses, A., Karaca, S. Dogar, C., Bayrak, R., Acikyidiz, M. & Yalcin, M. (2004). Determination of adsorptive properties of clay/water system: methylene blue sorption, Journal of Colloid and Interface Science, 269, 2, pp. 310-314.
  • [10]. Holmboe, N. & Kristensen, E. (2002). Ammonium adsorption in sediments of a tropical mangrove forest (Thailand) and a temperate Wadden Sea area (Denmark), Wetlands Ecology and Management, 10, pp. 453-460.
  • [11]. Hou, L. J., Liu, M., Jiang, H.Y., Xu, S.Y., Ou, D.N., Liu, Q.M. & Zhang, B.L. (2003). Ammonium adsorption by tidal flat surface sediments from the Yangtze Estuary, Environmental Geology, 45, 1, pp. 72-78.
  • [12]. Ji, Z.Y., Yuan, J.S. & Li, X.G. (2007). Removal of ammonium from wastewater using calcium from clinoptilolite, Journal of Hazardous Materials, 141, 3, pp. 483-488.
  • [13]. Kaiserli, A., Voutsa, D. & Samara, C. (2002). Phosphorus fractionation in lake sediments-Lakes Volvi and Koronia, N. Gress, Chemosphere, 46, 8, pp. 1147-1155.
  • [14]. Kelly, G. (1996). Environmental Engineering. Mc Graw Hill, Maidenhead, England 1996.
  • [15]. Krom, M.D. & Berner, R.A. (1981). The diagenesis of phosphorus in a nearshore marine sediment, Geochimca et Cosmochimica Acta, 45, 2, pp. 207-216.
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  • [18]. Martens, C.S., Berner, R.A. & Rosenfeld, J.K. (1978). Interstitial water chemistry of anoxic Long-Island Sound sediments. 2. Nutrient regeneration and phosphate removal 1, Limnolgy and Oceanography, 23, 4, pp. 605-617.
  • [19]. Metcalf, E. (2003). Wastewater Engineering: Treatment and Reuse, Mc Graw Hill. New York 2003.
  • [20]. Morin, J. & Morse, J.W. (1999). Ammonium release from resuspended sediments in the Laguna Madre estuary, Marine Chemistry, 65, 12, pp. 97-110.
  • [21]. Qzcan, A., Oncu, E.M. & Ozcan, A.S. (2006). Adsorption of Acid Blue 193 from aqueous solution onto DEDMA-sepiolite, Journal of Hazardous materials, 129, 1-3, pp. 244-252.
  • [22]. Rosenfeld, J.K. (1979). Ammonium adsorption in nearshore anoxic sediments, Limnology and Oceanography, 24, 2, pp. 356-364.
  • [23]. Rysgaa, S., Thastum, P., Dalsgaard, T., Christensen, P.B. & Sloth, N.P. (1999). Effects of salinity on NH4 + adsorption capacity, nitrification, denitrification in Danish estuary sediments, Estuaries, 22, 1, pp. 21-30.
  • [24]. Ugurlu, M. & Karaoglu, M.H. (2011). Adsorption of ammonium from an aqueous solution by fl y ash and sepiolite: Isotherm, kinetic and thermodynamic analysis, Microporous and Mesoporous Materials, 139, 1-3, pp. 173-178.
  • [25]. Zhou, A.M., Tang, H.X. & Wang, D.S. (2005). Phosphorus adsorption on natural sediments: Modeling and effects of pH and sediment composition, Water Research, 39, 7, pp. 1245-1254.
  • [26]. Zhou, Q.X., Gibson, C.E. & Zhu, Y.M. (2001). Evaluation of phosphorus bioavailability in sediments of three contrasting lakes in China and the UK, Chemosphere, 42, 2, pp. 221-225.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e9b43b75-7098-4f70-ab0b-35665fd5312d
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