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Oil Recovery from Oilfield Produced Water Using Zinc Oxide Nano Particle as Catalyst in Batch and Continuous System

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This article describes the design of photo catalyst reactor for oil removing from produced water. Real produced water containing a combination of organic compounds was treated with zinc oxide nanoparticles. In this study, ultraviolet radiations were used to find the efficiency of removing the oil content from the water produced that brought from the Al-Ahdab oilfield in kut/ Iraq by advanced oxidation process (AOP) using (ZnO/UV) in batch system and continuous system. In batch system were studied the effect of zinc oxide concentration (nanoparticles), time of irradiation, and pH. The highest removal rate of oil from the produced water (100%) was obtained during the following optimal conditions: ZnO NPs as catalyst = 55 mg/L, pH =3, at the time of irradiation of 90 minutes in batch experiments. In the continuous system, the effects of flowrate, number of UV-A lamp and time of reaction were studied, the results obtained were the efficiency of decomposition decreases with increasing the flow rate of solution in reactor, the maximum removal efficiency of the process (ZnO/UV) was 80% at 20 mL/min and irradiation time 120 min. In general, zinc oxide is beneficial through its high oil adsorption capacity in addition, It lowers the amount of oil in the produced water.
Rocznik
Strony
278--286
Opis fizyczny
Bibliogr. 33 poz., rys., tab.
Twórcy
  • Department of Environmental Engineering, College of Engineering, Mustansiriyha University, P.O. Box 14150, Babal-Mu’adhem, Baghdad, Iraq
  • Department of Environmental Engineering, College of Engineering, Mustansiriyha University, P.O. Box 14150, Babal-Mu’adhem, Baghdad, Iraq
Bibliografia
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  • 22. Rao A.N., Sivasankar B., Sadasivam V. 2009. Kinetic study on the photocatalytic degradation of salicylic acid using ZnO catalyst. J. Hazard. Mater., 166, (2–3), 1357–1361.
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  • 27. Ling H., Kim K., Liu Z., Shi J., Zhu X., Huang J. 2015. Photocatalytic degradation of phenol in water on as-prepared and surface modified TiO2 nanoparticles. Catal. Today., 258, 96–102.
  • 28. Hassan A.A. & Al-zobai K.M.M. 2019. Chemical oxidation for oil separation from oilfield produced water under UV irradiation using Titanium dioxide as a nano-photocatalyst by batch and continuous techniques. Int. J. Chem. Eng., vol. 2019.
  • 29. Faisal M., Khan S.B., Rahman M.M., Jamal A., Abdullah M.M. 2012. Fabrication of ZnO nanoparticles based sensitive methanol sensor and efficient photocatalyst. Appl. Surf. Sci., 258(19), 7515–7522.
  • 30. Hassan A.A., Naeem H., Hadi R. 2018. Degradation of oily waste water in aqueous phase using solar (ZnO, TiO2 and Al2O3) catalysts. Pakistan J. Biotechnol., 15, 909–916.
  • 31. Mitrović J., Radović M., Bojić D., Anđelković T., Purenović M., Bojić A. 2012. Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process. J. Serbian Chem. Soc., 77(4), 465–481.
  • 32. Mohammed R.M. Al-zobai K.M.M. 2020. Photocatalytic degradation of organic pollutants in petroleum refinery using TiO2/UV and ZnO/UV by batch and continuous process. Solid State Technol., 63(3), 5390–5404.
  • 33. Monteiro R.A.R., Rodrigues-Silva C., Lopes F.V.S., Silva A.M.T., Boaventura R.A.R., Vilar V.J.P. 2015. Evaluation of a solar/UV annular pilot scale reactor for 24 h continuous photocatalytic oxidation of ndecane. Chem. Eng. J., 280, 409–416.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-e9ae8890-c140-487c-8be0-3303a56efc20
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